Joint space-frequency block codes and signal alignment for heterogeneous networks

In this paper, we propose a new diversity-oriented space-frequency block codes (SFBC) and signal alignment (SA) enabled physical network coding (PNC) method for the uplink of heterogeneous networks. The proposed joint Dual-SFBC with SA-PNC design substantially reduces interference and enables connecting a larger number of users when compared with methods adopting interference alignment (IA) or PNC. The main motivation behind the dual SFBC and SA-PNC design is that it allows the efficient coexistence of macro and small cells without any inter-system channel information requirements. Numerical results also verify that the proposed method outperforms the existing SA-PNC static method without any additional information exchange requirement between the two systems while achieving the main benefits of IA and SA-PNC coordinated methods recently proposed.publishe

Advanced Technologies for Device-to-device Communications Underlaying Cellular Networks

The past few years have seen a major change in cellular networks, as explosive growth in data demands requires more and more network capacity and backhaul capability. New wireless technologies have been proposed to tackle these challenges. One of the emerging technologies is device-to-device (D2D) communications. It enables two cellular user equip- ment (UEs) in proximity to communicate with each other directly reusing cellular radio resources. In this case, D2D is able to of oad data traf c from central base stations (BSs) and signi cantly improve the spectrum ef ciency of a cellular network, and thus is one of the key technologies for the next generation cellular systems. Radio resource management (RRM) for D2D communications and how to effectively exploit the potential bene ts of D2D are two paramount challenges to D2D communications underlaying cellular networks. In this thesis, we focus on four problems related to these two challenges. In Chapter 2, we utilise the mixed integer non-linear programming (MINLP) to model and solve the RRM optimisation problems for D2D communications. Firstly we consider the RRM optimisation problem for D2D communications underlaying the single carrier frequency division multiple access (SC-FDMA) system and devise a heuristic sub- optimal solution to it. Then we propose an optimised RRM mechanism for multi-hop D2D communications with network coding (NC). NC has been proven as an ef cient technique to improve the throughput of ad-hoc networks and thus we apply it to multi-hop D2D communications. We devise an optimal solution to the RRM optimisation problem for multi-hop D2D communications with NC. In Chapter 3, we investigate how the location of the D2D transmitter in a cell may affect the RRM mechanism and the performance of D2D communications. We propose two optimised location-based RRM mechanisms for D2D, which maximise the throughput and the energy ef ciency of D2D, respectively. We show that, by considering the location information of the D2D transmitter, the MINLP problem of RRM for D2D communications can be transformed into a convex optimisation problem, which can be ef ciently solved by the method of Lagrangian multipliers. In Chapter 4, we propose a D2D-based P2P le sharing system, which is called Iunius. The Iunius system features: 1) a wireless P2P protocol based on Bittorrent protocol in the application layer; 2) a simple centralised routing mechanism for multi-hop D2D communications; 3) an interference cancellation technique for conventional cellular (CC) uplink communications; and 4) a radio resource management scheme to mitigate the interference between CC and D2D communications that share the cellular uplink radio resources while maximising the throughput of D2D communications. We show that with the properly designed application layer protocol and the optimised RRM for D2D communications, Iunius can signi cantly improve the quality of experience (QoE) of users and of oad local traf c from the base station. In Chapter 5, we combine LTE-unlicensed with D2D communications. We utilise LTE-unlicensed to enable the operation of D2D in unlicensed bands. We show that not only can this improve the throughput of D2D communications, but also allow D2D to work in the cell central area, which normally regarded as a “forbidden area” for D2D in existing works. We achieve these results mainly through numerical optimisation and simulations. We utilise a wide range of numerical optimisation theories in our works. Instead of utilising the general numerical optimisation algorithms to solve the optimisation problems, we modify them to be suitable for the speci c problems, thereby reducing the computational complexity. Finally, we evaluate our proposed algorithms and systems through sophisticated numer- ical simulations. We have developed a complete system-level simulation framework for D2D communications and we open-source it in Github: https://github.com/mathwuyue/py- wireless-sys-sim

Identification of Catalytic Active Sites for Durable Proton Exchange Membrane Fuel Cell: Catalytic Degradation and Poisoning Perspectives

