Advanced inorganic separators for alkaline batteries

A flexible, porous battery separator comprising a coating applied to a porous, flexible substrate is described. The coating comprises: (1) a thermoplastic rubber-based resin which is insoluble and unreactive in the alkaline electrolyte; (2) a polar organic plasticizer which is reactive with the alkaline electrolyte to produce a reaction product which contains a hydroxyl group and/or a carboxylic acid group; and (3) a mixture of polar particulate filler materials which are unreactive with the electrolyte, the mixture comprising at least one first filler material having a surface area of greater than 25 meters sq/gram, at least one second filler material having a surface area of 10 to 25 sq meters/gram, wherein the volume of the mixture of filler materials is less than 45% of the total volume of the fillers and the binder, the filler surface area per gram of binder is about 20 to 60 sq meters/gram, and the amount of plasticizer is sufficient to coat each filler particle. A method of forming the battery separator is also described

Using UV laser surface treatment to modify the wettability characteristics of polyamide 6,6 and its effects on osteoblast cell activity

Lasers can be used to modify the surface characteristics of a number of different materials for many applications. This paper details the way in which a KrF 248 nm excimer laser can be utilized to surface pattern and whole area irradiate nylon 6,6. 50 and 100 µm dimensioned trench and hatch patterns were induced in addition to the whole area irradiative processing which covered an area of 3.75 cm2 with fluencies ranging from 26 to 70 mJcm-2. The surface topography and roughness were determined with the use of a white light interferometer. From this it was found that the largest roughness, Sa, was 1.53 µm which arose from the 100 µm hatch excimer patterned sample. Wettability characteristics were obtained for each sample using a sessile drop device in which it was observed that the contact angle increased by up to 25° for the patterned samples and decreased by up to 15° for the large area processed samples. It is believed that the observed increase in contact angle can be attributed to the likely existence of a mixed-state wetting regime in which both Wenzel and Cassie-Baxter regimes are present over the liquid-solid interface. As a result of the small variation in surface roughness for the large area processed samples the observed decrease in contact angle can be explained by a modification of the surface chemistry and an increase in polar component (γp) and total surface energy (γT). Osteoblast cell activity was analyzed by carrying out cytotoxicity and alkaline leukocyte phosphatase (ALP) activity experiments, two major factors which are linked to sufficient cell growth and proliferation

Automated Detection of EUV Polar Coronal Holes During Solar Cycle 23

A new method for automated detection of polar coronal holes is presented. This method, called perimeter tracing, uses a series of 171, 195, and 304 \AA\ full disk images from the Extreme ultraviolet Imaging Telescope (EIT) on SOHO over solar cycle 23 to measure the perimeter of polar coronal holes as they appear on the limbs. Perimeter tracing minimizes line-of-sight obscurations caused by the emitting plasma of the various wavelengths by taking measurements at the solar limb. Perimeter tracing also allows for the polar rotation period to emerge organically from the data as 33 days. We have called this the Harvey rotation rate and count Harvey rotations starting 4 January 1900. From the measured perimeter, we are then able to fit a curve to the data and derive an area within the line of best fit. We observe the area of the northern polar hole area in 1996, at the beginning of solar cycle 23, to be about 4.2% of the total solar surface area and about 3.6% in 2007. The area of the southern polar hole is observed to be about 4.0% in 1996 and about 3.4% in 2007. Thus, both the north and south polar hole areas are no more than 15% smaller now than they were at the beginning of cycle 23. This compares to the polar magnetic field measured to be about 40% less now than it was a cycle ago.Comment: 18 pagers, 7 figures, accepted to Solar Physic

Throwing enhances humeral shaft cortical bone properties in pre-pubertal baseball players: a 12-month longitudinal pilot study

Objectives: To explore throwing athletes as a prospective, within-subject controlled model for studying the response of the skeleton to exercise. Methods: Male pre-pubertal throwing athletes (n=12; age=10.3±0.6 yrs) had distal humerus cortical volumetric bone mineral density (Ct.vBMD), cortical bone mineral content (Ct.BMC), total area (Tt.Ar), cortical area (Ct.Ar), medullary area (Me.Ar), cortical thickness (Ct.Th) and polar moment of inertia (IP) assessed within their throwing (exercised) and nonthrowing (control) arms by peripheral quantitative computed tomography at baseline and 12 months. Throwing-to-nonthrowing arm percent differences (i.e. bilateral asymmetry) were compared over time. Results: Over 12 months, the throwing arm gained 4.3% (95% Cl=1.1% to 7.5%), 2.9% (95% Cl=0.3% to 5.4%), 3.9% (95% Cl=0.7% to 7.0%), and 8.2% (95% Cl=2.0% to 6.8%) more Ct.BMC, Ct.Ar, Tt.Ar, and IP than the nonthrowing arm, respectively (all p<0.05). There was no significant effect of throwing on Ct.vBMD, Ct.Th and Me.Ar (all p=0.18-0.82). Conclusion: Throwing induced surface-specific cortical bone adaptation at the distal humeral diaphysis that contributed to a gain in estimated strength. These longitudinal pilot data support the utility of throwing athletes as a within-subject controlled model to explore factors influencing exercise-induced bone adaptation during the critical growing years

