Contactless 3D surface characterization of additive manufactured metallic components using terahertz time-domain spectroscopy

Terahertz time-domain spectroscopy has experienced significant progress in imaging, spectroscopy, and quality inspection, e.g., for semiconductor packaging or the automotive industry. Additive manufacturing alloys (also known as alloys for use in 3D printing) have risen in popularity in aerospace and biomedical industries due to the ability to fabricate intricate designs and shapes with high precision using materials with customized mechanical properties. However, these 3D-printed elements need to be polished thereafter, where the surface roughness is inspected using techniques such as the laser scanning microscope. In this study, we demonstrate the use of terahertz time-domain spectroscopy to assess the average roughness profile and height leveling of stainless steel for comparisons against the same parameters acquired using laser scanning microscopy. Our results highlight the potential of the proposed technique to rapidly inspect 3D-printed alloys over large areas, thus providing an attractive modality for assessing surface profiles of AM-manufactured terahertz components in the future

Quality Mapping of Offset Lithographic Printed Antenna Substrates and Electrodes by Millimeter-Wave Imaging

Offset lithographic printed flexible antenna substrate boards and electrodes have attracted much attention recently due to the boost of flexible electronics. Unmanned quality inspection of these printed substrate boards and electrodes demands high-speed, large-scale and nondestructive methods, which is highly desired for manufacturing industries. The work here demonstrates two kinds of millimeter (mm)-wave imaging technologies for the quality (surface uniformity and functionality parameters) inspection of printed silver substrates and electrodes on paper and thin polyethylene film, respectively. One technology is a mm-wave line scanner system and the other is a terahertz-time domain spectroscopy-based charge-coupled device (CCD) imaging system. The former shows the ability of detecting transmitted mm-wave amplitude signals only; its detection is fast in a second time scale and the system shows great potential for the inspection of large-area printed surface uniformity. The latter technology achieves high spatial resolution images of up to hundreds of micrometers at the cost of increased inspection time, in a time scale of tens of seconds. With the exception of absorption rate information, the latter technology offers additional phase information, which can be used to work out 2D permittivity distribution. Moreover, its uniformity is vital for the antenna performance. Additionally, the results demonstrate that compression rolling treatment significantly improves the uniformity of printed silver surfaces and enhances the substrate’s permittivity values

Imaging Cultural Heritage at Different Scales: Part I, the Micro-Scale (Manufacts)

Applications of non-invasive sensing techniques to investigate the internal structure and surface of precious and delicate objects represent a very important and consolidated research field in the scientific domain of cultural heritage knowledge and conservation. The present article is the first of three reviews focused on contact and non-contact imaging techniques applied to surveying cultural heritage at micro- (i.e., manufacts), meso- (sites) and macro-scales (landscapes). The capability to infer variations in geometrical and physical properties across the inspected surfaces or volumes is the unifying factor of these techniques, allowing scientists to discover new historical sites or to image their spatial extent and material features at different scales, from landscape to artifact. This first part concentrates on the micro-scale, i.e., inspection, study and characterization of small objects (ancient papers, paintings, statues, archaeological findings, architectural elements, etc.) from surface to internal properties

Thermoreflectance for Contactless Sintering Characterization: From Metal Nanoparticles to Stretchable Conductors

Sintering metal nanoparticles is a crucial step to achieve printed conductors. It is important to characterize and monitor nanoparticle sintering for process optimization and control. Here, we demonstrate that frequency-domain thermoreflectance (FDTR), an optical pump-probe technique, can be used for non-contact, non-destructive process monitoring that is compatible with high-throughput printed electronics manufacturing, unlike traditional electrical resistance measurements. The thermal conductivity measured from FDTR agrees well with thermal conductivity calculated using Wiedemann-Franz law from electrical conductivity measurements. Measurement time is reduced to 12 s by choosing a small number of measurement frequencies instead of a full frequency sweep and measuring them simultaneously. A Monte Carlo simulation was performed to predict the possibility of further reducing measurement time. Understanding of the sintering process allows tailoring of materials properties as demonstrated here to create a novel stretchable conductor. Differently sintered layers are combined to achieve a desirable stretchability-conductivity profile