Recent progress in synthetic strategies, analysis techniques, and computational modeling assist researchers to develop more active catalysts including metallic clusters to single-atom active sites (SACs). Metal coordinated N-doped carbons (M-N-C) are the most auspicious, with a large number of atomic sites, markedly performing for a series of electrochemical reactions. This perspective sums up the latest innovative and computational comprehension, while giving credit to earlier/pioneering work in carbonaceous assembly materials towards robust electrocatalytic activity for proton exchange membrane fuel cells via inclusive performance assessment of the oxygen reduction reaction (ORR). M-Nx-Cy are exclusively defined active sites for ORR, so there is a unique possibility to intellectually design the relatively new catalysts with much improved activity, selectivity, and durability. Moreover, some SACs structures provide better performance in fuel cells testing with long-term durability. The efforts to understand the connection in SACs based M-Nx-Cy moieties and how these relate to catalytic ORR performance are also conveyed. Owing to comprehensive practical application in the field, this study has covered very encouraging aspects to the current durability status of M-N-C based catalysts for fuel cells followed by degradation mechanisms such as macro-, microdegradation, catalytic poisoning, and future challenges

Studies on hereditary C2 deficiency: Frequent occurrence of severe infections, atherosclerosis and rheumatological manifestations

The complement system is a part of the innate immunity and is essential in the defence against microorganisms. Hereditary C2 deficiency (C2D) is one of the most common complement deficiency states with an estimated prevalence of 1:20,000 in persons of Western descent. In the present investigation, the identification of more than 40 C2D persons at a single centre combined with long observation periods provided a unique basis for assessment of C2D-associated manifestations and diseases. The predominant clinical manifestation was severe bacterial infections. The infections were mainly caused by Streptococcus pneumoniae. Repeated infections occurred primarily during infancy and childhood. On the other hand, about 25-30 % of the C2D persons remained healthy during the observation period. Immunological factors as IgG subclass levels, GM allotypes, complement proteins, and Fc receptors were assessed to explain this difference. Homozygosity for the G2M*n allele was strongly associated with protection against severe infections (p<0.001). This indicated that an efficient antibody response to polysaccharide antigens is of great importance in C2D. Mannan-binding lectin deficiency also contributed to the susceptibility to infection. The association between C2D and systemic lupus erythematosus (SLE) was confirmed, but notably the severity of SLE in patients with C2D was similar to that of other SLE patients. Another novel finding was a high occurrence of anti-cardiolipin antibodies (aCL) and antibodies to the collagen-like region of C1q. Both autoantibodies have a pro-atherosclerotic effect that might explain the high occurrence of cardiovascular disease found in the cohort. Interestingly, anti-phospholipid syndrome was not observed despite the high occurrence of aCL. Vaccination in 25 C2D persons resulted in antibody responses which show that C2D persons benefit from vaccination against infections caused by encapsulated bacteria such as pneumococci

Halide Perovskite and Perovskite-Inspired Nanocrystals for Optoelectronic Applications

Optoelectronic applications, such as photovoltaics (PVs) and light-emitting diodes (LEDs), play a key role in addressing the global energy crisis. Yet, they demand new semiconductors with high stability, low environmental impact, and low cost. One of the attractive ways of synthesizing semiconductor materials is their colloidal synthesis at the nanoscale, leading to nanocrystals (NCs). This thesis focuses on a promising family of NCs extensively investigated during the last decade, namely NCs based on halide perovskites and their derivatives. Halide perovskite nanocrystals (PNCs) display appealing optoelectronic properties due to high defect tolerance, tunable crystal structures and dimensions, and versatile synthesis. However, a comprehensive optimization of these PNCs synthesis to enhance their stability and optical properties is lacking. Furthermore, the understanding of the fundamental structure-property relationships in emerging PNCs is still very limited. At the same time, the toxicity of lead (Pb) present in the most efficient PNC compositions demands the development of eco-friendly lead-free PNCs for optoelectronic applications. In this dissertation, we have identified the relationships between the synthesis and the key properties of emerging or novel PNCs, starting from the popular CsPbI3 and then moving towards Pb-free compositions. In particular, we have (i) enhanced the phase stability of CsPbI3 PNCs by tailoring the reaction temperature, (ii) achieved highly luminescent CsMnCl3 PNCs by tailoring the synthesis of the emissive crystalline phase, and (iii) proposed the first-ever syntheses of Cs2TiX6 (X = Br and Cl) PNCs and phase-pure AgBiI4 perovskite-inspired NCs with enhanced stabilities for potential nonlinear optical applications. We believe that the results of this thesis will encourage other researchers and practitioners in the field to further investigate the promising perovskites and perovskite-inspired NCs that we have identified and eventually enable their usage in real-life optoelectronics applications

