Flash Memory Devices

Flash memory devices have represented a breakthrough in storage since their inception in the mid-1980s, and innovation is still ongoing. The peculiarity of such technology is an inherent flexibility in terms of performance and integration density according to the architecture devised for integration. The NOR Flash technology is still the workhorse of many code storage applications in the embedded world, ranging from microcontrollers for automotive environment to IoT smart devices. Their usage is also forecasted to be fundamental in emerging AI edge scenario. On the contrary, when massive data storage is required, NAND Flash memories are necessary to have in a system. You can find NAND Flash in USB sticks, cards, but most of all in Solid-State Drives (SSDs). Since SSDs are extremely demanding in terms of storage capacity, they fueled a new wave of innovation, namely the 3D architecture. Today “3D” means that multiple layers of memory cells are manufactured within the same piece of silicon, easily reaching a terabit capacity. So far, Flash architectures have always been based on "floating gate," where the information is stored by injecting electrons in a piece of polysilicon surrounded by oxide. On the contrary, emerging concepts are based on "charge trap" cells. In summary, flash memory devices represent the largest landscape of storage devices, and we expect more advancements in the coming years. This will require a lot of innovation in process technology, materials, circuit design, flash management algorithms, Error Correction Code and, finally, system co-design for new applications such as AI and security enforcement

Remote sensing based assessment of land cover and soil moisture in the Kilombero floodplain in Tanzania