The 2023 terahertz science and technology roadmap

Terahertz (THz) radiation encompasses a wide spectral range within the electromagnetic spectrum that extends from microwaves to the far infrared (100 GHz–∼30 THz). Within its frequency boundaries exist a broad variety of scientific disciplines that have presented, and continue to present, technical challenges to researchers. During the past 50 years, for instance, the demands of the scientific community have substantially evolved and with a need for advanced instrumentation to support radio astronomy, Earth observation, weather forecasting, security imaging, telecommunications, non-destructive device testing and much more. Furthermore, applications have required an emergence of technology from the laboratory environment to production-scale supply and in-the-field deployments ranging from harsh ground-based locations to deep space. In addressing these requirements, the research and development community has advanced related technology and bridged the transition between electronics and photonics that high frequency operation demands. The multidisciplinary nature of THz work was our stimulus for creating the 2017 THz Science and Technology Roadmap (Dhillon et al 2017 J. Phys. D: Appl. Phys. 50 043001). As one might envisage, though, there remains much to explore both scientifically and technically and the field has continued to develop and expand rapidly. It is timely, therefore, to revise our previous roadmap and in this 2023 version we both provide an update on key developments in established technical areas that have important scientific and public benefit, and highlight new and emerging areas that show particular promise. The developments that we describe thus span from fundamental scientific research, such as THz astronomy and the emergent area of THz quantum optics, to highly applied and commercially and societally impactful subjects that include 6G THz communications, medical imaging, and climate monitoring and prediction. Our Roadmap vision draws upon the expertise and perspective of multiple international specialists that together provide an overview of past developments and the likely challenges facing the field of THz science and technology in future decades. The document is written in a form that is accessible to policy makers who wish to gain an overview of the current state of the THz art, and for the non-specialist and curious who wish to understand available technology and challenges. A such, our experts deliver a 'snapshot' introduction to the current status of the field and provide suggestions for exciting future technical development directions. Ultimately, we intend the Roadmap to portray the advantages and benefits of the THz domain and to stimulate further exploration of the field in support of scientific research and commercial realisation

Imaging cultural heritage at different scales : part I, the micro-scale (manufacts)

Applications of non-invasive sensing techniques to investigate the internal structure and surface of precious and delicate objects represent a very important and consolidated research field in the scientific domain of cultural heritage knowledge and conservation. The present article is the first of three reviews focused on contact and non-contact imaging techniques applied to surveying cultural heritage at micro- (i.e., manufacts), meso- (sites) and macro-scales (landscapes). The capability to infer variations in geometrical and physical properties across the inspected surfaces or volumes is the unifying factor of these techniques, allowing scientists to discover new historical sites or to image their spatial extent and material features at different scales, from landscape to artifact. This first part concentrates on the micro-scale, i.e., inspection, study and characterization of small objects (ancient papers, paintings, statues, archaeological findings, architectural elements, etc.) from surface to internal properties.peer-reviewe

The 2022 magneto-optics roadmap

Magneto-optical (MO) effects, viz. magnetically induced changes in light intensity or polarization upon reflection from or transmission through a magnetic sample, were discovered over a century and a half ago. Initially they played a crucially relevant role in unveiling the fundamentals of electromagnetism and quantum mechanics. A more broad-based relevance and wide-spread use of MO methods, however, remained quite limited until the 1960s due to a lack of suitable, reliable and easy-to-operate light sources. The advent of Laser technology and the availability of other novel light sources led to an enormous expansion of MO measurement techniques and applications that continues to this day (see section 1). The here-assembled roadmap article is intended to provide a meaningful survey over many of the most relevant recent developments, advances, and emerging research directions in a rather condensed form, so that readers can easily access a significant overview about this very dynamic research field. While light source technology and other experimental developments were crucial in the establishment of today's magneto-optics, progress also relies on an ever-increasing theoretical understanding of MO effects from a quantum mechanical perspective (see section 2), as well as using electromagnetic theory and modelling approaches (see section 3) to enable quantitatively reliable predictions for ever more complex materials, metamaterials, and device geometries. The latest advances in established MO methodologies and especially the utilization of the MO Kerr effect (MOKE) are presented in sections 4 (MOKE spectroscopy), 5 (higher order MOKE effects), 6 (MOKE microscopy), 8 (high sensitivity MOKE), 9 (generalized MO ellipsometry), and 20 (Cotton–Mouton effect in two-dimensional materials). In addition, MO effects are now being investigated and utilized in spectral ranges, to which they originally seemed completely foreign, as those of synchrotron radiation x-rays (see section 14 on three-dimensional magnetic characterization and section 16 on light beams carrying orbital angular momentum) and, very recently, the terahertz (THz) regime (see section 18 on THz MOKE and section 19 on THz ellipsometry for electron paramagnetic resonance detection). Magneto-optics also demonstrates its strength in a unique way when combined with femtosecond laser pulses (see section 10 on ultrafast MOKE and section 15 on magneto-optics using x-ray free electron lasers), facilitating the very active field of time-resolved MO spectroscopy that enables investigations of phenomena like spin relaxation of non-equilibrium photoexcited carriers, transient modifications of ferromagnetic order, and photo-induced dynamic phase transitions, to name a few. Recent progress in nanoscience and nanotechnology, which is intimately linked to the achieved impressive ability to reliably fabricate materials and functional structures at the nanoscale, now enables the exploitation of strongly enhanced MO effects induced by light–matter interaction at the nanoscale (see section 12 on magnetoplasmonics and section 13 on MO metasurfaces). MO effects are also at the very heart of powerful magnetic characterization techniques like Brillouin light scattering and time-resolved pump-probe measurements for the study of spin waves (see section 7), their interactions with acoustic waves (see section 11), and ultra-sensitive magnetic field sensing applications based on nitrogen-vacancy centres in diamond (see section 17). Despite our best attempt to represent the field of magneto-optics accurately and do justice to all its novel developments and its diversity, the research area is so extensive and active that there remains great latitude in deciding what to include in an article of this sort, which in turn means that some areas might not be adequately represented here. However, we feel that the 20 sections that form this 2022 magneto-optics roadmap article, each written by experts in the field and addressing a specific subject on only two pages, provide an accurate snapshot of where this research field stands today. Correspondingly, it should act as a valuable reference point and guideline for emerging research directions in modern magneto-optics, as well as illustrate the directions this research field might take in the foreseeable future