Radio resource management techniques for QoS provision in 5G networks

Premi extraordinari doctorat UPC curs 2017-2018. Àmbit d’Enginyeria de les TICAs numerous mobile applications and over-the-top (OTT) services emerge and mobile Internet connectivity becomes ubiquitous, the provision of high quality of service (QoS) is more challenging for mobile network operators (MNOs). Research efforts focus on the development of innovative resource management techniques and have introduced the long term evolution advanced (LTE-A) communication standard. Novel business models make the growth of network capacity sustainable by enabling MNOs to combine their resources. The fifth generation (5G) mobile networks will involve technologies and business stakeholders with different capabilities and demands that may affect the QoS provision, requiring efficient radio resource sharing. The need for higher network capacity has introduced novel technologies that improve resource allocation efficiency. Direct connectivity among user equipment terminals (UEs) circumventing the LTE-A infrastructure alleviates the network overload. Part of mobile traffic is offloaded to outband device-to-device (D2D) connections (in unlicensed spectrum) enabling data exchange between UEs directly or via UEs-relays. Still, MNOs need additional spectrum resources and infrastructure. The inter-operator network sharing concept has emerged motivating the adoption of virtualization that enables network slicing, i.e., dynamic separation of resources in virtual slices (VSs). VSs are managed in isolation by different tenants using software defined networking and encompass core and radio access network resources allocated periodically to UEs. When UEs access OTT applications, flows with different QoS demands and priorities determined by OTT service providers (OSPs) are generated. OSPs’ policies should be considered in VS allocation. The coexisting technologies, business models and stakeholders require sophisticated radio resource management (RRM) techniques. To that end, RRM is performed in a complex ecosystem. When D2D communication involves data concurrently downloaded by the mobile network, QoS may be affected by LTE-A network parameters (resource scheduling policy, downlink channel conditions). It is also affected by the relay selection, as UEs may not be willing to help unknown UE pairs and UEs’ social ties in mobile applications may influence willingness for D2D cooperation. Thus, effective medium access control (MAC) mechanisms should coordinate D2D transmissions employing advanced techniques, e.g., network coding (NC). When UEs access OTT applications, OSPs’ policies are not considered by MNOs in RRM and OSPs cannot apply flow prioritization. Network neutrality issues also arise when OSPs claim resources from MNOs aiming to minimize grade of service (GoS). OSPs’ intervention may delay flows’ accommodation due to the time required for OSP-MNO interaction and the time the flows spent waiting for resources. This thesis proposes novel solutions to the RRM issues of outband D2D communication and VS allocation for OSPs in 5G networks. We present a cooperative D2D MAC protocol that leverages the opportunities for NC in D2D communication under the influence of LTE-A network parameters and its throughput performance analysis. The protocol improves D2D throughput and energy efficiency, especially for UEs with better downlink channel conditions. We next introduce social awareness in D2D MAC design and present a social-aware cooperative D2D MAC protocol that employs UEs’ social ties to promote the use of friendly relays reducing the total energy consumption. Motivated by the lack of approaches for OSP-oriented RRM, we present a novel flow prioritization algorithm based on matching theory that applies OSPs’ policies respecting the network neutrality and the analysis of its GoS and delay performance. The algorithm maintains low overhead and delay without affecting fairness among OSPs. Our techniques highlight the QoS improvement induced by the joint consideration of different technologies and business stakeholders in RRM design.A medida que varias aplicaciones móviles y servicios over-the-top (OTT) surgen y el Internet móvil se vuelve ubicua, la prestación de alta calidad de servicio (QoS) es desafiante para los operadores de red móvil (MNOs). Los estudios de investigación se enfocan en técnicas innovadoras para la gestión de recursos de red y han resultado en la especificación del estándar de comunicación long term evolution advanced (LTE-A). Modelos comerciales nuevos hacen que el crecimiento de la capacidad de red sea sostenible al permitir que MNOs combinen sus recursos. La quinta generación (5G) de redes móviles implicará tecnologías y partes comerciales interesadas con varias habilidades y demandas que pueden afectar la provisión de QoS y demandan la gestión eficaz de recursos de radio. La necesidad de capacidad de red más alta ha introducido tecnologías que hacen más eficiente la asignación de recursos. La conectividad directa entre terminales de equipos de usuarios (UEs) eludiendo la infraestructura LTE-A alivia la sobrecarga de red. Parte del tráfico es dirigido a conexiones de dispositivo a dispositivo (D2D) outband permitiendo la comunicación de UEs directamente o con relés. Los MNOs necesitan nuevos recursos de espectro e infraestructura. El intercambio de recursos entre MNOs ha surgido motivando la adopción de virtualización que realiza la segmentación de red i.e., la separación dinámica de recursos en trozos virtuales (VSs). Los VSs son administrados de forma aislada por inquilinos diferentes con software defined networking y abarcan recursos de red core y radio access asignadas periódicamente a UEs. Cuando UEs usan aplicaciones OTT, flujos de aplicación con demandas y prioridades definidas por proveedores de servicios OTT (OSPs) se generan. Las políticas de OSPs deben ser integradas en la asignación de VSs. La coexistencia de varias tecnologías y partes comerciales demanda técnicas sofisticadas de gestión de recursos radio (RRM). Con ese fin, la RRM se realiza en un ecosistema complejo. Si la comunicación D2D involucra datos descargados simultáneamente por la red móvil, los parámetros de red LTE-A (política de scheduling de recursos, condiciones de canal downlink) afectan el QoS. La selección de relés afecta el rendimiento porque los UEs no desean siempre ayudar a UEs desconocidos. Las relaciones sociales de los UEs en aplicaciones móviles pueden determinar la voluntad para la comunicación cooperativa D2D. Por lo tanto, mecanismos de control de acceso al medio (MAC) deben coordinar las transmisiones D2D con técnicas avanzadas ej., codificación de red. Si los UEs usan servicios OTT, las políticas de OSPs no son consideradas en RRM y los OSPs no emplean flujos prioritarios. Problemas de neutralidad de red surgen cuando los OSPs reclaman recursos de MNOs para minimizar el grado de servicio (GoS). La intervención de OSPs puede causar retraso en el servicio de flujos debido a la interacción OSP-MNO y el tiempo requerido para que los flujos reciban recursos. Esta tesis presenta soluciones nuevas para los problemas RRM de comunicación D2D outband y asignación de VSs a OSPs en redes 5G. Proponemos un protocolo D2D MAC cooperativo que explota las oportunidades de NC bajo la influencia de parámetros de red LTE-A y su análisis de rendimiento. El protocolo mejora el rendimiento y la eficiencia energética especialmente para UEs con mejores condiciones de canal downlink. Introducimos la conciencia social en el D2D MAC y proponemos un protocolo que utiliza relaciones sociales de UEs para elegir relés-amigos y reduce el consumo de energía. Dada la falta de técnicas que aborden el problema RRM de OSPs presentamos un algoritmo que aplique políticas de OSPs y respete la neutralidad usando la teoría de matching, y su análisis de GoS y retraso. El algoritmo induce bajo coste y retraso sin afectar la imparcialidad entre OSPs. Estas técnicas demuestran la mejora de QoS gracias a la consideración de tecnologas y partes comerciales diferentes en RRM.Award-winningPostprint (published version