Wetlands provide important ecological, biological, and social-economic services that are critical for human existence. The increasing demand for food, arable land shortage and changing climate conditions in East Africa have created a paradigm shift from upland cultivation to wetland use due to their year-round soil water availability. However, there is need to control and manage the activities within the wetlands to ensure sustainable use while negating any negative effects caused by these activities. This is implemented through the decisions made by the land managers within the wetlands. Providing the users of the wetlands with scientific knowledge acts as a support tool for policy-making geared towards the sustainable use of the wetlands. The overall research contains two main components: First, the need for timely land cover maps at a reasonable scale, and secondly, the assessment of soil moisture as a major contributor to agricultural production. The objectives of the study were to generate land cover maps from multi-sensor optical datasets and to assess the performance of single-polarized Sentinel-1 Gray Level Co-occurrence Matrix (GLCM) texture and Principal Component Analysis (PCA) features by applying multiple classification algorithms in a floodplain in the Kilombero catchment. Furthermore, soil moisture spatial-temporal patterns over three hydrological zones was assessed, estimation of soil moisture from radar data and generation of soil moisture products from global products was investigated. The correlation of the merged products to Normalized Difference Vegetation Index (NDVI) measures was also investigated. RapidEye, Sentinel-2 and Landsat images were used in determining the areal extents of four major land cover classes namely vegetated, bare, water and built up. The acquisition period of the images ranges from August 2013 to June 2015 for the RapidEye images, December 2015 to August 2016 for the Sentinel-2 images and 2013 to 2016 Landsat-8 images were included in the land cover time series dynamic study. However, the major challenge arising was cloud coverage and hence Sentinel-1 images were tested in the application of Synthetic Aperture Radar (SAR) in wetland mapping. Variograms were used in spatial-temporal assessment of soil moisture data collected from three hydrological zones, riparian, middle and fringe. A roughness parameter was derived from a semi-empirical model. Soil moisture was retrieved from TerraSAR-X and RadarSAT-2 with the retrieved roughness parameter as an input in a linear regression equation. Triple collocation was applied in error assessment of the global soil moisture products prior to development of a merged product. Cross-correlation was applied in relating NDVI to soil moisture. Optical data (RapidEye, Landsat-8, and Sentinel-2) generated land cover maps used in assessing the land cover dynamics over time. The land cover ratios were related to depth to groundwater. As the depth to groundwater reduced in June the bare land coverage was 45-57% while that of vegetation was 34-47%. In December when the depth to groundwater was highest, bare land coverage was 62-69% while that of the vegetated area was 27-25%. This indicates that depth of groundwater and vegetation coverage responds to seasonality. During the dry season, 68-81% of the total vegetation class is within the riparian zone. In the classification of the SAR images, the overall accuracies for the single polarized VV images ranged from 54-76%, 60-81% and 61-80% for Random Forest (RF), Neural Network (NN) and Support Vector Machine (SVM) respectively. GLCM features had overall accuracies of 64-86%, 65-88% and 65-86% for RF, NN, and SVM respectively. PCA derived images had similar overall accuracies of 68-92% for NN, RF, and SVM respectively. The PCA images had the highest overall accuracy for the entire time series indicating that reduction in the number of texture features to layers containing the maximum variance improves the accuracy. The standard deviation of soil moisture was noted to increase with increasing soil moisture. Soil texture plays a key role in soil moisture retention. The riparian fields had a high water content explained by the high clay and organic matter content. A roughness parameter was derived and utilized in the retrieval of soil moisture from SAR resulting to R2 of 0.88- 0.92 between observed and simulated soil moisture values from co-polarized RadarSAT-2 HH and TerraSAR-X HH and VV. Merged soil moisture product from FEWSNET Land Data Assimilation System_NOAH (FLDAS_NOAH), ECMWF Re-Analysis Interim (ERA-Interim) and Soil Moisture and Ocean Salinity (SMOS) and FLDAS_Variable Infiltration Capacity (VIC), ERA-Interim and SMOS had similar patterns attributed to FLDAS_NOAH and FLDAS_VIC forced by the same precipitation product (RFE). Cross-correlation of Moderate-resolution Imaging Spectrometer (MODIS) NDVI and the merged soil moisture products revealed a 2-month lag of NDVI. Hence, the relationship is useful in determining the Start of Season from soil moisture products. In conclusion, the successful land cover mapping of the study area demonstrated the use of satellite imagery for wetland characterization. The vast coverage and frequent acquisitions of optical and microwave remotely sensed data additionally make the approaches transferable to other locations and allow for mapping at larger scales. Soil moisture assessment from point data revealed varied soil moisture patterns whereas global remotely sensed and modeled products rather provide complementary information about growing conditions, and hence a situational assessment tool of potential of physical availability dimension of food security. This study forms a baseline upon which additional monitoring and assessment of the Kilombero wetland ecosystem can be performed with the current results marked as a reference. Moreover, the study serves as a demonstration case of remote sensing based approaches for land cover and soil moisture mapping, whose results are useful to stakeholders to aid in the implementation of adapted production techniques for yield optimization while minimizing the unsustainable use of the natural resources.Feuchtgebiete erbringen wichtige ökologische, biologische