Super nucleation and orientation of poly (butylene terephthalate) crystals in nanocomposites containing highly reduced graphene oxide

The ring opening polymerization of cyclic butylene terephthalate into poly (butylene terephthalate) (pCBT) in the presence of reduced graphene oxide (RGO) is an effective method for the preparation of polymer nanocomposites. The inclusion of RGO nanoflakes dramatically affects the crystallization of pCBT, shifting crystallization peak temperature to higher temperatures and, overall, increasing the crystallization rate. This was due to a super nucleating effect caused by RGO, which is maximized by highly reduced graphene oxide. Furthermore, combined analyses by differential scanning calorimetry (DSC) experiments and wide angle X-ray diffraction (WAXS) showed the formation of a thick {\alpha}-crystalline form pCBT lamellae with a melting point of ~250 {\deg}C, close to the equilibrium melting temperature of pCBT. WAXS also demonstrated the pair orientation of pCBT crystals with RGO nanoflakes, indicating a strong interfacial interaction between the aromatic rings of pCBT and RGO planes, especially with highly reduced graphene oxide. Such surface self-organization of the polymer onto the RGO nanoflakes may be exploited for the enhancement of interfacial properties in their polymer nanocomposites

Role of the synthesis route on the properties of hybrid LDH-graphene as basic catalysts

Layered double hydroxides (LDH or HT) or their derived mixed oxides present marked acid-base properties useful in catalysis, but they lead to agglomerate inducing a weak accessibility to the active sites. In this study we report the preparation and characterization of HT/Graphene (HT/rGO) nanocomposites as active and selective basic catalysts for the acetone condensation reaction. The graphene high specific surface area and structural compatibility with the HT allowed increasing the number and accessibility of the active sites and activity of this later. Two series of HT/rGO nanocomposites with 0.5 = HT/rGO = 10 mass ratio were prepared by: i) direct HT coprecipitation in the presence of GO; ii) self-assembly of preformed HT with GO. The prepared HT/rGO nanocomposites were dried either in air at 80 °C or freeze-dried. A series of characterizations showed the great influence of the preparation method and HT/rGO mass ratio on both the nanocomposite structure and catalytic activity. An optimum activity was observed for a HT/rGO = 10 catalyst. Particularly, the highest catalytic activity was found in those nanocomposites obtained by coprecipitation and freeze dried (3 times more active than bulk HT) which can be connected to their structure with a better accessibility to the basic sites.Postprint (author's final draft

Effects of chemical structure and morphology of graphene-related materials (GRMs) on melt processing and properties of GRM/polyamide-6 nanocomposites

In this work, different graphene-related materials (GRMs) and polyamide-6 (PA6) were melt compounded by twin screw extrusion. The GRMs prepared were graphene nanoplatelets (GNPs), graphene oxide (GO), reduced graphene oxide (rGO) and silane functionalised reduced graphene oxide (f-rGO). The GRMs had comparable lateral size (20-30μm), but different thickness and surface chemistry which resulted in different behaviour in processing of melt flow, maximum loading in the PA6 matrix (15%wt for GNPs, 10%wt for GO, 2%wt for rGO and 2.5%wt for f-rGO) as well as mechanical properties. A second extrusion phase produced formulations with lower concentration of GRMs. In the case of f-rGO/PA6, the melt flow index increased by over 76% at 0.5%wt loading compared with the pure PA6 resin, facilitating processing and dispersion of the flakes within the matrix and increasing the elastic modulus and tensile strength by 39%. However, high filler content above 10% has been achieved only for GNPs improving the elastic modulus by 50% at 15%wt

Cross-linked CoMoO4/rGO nanosheets as oxygen reduction catalyst

Development of inexpensive and robust electrocatalysts towards oxygen reduction reaction (ORR) is crucial for the cost-affordable manufacturing of metal-air batteries and fuel cells. Here we show that cross-linked CoMoO4 nanosheets and reduced graphene oxide (CoMoO4/rGO) can be integrated in a hybrid material under one-pot hydrothermal conditions, yielding a composite material with promising catalytic activity for oxygen reduction reaction (ORR). Cyclic voltammetry (CV) and linear sweep voltammetry (LSV) were used to investigate the efficiency of the fabricated CoMoO4/rGO catalyst towards ORR in alkaline conditions. The CoMoO4/rGO composite revealed the main reduction peak and onset potential centered at 0.78 and 0.89 V (vs. RHE), respectively. This study shows that the CoMoO4/rGO composite is a highly promising catalyst for the ORR under alkaline conditions, and potential noble metal replacement cathode in fuel cells and metal-air batteries

