BIOREMEDIASI Zn(II) PADA LIMBAH CAIR GALVANISASI DENGAN Skeletonema sp.

Penelitian ini bertujuan untuk mengetahui ada atau tidak ada perbedaan jumlah sel Skeletonema sp. dalam limbah cair galvanisasi dibandingkan kontrol, jumlah sel Skeletonema sp. dalam limbah cair galvanisasi berdasarkan variasi waktu kontak, efisiensi penyishan Zn(II) oleh Skeletonema sp. pada limbah cair galvanisasi berdasarkan variasi waktu kontak, dan jumlah sel dalam satu koloni Skeletonema sp. pada limbah cair galvanisasi berdasarkan variasi waktu kontak. Penelitian ini menggunakan Skeletonema sp. sebagai agen bioremediasi pada limbah cair galvanisasi dengan variasi waktu kontak (1, 2, 3, 4, 5 hari). Data pengamatan dianalisa secara statistik menggunakan Uji T, Uji F, dan Uji H. Hasil penelitian menunjukkan jumlah sel Skeletonema sp. dalam limbah cair galvanisasi dan kontrol berbeda. Jumlah sel Skeletonema sp. dalam limbah cair galvanisasi semakin meningkat pada waktu kontak satu hingga tiga hari, kemudian menurun hingga waktu kontak lima hari. Jumlah sel Skeletonema sp. dalam limbah cair galvanisasi paling tinggi didapatkan saat waktu kontak tiga hari (128 x 104 sel/mL). Jumlah sel dalam satu koloni Skeletonema sp. Tertinggi juga berada pada waktu kontak tiga hari (10 sel/koloni). Penyerapan maksimum terjadi pada waktu kontak lima hari sebesar 41,73%. Berdasarkan hasil penelitian dapat dikatakan Skeletonema sp. dapat tumbuh dan berpotensi melakukan penyerapan Zn(II) di limbah cair galvanisasi

Indicative Conditionals are Material - Expanding the Survey

Adam Rieger (2013) has carried out a survey of arguments in favour of the material account of indicative conditionals. These arguments involve simple and direct demonstrations of the material account. I extend the survey with new arguments and clarify the logical connections among them. I also show that the main counter-examples against these arguments are not successful either because their premises are just as counter-intuitive as the conclusions, or because they depend on contextual fallacies. The conclusion is that the unpopularity of the material account is unjustified and that a more systematic approach in the analysis of arguments is long overdue in our attempts to understand the nature of conditionals

The synthesis and the catalytic (catalase and tyrosinase) activities of amino acid copper complexes covalently grafted onto silica gel

In this work the synthesis, structure and certain catalytic properties of amino acid copper complexes covalently grafted onto silica gel are described. The following enzyme mimicking complexes were synthesized and characterised by experimental (FT-IR) and computational (mainly MM+) methods: BOC-His-Cu/silica gel, BOC-Tyr-Cu/silica gel, His-OMe-Cu/silica gel, Tyr-OMe-Cu/silica gel, H-His-Cu/silica gel, H-Tyr-Cu/silica gel His-OH-Cu/silica gel and Tyr-OH-Cu/silica gel. The activities of these substances were also tested in the decomposition of hydrogen peroxide. The majority of the substances proved to be good enzyme mimics displaying either catalase or tyrosinase activity

Fully coordinated silica nanoclusters: (SiO2)(N) molecular rings

A new form of finite silica with edge-sharing SiO2 units connected in a ring is proposed. High-level density-functional calculations for (SiO2)(N), N = 4-14, show the rings to be energetically more stable than the corresponding (SiO2)(N) linear chains for N > 11. The rings display frequency modes in remarkable agreement with infrared bands measured on dehydrated silica surfaces indicating their potential as models of strained extended silica systems. Silica rings, if synthesized, may also be useful precursors for new bulk-silica polymorphs with tubular or porous morphologies

Reinforcement of natural rubber by precipitated silica: the influence of processing temperature