und sozial-ökonomische Dienstleistungen, welche entscheidend für das menschliche Dasein sind. Der steigende Bedarf an Nahrung, der Mangel an landwirtschaftlichen Nutzflächen und die Veränderung der klimatischen Bedingungen in Ostafrika haben zu einem Paradigmenwechsel vom Anbau im Hochland hin zur Nutzung von Feuchtgebieten geführt. Allerdings sind Kontrolle und Management der Aktivitäten in Feuchtgebieten notwendig, um die nachhaltige Nutzung zu sichern und negative Effekte dieser Aktivitäten zu vermeiden. Die Implementierung erfolgt durch die Landverwalter in den Feuchtgebieten. Den Nutzern von Feuchtgebieten wissenschaftliche Erkenntnisse bereitzustellen dient als Hilfsmittel zur politischen Entscheidungsfindung für die nachhaltige Feuchtgebietsnutzung. Die Forschung im Rahmen der Dissertation beinhaltet zwei Hauptkomponenten: erstens den Bedarf an aktuellen Landbedeckungskarten auf einer angemessenen Skalenebene und zweitens die Erfassung der Bodenfeuchte als wichtiger Einflussfaktor auf die landwirtschaftliche Produktion. Das Ziel der Untersuchung war, Landbedeckungskarten auf Grundlage von multisensorischen optischen Daten zu erstellen und die Eignung der Textur der einfach polarisierten Sentinel-1 Grauwertmatrix (GLCM) sowie der einer Hauptkomponentenanalyse (PCA) bei Anwendung unterschiedlicher Klassifikationsalgorithmen zu beurteilen. Des Weiteren wurden raum-zeitliche Bodenfeuchtemuster über drei hydrologische Zonen hinweg modelliert, die Bodenfeuchte aus Radardaten abgeleitet sowie die Erstellung von Bodenfeuchteprodukten auf Basis von globalen Produkten untersucht. Die Korrelation der Bodenfeuchteprodukte mit dem Normalisierten Differenzierten Vegetationsindex (NDVI) wurde ebenfalls analysiert. RapidEye, Sentinel-2 und Landsat Bilder wurden genutzt um die räumliche Ausdehnung der vier Hauptklassen (Vegetation, freiliegender Boden, Wasser und Bebauung) der Landbedeckung zu ermitteln. Für die Zeitreihenanalyse der der Landbedeckungsdynamik wurden RapidEye-Daten von August 2013 bis Juni 2015, Sentinel-2-Bilder von Dezember 2015 bis August 2016 und Landsat-8-Bilder von 2013 bis 2016 verwendet. Die größte Herausforderung war jedoch die Wolkenbedeckung, weshalb die Anwendung von Synthetic Aperture Radar (SAR) für die Feuchtgebietskartierung getestet wurde. Die gemessene Bodenfeuchte wurde mittels Variogrammen für die drei hydrologischen Zonen (Uferzone, Mitte und Randgebiete) raum-zeitlich interpoliert. Ein Rauhigkeitsparameter wurde aus einem semi-empirischen Modell hergeleitet. Die Bodenfeuchte wurde aus TerraSAR-X und RadarSAT-2- Bildern unter Verwendung des Rauhigkeitsparameters als Eingangsgröße in einer linearen Regression abgeleitet. Vor der Zusammenführung der Produkte wurde das globale Bodenfeuchteprodukt mithilfe von dreifacher Kollokation auf Fehler überprüft. Die Kreuzkorrelation zwischen NDVI und Bodenfeuchte wurde berechnet. Optische Daten (RapidEye, Landsat-8 und Sentinel-2) wurden genutzt, um die zeitliche Dynamik der Landbedeckung zu bestimmen. Die Landbedeckungsverhältnisse wurde mit der Höhe des Grundwasserspiegels korreliert. Ein hoher Grundwasserstand im Juni resultierte in 45-57% unbedecktem Boden, während der Anteil der Vegetation 34-47% betrug. Im Dezember, als der Grundwasserspiegel seinen Tiefststand hatte, erhöhte sich der Anteil des freiliegenden Bodens auf 62-69% und der Anteil der Vegetation verringerte sich auf 27-25%. Das zeigt, dass Grundwasserspiegel und Vegetation saisonalen Schwankungen unterworfen sind. Während der Trockenzeit liegen 68-81% der gesamten als Vegetation klassifizierten Fläche innerhalb der Uferzone. In der Klassifikation der SAR-Bilder liegt die Gesamtgenauigkeit der einfach polarisierten VV-Bilder im Rahmen von 54-76%, 60-81% und 61-80%, entsprechend für Random Forest (RF), Neuronale Netze (NN) und Support Vector Machine (SVM). Die GLCM ergab eine Gesamtgenauigkeit von 64-86%, 65-88% und 65-86% für RF, NN und SVM. Die über eine PCA abgeleiteten Bilder erreichten eine ähnliche Genauigkeit von 68-92% für NN, RF und SVM. Die PCA-Bilder weisen die höchste Gesamtgenauigkeit der gesamten Zeitreihe auf, was darauf hinweist, dass eine Reduktion von Textureigenschaften auf Layer der maximalen Varianz enthalten, die Genauigkeit erhöht. Die Standardabweichung der Bodenfeuchte stieg mit zunehmender Bodenfeuchte. Die Bodentextur spielt dabei eine Schlüsselrolle für das Wasserhaltevermögen des Bodens. Die Uferzone wies einen hohen Wassergehalt auf, was durch den hohen Anteil von Ton und Humus zu erklären ist. Die beobachteten und simulierten Bodenfeuchtewerte von co-polarisierten RadarSAT-2 HH, TerraSAR-X HH und VV Daten korrelieren mit einem R2 von 0.88 - 0.92. Die zusammengesetzten globalen Bodenfeuchteprodukte von FLDAS_NOAH, ERA-Interim sowie SMOS und FLDAS_VIC, ERA-Interim und SMOS zeigen ähnliche Muster wie FLDAS_NOAH und FLDAS_VIC, was über die Verwendung desselben Niederschlagsproduktes (RFE) zu erklären ist. Die Kreuzkorrelation von MODIS NDVI und den zusammengeführten Bodenfeuchteprodukten ergab eine zeitliche Verzögerung des NDVI von zwei Monaten. Dieser Zusammenhang kann daher bei der Bestimmung des Saisonbeginns aus Bodenfeuchtigkeitsprodukten nützlich sein. Zusammengefasst hat die Studie gezeigt, wie Satellitenbilder zur Charakterisierung von Wetlands genutzt werden können. Die große Abdeckung und häufige Aufnahme der optischen und Mikrowellen-Fernerkundungsdaten ermöglichen darüber hinaus die Übertragung der Ansätze auf weitere Gebiete und Kartierung auf größeren Skalen. Die Punktmessungen zeigen kleinräumige Muster der Bodenfeuchte, während globale Fernerkundungsprodukte und Modelle Informationen über die Wachstumsbedingungen liefern und somit ein Bewertungsinstrument der Ernährungssicherheit darstellen können. Weiterhin bildet die Studie eine Basis, auf der ein weitergehendes Monitoring und eine Bewertung des Feuchtgebietsökosystems durchgeführt werden kann. Sie ist ein Beispiel für fernerkundungsbasierte Ansätze zur Landbedeckungs- und Bodenfeuchtekartierung; ihre Ergebnisse sind nützlich, um Akteuren bei der Implementierung von Produktionstechniken zu unterstützen, welche die Erträge maximieren und gleichzeitig die nicht nachhaltige Nutzung der natürlichen Ressourcen minimieren

