Assessment of plastics in the National Trust: a case study at Mr Straw's House

The National Trust is a charity that cares for over 300 publically accessible historic buildings and their contents across England, Wales and Northern Ireland. There have been few previous studies on preservation of plastics within National Trust collections, which form a significant part of the more modern collections of objects. This paper describes the design of an assessment system which was successfully trialled at Mr Straws House, a National Trust property in Worksop, UK. This system can now be used for future plastic surveys at other National Trust properties. In addition, the survey gave valuable information about the state of the collection, demonstrating that the plastics that are deteriorating are those that are known to be vulnerable, namely cellulose nitrate/acetate, PVC and rubber. Verifying this knowledge of the most vulnerable plastics enables us to recommend to properties across National Trust that these types should be seen as a priority for correct storage and in-depth recording

LED Selection for Spectral (Multispectral) Imaging

Research was performed to design an LED-based spectral imaging system having channels, commonly referred to as a multispectral imaging system. The first part tackled the evaluation of a camera model in predicting the signals of a 10 LED LEDmotive Technologies Spectra Tunelab coupled with a Finger Lakes Instrumentation panchromatic camera. The camera model was shown to be valid and effective in predicting the camera signal taking into account the color transformation noise. The second part involved the computational selection of 10 LEDs in order to determine the optimum combination for a custom Spectra Tunelab. The computational selection used the spectral data provided by the manufacturer for their 37 available LEDs. The LEDs were grouped according to a specified wavelength range. The binning process helped in decreasing the computational cost and time; the possible combinations were reduced to 110,592 from the initial calculated value of 348,330,136 possible combinations. The combinations were further reduced to 1000 according to spectral reflectance Root-Mean-Square-Error (RMSE). The Euclidean and score ranking methods were then used to evaluate color transformation noise, spectral error and colorimetric accuracy. Goodness of Fit Coefficient and Throughput were calculated as well to further evaluate the combinations. A compromise among the values were reached to identify the best possible LED combination. The optimal combination has peak wavelengths at 390 nm, 450 nm, 475 nm, 505 nm, 540 nm, 550 nm, 590 nm, 620 nm, 660 nm, and 745 nm. All the LEDs were narrow band except the LED with its peak wavelength at 550 nm. This particular LED was similar to the human visual system’s luminous efficiency function. Its inclusion was important for colorimetric accuracy and small color transformation noise. When evaluating a large color-gamut target made using commonly used commercial pigments and several artist pigments, the following quality metrics were achieved: average ∆E00 of 0.12, total Noise, N of 3.35, a lightness noise (∆L) of 1.22, spectral reflectance RMSE of 6.4 x10-3, GFC of 0.97 and a total throughput of 646.85

Aiding the conservation of two wooden Buddhist sculptures with 3D imaging and spectroscopic techniques

The conservation of Buddhist sculptures that were transferred to Europe at some point during their lifetime raises numerous questions: while these objects historically served a religious, devotional purpose, many of them currently belong to museums or private collections, where they are detached from their original context and often adapted to western taste. A scientific study was carried out to address questions from Museo d'Arte Orientale of Turin curators in terms of whether these artifacts might be forgeries or replicas, and how they may have transformed over time. Several analytical techniques were used for materials identification and to study the production technique, ultimately aiming to discriminate the original materials from those added within later interventions

TECHNART 2017. Non-destructive and microanalytical techniques in art and cultural heritage. Book of abstracts

440 p.TECHNART2017 is the international biannual congress on the application of Analytical Techniques in Art and Cultural Heritage. The aim of this European conference is to provide a scientific forum to present and promote the use of analytical spectroscopic techniques in cultural heritage on a worldwide scale to stimulate contacts and exchange experiences, making a bridge between science and art. This conference builds on the momentum of the previous TECHNART editions of Lisbon, Athens, Berlin, Amsterdam and Catania, offering an outstanding and unique opportunity for exchanging knowledge on leading edge developments. Cultural heritage studies are interpreted in a broad sense, including pigments, stones, metal, glass, ceramics, chemometrics on artwork studies, resins, fibers, forensic applications in art, history, archaeology and conservation science. The meeting is focused in different aspects: - X-ray analysis (XRF, PIXE, XRD, SEM-EDX). - Confocal X-ray microscopy (3D Micro-XRF, 3D Micro-PIXE). - Synchrotron, ion beam and neutron based techniques/instrumentation. - FT-IR and Raman spectroscopy. - UV-Vis and NIR absorption/reflectance and fluorescence. - Laser-based analytical techniques (LIBS, etc.). - Magnetic resonance techniques. - Chromatography (GC, HPLC) and mass spectrometry. - Optical imaging and coherence techniques. - Mobile spectrometry and remote sensing

X-ray fluorescence applied to yellow pigments based on lead, tin and antimony: comparison of laboratory and portable instrumentation