Sensing water accumulation and transport in proton exchange membrane fuel cells with terahertz radiation

Fuel cells are like batteries in the sense that they are electrochemical cells whose main components are two electrodes (anode and cathode) and an electrolyte material. They differ from most batteries as they require a continuous stream of fuel and oxidant, generating electricity and heat for as long as these are supplied. Perfluorinated sulfonic-acid ionomers such as Nafion are the most common proton exchange membrane material (solid electrolyte) whose structure underpins its unique water and chemical/mechanical stability properties. Pure hydrogen and air are typically used as the fuel and oxidant, respectively, and by-products are water and waste heat. Due to their high efficiency, low temperature operation and capacity to quickly vary their output to meet shifting demands, these fuel cells are attractive to the automobile industry, although they can also be used for stationary power production. Water management is a prominent issue in proton exchange membrane fuel cell technology. Strategies in this topic must maintain a delicate balance between adequate hydration levels in the Nafion proton electrolyte membrane to maximise proton conductivity, and minimal flooding, which hinders mass transport to active sites. The complex nature of water transport in these fuel cells can be investigated via in situ or ex situ diagnostics with visualisation techniques such as neutron imaging or optical diagnostics. Despite the wealth of information provided by these techniques, they suffer from issues such as limited availability, excessive cost, limited sensitivity, and penetration depth. Terahertz radiation has been growing in popularity for contactless and non-destructive testing across various industrial sectors, including pharmaceutical coating analysis, defect identification, and gas pipeline monitoring. The ability of terahertz waves to penetrate through dielectric materials such as plastics or ceramics combined with strong attenuation by liquid water provides the necessary contrast to image water presence in proton exchange membrane fuel cells and their components. Motivated by the recent commercial availability of a compact terahertz source and video-rate terahertz camera, a simple terahertz imaging system in transmission geometry was realised. First, as a first step towards flooding inspection in an operating fuel cell, the feasibility of the imaging system for visualising and quantifying liquid water during an ambient air desorption process for Nafion membranes of a wide range of thicknesses – NRE-212 (50 µm), N-115 (127µm), N-117 (180 µm) and N-1110 (254 µm) was investigated. It was demonstrated that the imaging system was able to quantify liquid water in the 25-500 µm thickness range, estimate membrane weight change related to liquid water desorption, which correlated well against simultaneous gravimetric analysis and visualise the room temperature liquid water desorption process of a partially hydrated Nafion N-117 membrane. Further work consisted in imaging water build-up inside an operating proton exchange membrane fuel cell using the terahertz imaging system, combined with high-resolution optical imaging. Using a custom-built, laboratory-scale, terahertz, and optically transparent fuel cell, two-phase flow phenomena of water accumulation and transport, such as membrane hydration, main droplet occurrence, water pool formation, growth, and eventual flush out by gases were imaged. Results of the terahertz agree with simultaneous optical imaging and electrochemical readings. To demonstrate the potential used of the proposed imaging modality, the effect of air gas flow rates on flooding was demonstrated

Fundamentals and Recent Advances in Epitaxial Graphene on SiC

This book is a compilation of recent studies by recognized experts in the field of epitaxial graphene working towards a deep comprehension of growth mechanisms, property engineering, and device processing. The results of investigations published within this book develop cumulative knowledge on matters related to device-quality epaxial graphene on SiC, bringing this material closer to realistic applications