Novel miniaturised and highly versatile biomechatronic platforms for the characterisation of melanoma cancer cells

There has been an increasing demand to acquire highly sensitive devices that are able to detect and characterize cancer at a single cell level. Despite the moderate progress in this field, the majority of approaches failed to reach cell characterization with optimal sensitivity and specificity. Accordingly, in this study highly sensitive, miniaturized-biomechatronic platforms have been modeled, designed, optimized, microfabricated, and characterized, which can be used to detect and differentiate various stages of melanoma cancer cells. The melanoma cell has been chosen as a legitimate cancer model, where electrophysiological and analytical expression of cell-membrane potential have been derived, and cellular contractile force has been obtained through a correlation with micromechanical deflections of a miniaturized cantilever beam. The main objectives of this study are in fourfold: (1) to quantify cell-membrane potential, (2) correlate cellular biophysics to respective contractile force of a cell in association with various stages of the melanoma disease, (3) examine the morphology of each stage of melanoma, and (4) arrive at a relation that would interrelate stage of the disease, cellular contractile force, and cellular electrophysiology based on conducted in vitro experimental findings. Various well-characterized melanoma cancer cell lines, with varying degrees of genetic complexities have been utilized. In this study, two-miniaturized-versatile-biomechatronic platforms have been developed to extract the electrophysiology of cells, and cellular mechanics (mechanobiology). The former platform consists of a microfluidic module, and stimulating and recording array of electrodes patterned on a glass substrate, forming multi-electrode arrays (MEAs), whereas the latter system consists of a microcantilever-based biosensor with an embedded Wheatstone bridge, and a microfluidic module. Furthermore, in support of this work main objectives, dedicated microelectronics together with customized software have been attained to functionalize, and empower the two-biomechatronic platforms. The bio-mechatronic system performance has been tested throughout a sufficient number of in vitro experiments.Open Acces