X-ray fluorescence is a diagnostic approach particularly suited to be utilized in cultural heritage sector since it falls in the non-destructive and non-invasive analytical tools. However there are big differences between portable and laboratory instrumentation that make difficult to perform a comparison in terms of quality and reliability of the results. The present study is specifically addressed to investigate these differences in respect of the same analytical sample-set. To reach this goal a comparison was thus carried out between portable and bench top devices X-ray fluorescence devices and techniques were used on different type of yellow pigments based on lead, tin and antimony obtained in laboratory, reproducing the instructions described in “old” recipes, that is: i) mortar of lead and tin produced on the basis of the recipe 13 /c V of the “Manuscript of Danzica” and “ Li tre libri dell’arte del Vasaio” by Cipriano Piccolpasso; ii) two types of lead and tin yellow (Pb2SnO4 and PbSnO3) produced starting from the indications of the 272 and 273 recipes of the “Bolognese Manuscript”; iii) lead antimonate (Pb2Sb2O7) obtained by following the instructions of the Piccolpasso’s treatise and those contained on the “Istoria delle pitture in maiolica fatte in Pesaro e ne’ luoghi circonvicini di Giambattista Passeri” and finally iv) lead, tin and antimony yellow (Pb2SnSbO6,5) obtained starting from the information contained in the paper 30 R of “Manuscript of Danzica” [1]. The XRF analysis were performed using a laboratory instrumentation (Bruker M4 Tornado) and a handset analytical device (Assing Surface Monitor). In order to perform a significant statistical comparison among acquired and processed data, all the analyses have been carried out utilizing the same sample, the same acquisition set up and operative conditions. A chemometric approach, based on the utilization of Principal Component Analysis (PCA) and multivariate analytical based tools [2], was utilized in order to verify the spectral differences, and related informative content, among the different produced yellow pigments. The multivariate approach on the results revealed instrumental differences between the two systems and allowed to compare the common characteristics of the set of pigments analyzed

Electronic Imaging & the Visual Arts. EVA 2012 Florence

The key aim of this Event is to provide a forum for the user, supplier and scientific research communities to meet and exchange experiences, ideas and plans in the wide area of Culture & Technology. Participants receive up to date news on new EC and international arts computing & telecommunications initiatives as well as on Projects in the visual arts field, in archaeology and history. Working Groups and new Projects are promoted. Scientific and technical demonstrations are presented

A framework for surface metrology on Cultural Heritage objects based on scanning conoscopic holography

L'applicazione della metrologia di superficie e dell'analisi dimensionale allo studio dei beni culturali può rivelare importanti informazioni sull'oggetto e favorire l'integrazione di molteplici tecniche diagnostiche. Tuttavia, l'applicazione di queste discipline ai Beni Culturali richiede particolari requisiti e attenzioni. In questa tesi, presento i risultati dell'implementazione di diversi sistemi di misurazione della superficie basati sul principio della conoscopia olografica. I senori conoscopici sono strumenti capaci di misurare distanze con precisione micrometrica a scale diverse, accoppiati a slitte micrometriche possono essere utilizzati per acquisire scansioni areali dell'oggetto in esame. Per facilitare la loro applicazione alle opere d'arte ho sviluppato un extit{framework} per applicare la metrologia di superficie ai beni culturali. Il framework copre diversi aspetti del processo di analisi ed utilizzo dei dati e comprende la creazione di raccolte di campioni, le strategie per la scansione dell'oggetto, l'archiviazione e l'analisi dei dati ed eventualmente l'incertezza legata alla misura. Il extit{framework} mira a rendere più accessibile l'implementazione della metrologia di superficie e dei sistemi di scansione dell'analisi dimensionale per l'analisi dei beni culturali. I risultati raccolti su una varietà di materiali artistici (metalli, dipinti su tavola, tela, carta, pergamena e dipinti murali) mostrano come questi sistemi possano essere utilizzati per monitorare gli effetti delle procedure di pulitura, la stabilità dimensionale delle opere d'arte ed il loro invecchiamento.The application of surface metrology and dimensional analysis to the study of artworks can reveal important information on the object and aid the integration of multiple techniques. However, the application of these disciplines to Cultural Heritage objects necessitates particular care and requirements. In this dissertation, I present the results of the implementation of different systems, based on Conoscopic Holography range finders, for measuring the surface. Conoscopic holography range finders are viable instruments for measuring distances with micrometer accuracy at different scales, coupled with micrometric stages they can be used for acquiring areal scans of the object under investigation. To ease their application to artworks I built a framework for applying surface metrology to Cultural Heritage objects. The framework covers different aspects of the research workflow comprising the creation of samples collections, the strategies for scanning the object, the storing and the analysis of the data and eventually the uncertainty linked to the measurement. This framework aims to make more accessible the implementation of surface metrology and dimensional analysis scanning systems tailored to the analysis of Cultural Heritage objects. The results collected on a variety of artworks materials (metals, panels painting, canvas, paper, parchment and mural paintings) show how these systems can be used for monitoring the effects of cleaning procedures, the dimensional stability of the artworks and their ageing

5th International Conference. Youth in Conservation of Cultural Heritage YOCOCU. Book of abstracts.

Depto. de Mineralogía y PetrologíaFac. de Ciencias GeológicasTRUEYouth in Conservation of Cultural Heritage - YOCOCU EspañaMuseo Centro de Arte Reina Sofía MNCARSFundación Reina Sofíapu