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Activation energy in particle suspensions
Assuming that the molar activation energy in a fluid is interpreted as a measure of the potential energy barrier required for the molecular movement [1], the viscosity of a fluid depends on the actual size of the molecules, and the presence of solid particles in a suspension increases the dissipation of energy when the system flows, therefore it is expected that the viscosity of the suspension is higher than that of the pure solvent at a given temperature. The dependence of the viscosity of some silica/glycol suspensions with the temperature can be fitted using an empirical function analogous to the Arrhenius equation, lnη=E/RT-lnC, where η is the viscosity, C is a system-dependent constant, E is the molar activation energy for the viscous flow, T is the absolute temperature and R is the gas universal constant. When the temperature of the suspension decreases two effects are observed. First, larger aggregates of particles are formed due to the reduction of the thermal agitation and, second, the number of links among the molecules of the liquid phase increases. These two effects give place to a higher increase in the viscosity with the temperature compared to the pure solvent. Assuming that a higher viscosity value is due to a smaller free volume available for the molecular movement, and taking into account that the free suspension volume is limited only to the liquid fraction [2], it should be expected that the viscosity of the suspension is less sensitive to temperature than that of the pure solvent.
In this work the dependence on the temperature of the viscosity values of the silica/glycol suspensions is compared to that of the liquid media. The results have shown a lower activation energy when the solid volume fraction increases, which has been explained with a scheme that assumes that the particle links are less sensitive to thermal energy absorption than the joining bonds among the solvent molecules. Our conclusion is that, for a given mechanical energy applied to the system, the thermal energy absorbed by the system is mainly used in the rupture of bonds between the solvent molecules. This study can be useful to understand the mechanisms that govern the differences in the activation energy values found between samples of foods, in which many factors are connected with sample composition [3].
[1] Briscoe B, Luckham P, Zhu S. Rheological properties of poly (ethylene oxide) aqueous solutions. J Appl Polym Sci 70 (1998) 419-429.
[2] Shenoy AV. Rheology of filled polymer systems. Kluwer Acad Pub, 1999, The Netherlands.
[3] Alvarez MD, Canet W. Time-independent and time-dependent rheological characterization of vegetable-based infant purees. J Food Eng 114 (2013) 449-464.Universidad de Málaga, Campus de Excelencia Internacional Andalucía Tech
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Ampk regulates IgD expression but not energy stress with B cell activation.
Ampk is an energy gatekeeper that responds to decreases in ATP by inhibiting energy-consuming anabolic processes and promoting energy-generating catabolic processes. Recently, we showed that Lkb1, an understudied kinase in B lymphocytes and a major upstream kinase for Ampk, had critical and unexpected roles in activating naïve B cells and in germinal center formation. Therefore, we examined whether Lkb1 activities during B cell activation depend on Ampk and report surprising Ampk activation with in vitro B cell stimulation in the absence of energy stress, coupled to rapid biomass accumulation. Despite Ampk activation and a controlling role for Lkb1 in B cell activation, Ampk knockout did not significantly affect B cell activation, differentiation, nutrient dynamics, gene expression, or humoral immune responses. Instead, Ampk loss specifically repressed the transcriptional expression of IgD and its regulator, Zfp318. Results also reveal that early activation of Ampk by phenformin treatment impairs germinal center formation but does not significantly alter antibody responses. Combined, the data show an unexpectedly specific role for Ampk in the regulation of IgD expression during B cell activation
A phase transition in a system driven by coloured noise
For a system driven by coloured noise, we investigate the activation energy of escape, and the dynamics during the escape. We have performed analogue experiments to measure the change in activation energy as the power spectrum of the noise varies. An adiabatic approach based on path integral theory allows us to calculate analytically the critical value at which a phase transition in the activation energy occurs
Analytic Expression for Magnetic Activation Energy
We theoretically investigate the magnetic activation energy of permanent
magnets. Practically, it is widely used in a phenomenological form as