Wearable and Nearable Biosensors and Systems for Healthcare

Biosensors and systems in the form of wearables and “nearables” (i.e., everyday sensorized objects with transmitting capabilities such as smartphones) are rapidly evolving for use in healthcare. Unlike conventional approaches, these technologies can enable seamless or on-demand physiological monitoring, anytime and anywhere. Such monitoring can help transform healthcare from the current reactive, one-size-fits-all, hospital-centered approach into a future proactive, personalized, decentralized structure. Wearable and nearable biosensors and systems have been made possible through integrated innovations in sensor design, electronics, data transmission, power management, and signal processing. Although much progress has been made in this field, many open challenges for the scientific community remain, especially for those applications requiring high accuracy. This book contains the 12 papers that constituted a recent Special Issue of Sensors sharing the same title. The aim of the initiative was to provide a collection of state-of-the-art investigations on wearables and nearables, in order to stimulate technological advances and the use of the technology to benefit healthcare. The topics covered by the book offer both depth and breadth pertaining to wearable and nearable technology. They include new biosensors and data transmission techniques, studies on accelerometers, signal processing, and cardiovascular monitoring, clinical applications, and validation of commercial devices

Wetland mapping and monitoring using polarimetric and interferometric synthetic aperture radar (SAR) data and tools

Wetlands are home to a great variety of flora and fauna species and provide several unique environmental functions, such as controlling floods, improving water-quality, supporting wildlife habitat, and shoreline stabilization. Detailed information on spatial distribution of wetland classes is crucial for sustainable management and resource assessment. Furthermore, hydrological monitoring of wetlands is also important for maintaining and preserving the habitat of various plant and animal species. This thesis investigates the existing knowledge and technological challenges associated with wetland mapping and monitoring and evaluates the limitations of the methodologies that have been developed to date. The study also proposes new methods to improve the characterization of these productive ecosystems using advanced remote sensing (RS) tools and data. Specifically, a comprehensive literature review on wetland monitoring using Synthetic Aperture Radar (SAR) and Interferometric SAR (InSAR) techniques is provided. The application of the InSAR technique for wetland mapping provides the following advantages: (i) the high sensitivity of interferometric coherence to land cover changes is taken into account and (ii) the exploitation of interferometric coherence for wetland classification further enhances the discrimination between similar wetland classes. A statistical analysis of the interferometric coherence and SAR backscattering variation of Canadian wetlands, which are ignored in the literature, is carried out using multi-temporal, multi-frequency, and multi-polarization SAR data. The study also examines the capability of compact polarimetry (CP) SAR data, which will be collected by the upcoming RADARSAT Constellation Mission (RCM) and will constitute the main source of SAR observation in Canada, for wetland mapping. The research in this dissertation proposes a methodology for wetland classification using the synergistic use of intensity, polarimetry, and interferometry features using a novel classification framework. Finally, this work introduces a novel model based on the deep convolutional neural network (CNN) for wetland classification that can be trained in an end-to-end scheme and is specifically designed for the classification of wetland complexes using polarimetric SAR (PolSAR) imagery. The results of the proposed methods are promising and will significantly contribute to the ongoing efforts of conservation strategies for wetlands and monitoring changes. The approaches presented in this thesis serve as frameworks, progressing towards an operational methodology for mapping wetland complexes in Canada, as well as other wetlands worldwide with similar ecological characteristics

Molecular Dynamics Simulation

Condensed matter systems, ranging from simple fluids and solids to complex multicomponent materials and even biological matter, are governed by well understood laws of physics, within the formal theoretical framework of quantum theory and statistical mechanics. On the relevant scales of length and time, the appropriate ‘first-principles’ description needs only the Schroedinger equation together with Gibbs averaging over the relevant statistical ensemble. However, this program cannot be carried out straightforwardly—dealing with electron correlations is still a challenge for the methods of quantum chemistry. Similarly, standard statistical mechanics makes precise explicit statements only on the properties of systems for which the many-body problem can be effectively reduced to one of independent particles or quasi-particles. [...