Access Network Selection in Heterogeneous Networks

The future Heterogeneous Wireless Network (HWN) is composed of multiple Radio Access Technologies (RATs), therefore new Radio Resource Management (RRM) schemes and mechanisms are necessary to benefit from the individual characteristics of each RAT and to exploit the gain resulting from jointly considering the whole set of the available radio resources in each RAT. These new RRM schemes have to support mobile users who can access more than one RAT alternatively or simultaneously using a multi-mode terminal. An important RRM consideration for overall HWN stability, resource utilization, user satisfaction, and Quality of Service (QoS) provisioning is the selection of the most optimal and promising Access Network (AN) for a new service request. The RRM mechanism that is responsible for selecting the most optimal and promising AN for a new service request in the HWN is called the initial Access Network Selection (ANS). This thesis explores the issue of ANS in the HWN. Several ANS solutions that attempt to increase the user satisfaction, the operator benefits, and the QoS are designed, implemented, and evaluated. The thesis first presents a comprehensive foundation for the initial ANS in the H\VN. Then, the thesis analyses and develops a generic framework for solving the ANS problem and any other similar optimized selection problem. The advantages and strengths of the developed framework are discussed. Combined Fuzzy Logic (FL), Multiple Criteria Decision Making (MCDM) and Genetic Algorithms (GA) are used to give the developed framework the required scalability, flexibility, and simplicity. The developed framework is used to present and design several novel ANS algorithms that consider the user, the operator, and the QoS view points. Different numbers of RATs, MCDM tools, and FL inference system types are used in each algorithm. A suitable simulation models over the HWN with a new set of performance evolution metrics for the ANS solution are designed and implemented. The simulation results show that the new algorithms have better and more robust performance over the random, the service type, and the terminal speed based selection algorithms that are used as reference algorithms. Our novel algorithms outperform the reference algorithms in- terms of the percentage of the satisfied users who are assigned to the network of their preferences and the percentage of the users who are assigned to networks with stronger signal strength. The new algorithms maximize the operator benefits by saving the high cost network resources and utilizing the usage of the low cost network resources. Usually better results are achieved by assigning the weights using the GA optional component in the implemented algorithms