The thermal history and in particular the mixing dump temperature is a parameter of paramount importance in mixing rubber and silica with a silane coupling agent in order to achieve proper silanization of silica and to avoid premature scorch reactions. In this work, the influence of mixing dump temperature on the performance of silica reinforced Natural Rubber (NR) is investigated. The investigation also includes the effect of non-rubber constituents, primarily proteins in NR, by using deproteinized Natural Rubber (DPNR) and synthetic polyisoprene (IR). The vulcanization properties and rubber-to-filler interactions of silica reinforced NR in presence and absence of a silane coupling agent are highlighted. With increasing mixing dump temperature, the silanization reaction between silica and silane coupling agent proceeds further. At sufficiently high dump temperature, filler-filler interactions in the NR-silica compounds are reduced and silica-rubber interaction improved as evidenced by a drop in the Payne effect and increment in chemically bound rubber. It is demonstrated that NR and IR compounds mixed till above the optimum dump temperature exhibit cure reversion and reduction in tensile properties. On the other hand, DPNR-silica vulcanizates show slightly more constant physical properties

Silica in Protoplanetary Disks

Mid-infrared spectra of a few T Tauri stars (TTS) taken with the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope show prominent narrow emission features indicating silica (crystalline silicon dioxide). Silica is not a major constituent of the interstellar medium; therefore, any silica present in the circumstellar protoplanetary disks of TTS must be largely the result of processing of primitive dust material in the disks surrouding these stars. We model the silica emission features in our spectra using the opacities of various polymorphs of silica and their amorphous versions computed from earth-based laboratory measurements. This modeling indicates that the two polymorphs of silica, tridymite and cristobalite, which form at successively higher temperatures and low pressures, are the dominant forms of silica in the TTS of our sample. These high temperature, low pressure polymorphs of silica present in protoplanetary disks are consistent with a grain composed mostly of tridymite named Ada found in the cometary dust samples collected from the STARDUST mission to Comet 81P/Wild 2. The silica in these protoplanetary disks may arise from incongruent melting of enstatite or from incongruent melting of amorphous pyroxene, the latter being analogous to the former. The high temperatures of 1200K-1300K and rapid cooling required to crystallize tridymite or cristobalite set constraints on the mechanisms that could have formed the silica in these protoplanetary disks, suggestive of processing of these grains during the transient heating events hypothesized to create chondrules.Comment: 47 pages, 9 figures, to appear in the 1 January, 2009 issue of the Astrophysical Journa

A ceramic composite thermal insulation

Ceramic composite thermal insulation comprised of alumina-silica fibers, pigmentary potassium titanate, and asbestos fibers, bonded with a colloidal silica sol has improved insulating capabilities to both radiant and convective heat. Gelation of the colloidal silica sol prevents binder migration

Bulk or surface grafted silylated Ru(ii) complexes on silica as luminescent nanomaterials

A series of Ru(II) complexes with monosilylated-dipyridine ligand have been synthesized and fully characterized and were then covalently attached to silica nanoparticles. Two types of hybrids were obtained depending on the experimental procedure. In the first approach, metal complexes were incorporated inside the silica nanoparticles leaving a free hydroxylated silica surface for further functionalization. These silica based nanohybrids are similar to the well known nanoparticles encapsulating [Ru(bpy)3]2+ complexes preventing the release of the dye when used in aqueous or organic solutions. Size and luminescence properties vary throughout the series of metal complexes. The second approach leads to ruthenium(II) complexes covalently attached to the silica nanoparticle surface via hydrolysis and condensation of the ethoxysilyl group with silanol sites of Ludox type silica nanoparticles. This leads to the grafting of a monolayer for complexes with the monoethoxysilyl dipyridine ligand. In contrast, the complexes with triethoxysilyl ligands can lead to small amounts of oligomers, but their quantity is limited by the sterical constraints imposed by the molecular structure. The size of the hybrids depends on the starting particles. 29Si and 13C solid state NMR are used to characterize silica surface properties whereas TEM and SEM confirm nanosize and morphology of the hybrids. The complexes and the nanohybrids are luminescent, with variations for ruthenium(II) complexes that are covalently incorporated or grafted on the silica surfac