Forest attributes mapping with SAR data in the romanian South-Eastern Carpathians requirements and outcomes

Esta tesis doctoral se centra en la estimación de variables forestales en la zona Sureste de los Cárpatos Rumanos a partir de imágenes de radar de apertura sintética. La investigación abarca parte del preprocesado de las imágenes, métodos de generación de mosaicos y la extracción de la cobertura de bosque, sus subtipos o su biomasa. La tesis se desarrolló en el Instituto Nacional de Investigación y Desarrollo Forestal Marín Dracea (INCDS) y la Universidad de Alcalá (UAH) gracias a varios proyectos: el proyecto EO-ROFORMON del INCDS (Prototyping an Earth-Observation based monitoring and forecasting system for the Romanian forests), y el proyecto EMAFOR de la UAH (Synthetic Aperture Radar (SAR) enabled Analysis Ready Data (ARD) cubes for efficient monitoring of agricultural and forested landscapes). El proyecto EO-ROFORMON fue financiado por la Autoridad Nacional para la Investigación Científica de Rumania y el Fondo Europeo de Desarrollo Regional. El proyecto EMAFOR fue financiado por la Comunidad Autónoma de Madrid (España). El objetivo de esta tesis es el desarrollo de algoritmos para la extracción de variables forestales de uso general como la cobertura, el tipo o la biomasa del bosque a partir de imagen de radar de apertura sintética. Para alcanzar dicho propósito se analizaron posibles fuentes de sesgo sistemático que podrían aparecer en zonas de montaña (ej., normalización topográfica, generación de mosaicos), y se aplicaron técnicas de aprendizaje de máquina para tareas de clasificación y regresión. La tesis contiene ocho secciones: una introducción, cinco publicaciones en revistas o actas de congresos indexados, una pendiente de publicación (quinto capítulo) y las conclusiones. La introducción contextualiza la importancia del bosque, cómo se recoge la información sobre su estado (ej., inventario forestal) y las iniciativas o marcos legislativos que requieren dicha información. A continuación, se describe cómo la teledetección puede complementar la información de inventario forestal, detallando el contexto histórico de las distintas tecnologías, su funcionamiento, y cómo pueden ser aplicadas para la extracción de información forestal. Por último, se describe la problemática y el monitoreo del bosque en Rumanía, detallando el objetivo de la tesis y su estructura. El primer capítulo analiza la influencia del modelo digital de elevaciones (MDE) en la calidad de la normalización topográfica, analizando tres MDE globales (SRTM, AW3D y TanDEM-X DEM) y uno nacional (PNOA-LiDAR). Los experimentos se basan en la comparación entre órbitas, con un MDE de referencia, y la variación del acierto en la clasificación dependiendo del MDE empleado para la normalización. Los resultados muestran una menor diferencia ente órbitas al utilizar un MDE con una mejor resolución (ej. TanDEM-X, PNOA-LIDAR), especialmente en el caso de zonas con fuertes pendientes o formas del terreno complejas, como pueden ser los valles. En zonas de alta montaña las imágenes de radar de apertura sintética (SAR) sufren frecuentes distorsiones. Estas distorsiones dependen de la geometría de adquisición, por lo que es posible combinar imágenes adquiridas desde varias órbitas para que la cobertura sea lo más completa posible. El segundo capítulo evalúa dos metodologías para la clasificación de usos del suelo utilizando datos de Sentinel-1 adquiridos desde varias órbitas. El primer método crea clasificaciones por órbita y las combina, mientras que el segundo genera un mosaico con datos de múltiples órbitas y lo clasifica. El acierto obtenido mediante combinación de clasificaciones es ligeramente mayor, mientras que la clasificación de mosaicos tiene importantes omisiones de las zonas boscosas debido a problemas en la normalización topográfica y a los efectos direccionales. El tercer capítulo se enfoca en separar la cobertura forestal de otras coberturas del suelo (urbano, vegetación baja, agua) analizando la utilidad de las variables basadas en la coherencia interferométrica. En él se realizan tres clasificaciones de máquina vector-soporte basadas en un conjunto concreto de variables. El primer conjunto contiene las estadísticas anuales de la retrodispersión (media y desviación típica anual), el segundo añade la coherencia a largo plazo (separación temporal mayor a un año), el tercero incluye las estadísticas de la coherencia a corto plazo (mínima separación temporal). Utilizar variables basadas en la coherencia aumenta el acierto de la clasificación hasta un 5% y reduce los errores de omisión de la cobertura forestal. El cuarto capítulo evalúa la posibilidad de detectar talas selectivas utilizando datos de Sentinel-1 y Sentinel-2. Sus resultados muestran que la detección resulta muy difícil debido a la saturación de los sensores y la confusión introducida por el efecto de la fenología. El quinto capítulo se centra en la clasificación de tipos de bosque basado en una serie temporal de datos Sentinel-1. Se basa en la creación de un conjunto de modelos que describen la relación entre la retrodispersión y el ángulo local de incidencia para un determinado tipo de bosque y fecha concreta. Para cada píxel se calcula el residuo respecto al modelo de cada uno de los tipos de bosque, acumulando dichos residuos a lo largo de la serie temporal. Hecho esto, cada píxel es asignado al tipo de bosque que acumula un menor residuo. Los resultados son prometedores, mostrando que frondosas y coníferas tienen un comportamiento distintivo, y que es posible separar ambos tipos de bosque con un alto grado de acierto. El sexto capítulo está dedicado a la estimación de biomasa utilizando datos Sentinel-1, ALOS PALSAR y regresión Random Forest. Se obtiene un error similar para ambos sensores a pesar de utilizar una banda diferente (band-C vs. -L), con poca reducción en el error cuando ambas bandas se utilizan conjuntamente. Sin embargo, el ajuste de un estimador adaptado a las condiciones locales de Rumanía sí ofreció una reducción de del error al ser comparado con las estimaciones globales de biomasa