Ice in the Antarctic polar stratosphere

On six occasions during the 1987 Airborne Antarctic Ozone Experiment, the Polar Stratospheric Cloud (PSC) ice crystals were replicated over the Palmer Peninsula at approximately 70 deg South. The sampling altitude was approximately 60 to 65 thousand feet, the temperature range was -83.5 to -72C and the atmosphere was subsaturated in all cases. The collected crystals were predominantly complete and hollow prismatic columns with maximum dimensions up to 217 microns. Evidence of scavenging of submicron particles was detected on several crystals. While the replicated crystal sizes were larger than anticipated, their relatively low concentration results in a total surface area less than one tenth that of the sampled aerosol particles. The presence of large crystals suggest that PSC ice crystals can play a very important role in stratospheric dehydration processes

XMM-Newton Observations of Radio Pulsars B0834+06 and B0826-34 and Implications for Pulsar Inner Accelerator

We report the X-ray observations of two radio pulsars with drifting subpulses: B0834 + 06 and B0826 - 34 using \xmm\. PSR B0834 + 06 was detected with a total of 70 counts from the three EPIC instruments over 50 ks exposure time. Its spectrum was best described as that of a blackbody (BB) with temperature $T_s=(2.0^{+2.0}_{-0.9}) \times 10^6$ K and bolometric luminosity of $L_b=(8.6^{+14.2}_{-4.4}) \times 10^{28}$ erg s$^{-1}$. As it is typical in pulsars with BB thermal components in their X-ray spectra, the hot spot surface area is much smaller than that of the canonical polar cap, implying a non-dipolar surface magnetic field much stronger than the dipolar component derived from the pulsar spin-down (in this case about 50 times smaller and stronger, respectively). The second pulsar PSR B0826 - 34 was not detected over 50 ks exposure time, giving an upper limit for the bolometric luminosity $L_b \leq 1.4 \times 10^{29}$ erg s$^{-1}$. We use these data as well as the radio emission data concerned with drifting subpulses to test the Partially Screened Gap (PSG) model of the inner accelerator in pulsars.Comment: Accepted for publication by The Astrophysical Journa

Lomustine Analogous Drug Structures for Intervention of Brain and Spinal Cord Tumors: The Benefit of In Silico Substructure Search and Analysis

Lomustine is a nitrosourea anticancer agent shown to be effective for treatment of childhood medulloblastoma. In silico substructure searches produced 17 novel nitrosourea agents analogous to lumustine and retaining activity for DNA alkylation and cytotoxic activity. The mean values for Log P, polar surface area, formula weight, number of oxygens & nitrogens, and rotatable bonds were 2.524, 62.89 Anstroms2, 232.8, 5, and 2, respectively. All 17 agents have formula weight less than 450 and Log P less than 5, two criteria preferred for blood-brain barrier penetration.These agents have a polar surface area less than 90 Angstroms2. Each show zero violations of the Rule of five indicating favorable drug likeness and oral drug activity. Hierarchical cluster analysis indicated that 16 of the novel agents were highly similar to lomustine, save for agent 12 which bears a hydroxylated branched carbon substituent. A total of 17 novel anticancer agents were elucidated having molecular properties very effective for penetrating through the BBB and into the central nervous system. This study shows the effectiveness of in silico search and recognition of anticancer agents that are suitable for the clinical treatment of brain tumors

Comparison of carbon and opal export rates between summer and spring bloom periods in the region of the Antarctic Polar Front, SE Atlantic.

Although primary production in the Antarctic Circumpolar Current is not above the world average and carbon burial rates are low, 70% of the world's opal burial occurs in this zone and it has been suggested that blooms of large diatoms are responsible for this extraordinary situation. Here we compare export fluxes during bloom and steady-state situations near the Antarctic Polar Front in the SE Atlantic.In a previous expedition during the austral spring, we observed the development of a bloom that led to the sudden export of particles (Rutgers van der Loeff et al., 1997). Here we report the results of a second expedition to the same area in summer (Dec-Jan), 3 years later. 234Th was monitored in the surface water and in Rosette casts down to a water depth of 500m as tracer of export production in an intensive sampling program within a box of 275 x 375 km.The distribution of particulate and dissolved 234Th was remarkably constant over time and location. Total (dissolved + particulate) 234Th activities were depleted relative to its parent 238U at the surface (234Th/238U activity ratio approximately 83%), reaching equilibrium at a depth of around 190m. This constant depletion corresponds to a 234Th export rate of 1115 dpm m-2 d-1, 35% of the value observed during the spring bloom

Removal of captopril pharmaceutical from synthetic pharmaceutical-industry wastewaters:Use of activated carbon derived from Butia catarinensis

A high surface area activated carbon was produced from the seed of Butia catarinensis (Bc), which was utilized for removing captopril from synthetic pharmaceutical industry wastewaters. The activated carbon was made by mixing ZnCl2 and Bc at a proportion of 1:1 and pyrolyzed at 600° (ABc-600). The material was characterized by the Boehm titration, hydrophilic/ hydrophobic ratio, elemental analysis, TGA, FTIR, and N2 isotherm (surface area (SBET), total pore volume (TPV), and pore size distribution (PSD)). The characterization data showed that the adsorbent displayed a hydrophilic surface due to the presence of several polar groups. The carbon material presented a TPV of 0.392 cm3 g−1, and SBET of 1267 m2 g−1. The equilibrium and kinetics data were suitably fitted to Liu isotherm and Avrami-fractional-order. The employment of the ABc-600 in the treatment of synthetic pharmaceutical industry wastewater exhibited high effectiveness in their removals (up to 99.0 %)