where is the activation energy in the absence of an
external magnetic field , is a real parameter, and is
defined by the equation . We derive the general
and direct expressions for these phenomenological parameters under the
restriction of uniform rotation of magnetization and on the basis of the
perturbative theory with respect to . Further,we apply our
results to NdFeB magnets and confirm the validity of the proposed
method by comparing with the Monte Carlo calculations.Comment: 8 pages, 2 figure
Microscopic theory of the activated behavior of the quantized Hall effect
The thermally activated behavior of the gate defined narrow Hall bars is
studied by analyzing the existence of the incompressible strips within a
Hartree-type approximation. We perform self-consistent calculations considering
the linear response regime, supported by a local conductivity model. We
investigate the variation of the activation energy depending on the width of
samples in the range of . We show that the largest
activation energy of high-mobility narrow samples, is at the low field edge of
Hall filling factor 2 plateau (exceeding half of the cyclotron energy), whereas
for relatively wide samples the higher activation energy is obtained at the
high field edge of Hall plateau. In contrast to the single-particle theories
based on the localization of electronic states, we found that the activation
energy is almost independent of the properties of the density of states.Comment: 8 pages, 4 figure
Ignition of thermally sensitive explosives between a contact surface and a shock
The dynamics of ignition between a contact surface and a shock wave is investigated using a
one-step reaction model with Arrhenius kinetics. Both large activation energy asymptotics and
high-resolution finite activation energy numerical simulations are employed. Emphasis is on comparing
and contrasting the solutions with those of the ignition process between a piston and a shock,
considered previously. The large activation energy asymptotic solutions are found to be qualitatively
different from the piston driven shock case, in that thermal runaway first occurs ahead of
the contact surface, and both forward and backward moving reaction waves emerge. These waves
take the form of quasi-steady weak detonations that may later transition into strong detonation
waves. For the finite activation energies considered in the numerical simulations, the results are
qualitatively different to the asymptotic predictions in that no backward weak detonation wave
forms, and there is only a weak dependence of the evolutionary events on the acoustic impedance
of the contact surface. The above conclusions are relevant to gas phase equation of state models.
However, when a large polytropic index more representative of condensed phase explosives is used,
the large activation energy asymptotic and finite activation energy numerical results are found to
be in quantitative agreement
Relaxation dynamics of Fe55Cr10Mo14C15B6 metallic glass explored by mechanical spectroscopy and calorimetry measurements
In this work, the mechanical relaxation dynamics of Fe55Cr10Mo14C15B6 metallic glass is explored by mechanical spectroscopy. The temperature-dependent loss modulus E″(T) shows the features of β relaxation well below glass transition temperature Tg. This β relaxation can be well described in the framework of anelastic theory by a thermal activated process with activation energy of 165 kJ mol−1. Structural relaxation, also known as physical aging, has a large effect on the glass properties. The activation energy spectrum of structural relaxation is characterized by differential scanning calorimetry measuring the heat flow difference between as-quenched and relaxed states. The obtained energy spectrum is well described by a lognormal distribution with maximum probability activation energy of 176 kJ mol−1. The obtained activation energy of structural relaxation is similar to that of β relaxation observed from mechanical spectroscopy. Both values are also close to the Johari–Goldstein β relaxation estimated by the empirical rule Eβ = 26RTg.Peer ReviewedPostprint (author's final draft
Effect of electron irradiation on vortex dynamics in YBa_2Cu_3O_{7-x} single crystals
We report on drastic change of vortex dynamics with increase of quenched
disorder: for rather weak disorder we found a single vortex creep regime, which
we attribute to a Bragg-glass phase, while for enhanced disorder we found an
increase of both the depinning current and activation energy with magnetic
field, which we attribute to entangled vortex phase. We also found that
introduction of additional defects always increases the depinning current, but
it increases activation energy only for elastic vortex creep, while it
decreases activation energy for plastic vortex creep.Comment: 4 pages, 3 figures, submited to Phys. Rev.
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