Optical Properties of Strongly Correlated Transition Metal Oxides

The strong electron interactions in transition metal oxides offer wide-ranging phenomena of interest to condensed matter physics and potential applications in novel electronic devices. This thesis focuses on optical studies performed on three such systems: colossal magnetoresistant (CMR) manganites, multiferroic LuMnO<sub>3</sub>, and dilute magnetic oxide (DMO) cobalt-doped TiO<sub>2</sub>. Optical measurements, using a variety of techniques, of thin film and bulk samples extend over a range of frequencies (0.002-5 eV) and temperatures (4-350 K) and determine the optical constants. Optical properties provide important insights into the electronic structure of these exciting systems and illustrate the value of optical measurements as a probe of novel materials. The pseudocubic manganites exhibit a rich phase diagram that includes, in addition to CMR, various types of magnetic, charge, and orbitally ordered phases. For the CMR manganites, the optical spectra and oscillator strength changes compare with models that require both double exchange and the dynamic Jahn-Teller effect in the description of the electronic structure. In the ferromagnetic state, results on the electronic scattering rate and mass enhancement refute the claims of an anomalously small Drude weight in these materials. Smaller rare-earth ions in the manganites (<i>e.g.</i>, Lu) result in crystallization into a hexagonal structure and a multiferroic ground state, in which ferroelectricity and antiferromagnetism occur simultaneously. A symmetry-allowed on-site Mn <i>d-d</i> optical transition blueshifts in the antiferromagnetic state resulting from Mn-Mn superexchange. TO phonon frequencies exhibit similar temperature dependent shifts arising from spin-phonon interactions. Further, these phonons dominantly contribute to the known anomaly below <i>T<sub>N</sub></i> of the quasi-static dielectric constant. Cobalt-doped TiO<sub>2</sub> has received recent attention as a new DMO displaying room temperature ferromagnetism. Optical conductivity of low-doped samples reveals an absence of absorption below an onset of interband transitions at 3.6 eV and a blue shift of the band edge with doping. The absence of below band gap absorption remains inconsistent with band calculations and suggests that strong on-site Coulomb interactions shift the optical transitions to energies above the gap