Sunspot area catalogue revisited: Daily cross-calibrated areas since 1874

Long and consistent sunspot area records are important for understanding the long-term solar activity and variability. Multiple observatories around the globe have regularly recorded sunspot areas, but such individual records only cover restricted periods of time. Furthermore, there are also systematic differences between them, so that these records need to be cross-calibrated before they can be reliably used for further studies. We produce a cross-calibrated and homogeneous record of total daily sunspot areas, both projected and corrected, covering the period between 1874 and 2019. A catalogue of calibrated individual group areas is also generated for the same period. We have compared the data from nine archives: Royal Greenwich Observatory (RGO), Kislovodsk, Pulkovo, Debrecen, Kodaikanal, Solar Optical Observing Network (SOON), Rome, Catania, and Yunnan Observatories, covering the period between 1874 and 2019. Mutual comparisons of the individual records have been employed to produce homogeneous and inter-calibrated records of daily projected and corrected areas. As in earlier studies, the basis of the composite is formed by the data from RGO. After 1976, the only datasets used are those from Kislovodsk, Pulkovo and Debrecen observatories. This choice was made based on the temporal coverage and the quality of the data. In contrast to the SOON data used in previous area composites for the post-RGO period, the properties of the data from Kislovodsk and Pulkovo are very similar to those from the RGO series. They also directly overlap the RGO data in time, which makes their cross-calibration with RGO much more reliable. We have also computed and provide the daily Photometric Sunspot Index (PSI) widely used, e.g., in empirical reconstructions of solar irradiance.Comment: Accepted for publication in Astronomy and Astrophysics. An additional file (animation) is available at https://www.dropbox.com/s/armawopcxt8kmb9/Mandal_2020_butterfly_diagram.zip?dl=

Experimental and Modeling Studies of the Reaction Kinetics of Alkaline-Catalyzed used Frying Oil Glycerolysis using Isopropyl Alcohol as a Reaction Solvent

An alkaline catalyzed glycerolysis of used frying oil using sodium hydroxide and isopropyl alcohol as solvent was investigated. A reaction kinetic model considering glycerol-triglyceride solubility and a second order kinetic mechanism was also developed. The effect of variations in glycerol to used frying oil molar ratio (RGO = 2:1 to 4:1) and temperature (60 to 80ºC) on the rate of reaction were investigated, while the isopropyl alcohol to used frying oil ratio (2:1 v/w) and the concentration of catalyst (3 wt% based on used frying oil) were held constant. Results showed that both RGO and temperature affected the glycerolysis reaction kinetic, with the effect of RGO was found to be superior. The proposed model showed its good agreement with the experimental data. Glycerolysis at RGO = 3:1 and 80ºC in 90 min was found to be a relatively good condition, where 91.03% of tryglceride was converted into MG

Reduced graphene oxide-multiwalled carbon nanotubes hybrid film with low Pt loading as counter electrode for improved photovoltaic performance of dye-sensitised solar cells

In this work, the role of reduced graphene oxide (rGO) with hyperbranched surfactant and its hybridisation with multiwalled carbon nanotubes (MWCNTs) and platinum (Pt) nanoparticles (NPs) as counter electrode (CE) were investigated to determine the photovoltaic performance of dye-sensitised solar cells (DSSCs). Sodium 1,4-is(neopentyloxy)-3-(neopentyloxycarbonyl)- 1,4-dioxobutane-2-sulphonate (TC14) surfactant was utilised as dispersing and stabilising agent in electrochemical exfoliation to synthesise graphene oxide (GO) as initial solution for rGO production prior to its further hybridisation and fabrication as thin film. A chemical reduction process utilising hydrazine hydrate was conducted to produce rGO due to the low temperature process and water-based GO solution. Subsequently, hybrid solution was prepared by mixing 1 wt% MWCNTs into the produced rGO solution. TC14-rGO and TC14-rGO_MWCNTs hybrid solution were transferred into fluorine-doped tin oxide substrate to fabricate thin film by spraying deposition method. Finally, the CE films were prepared by coating with thin Pt NPs. Photoanode film was prepared by a two-step process: hydrothermal growth method to synthesise titanium dioxide nanowires (TiO2 NWs) and subsequent squeegee method to apply TiO2 NPs. According to solar simulator measurement, the highest energy conversion efficiency (η) was achieved by using CE-based TC14-rGO_MWCNTs/Pt (1.553%), with the highest short current density of 4.424 mA/cm2. The highest η was due to the high conductivity of CE hybrid film and the morphology of fabricated TiO2 NWs/TiO2 NPs. Consequently, the dye adsorption was high, and the photovoltaic performance of DSSCs was increased. This result also showed that rGO and rGO_MWCNTs hybrid can be used as considerable potential candidate materials to replace Pt gradually

Interfacial Morphology Addresses Performance of Perovskite Solar Cells Based on Composite Hole Transporting Materials of Functionalized Reduced Graphene Oxide and P3HT

The development of novel hole transporting materials (HTMs) for perovskite solar cells (PSCs) that can enhance device's reproducibility is a largely pursued goal, even to the detriment of a very high efficiency, since it paves the way to an effective industrialization of this technology. In this work, we study the covalent functionalization of reduced graphene oxide (RGO) flakes with different organic functional groups with the aim of increasing the stability and homogeneity of their dispersion within a poly(3-hexylthiophene) (P3HT) HTM. The selected functional groups are indeed those recalling the two characteristic moieties present in P3HT, i.e., the thienyl and alkyl residues. After preparation and characterization of a number of functionalized RGO@P3HT blends, we test the two containing the highest percentage of dispersed RGO as HTMs in PSCs and compare their performance with that of pristine P3HT and of the standard Spiro-OMeTAD HTM. Results reveal the big influence of the morphology adopted by the single RGO flakes contained in the composite HTM in driving the final device performance and allow to distinguish one of these blends as a promising material for the fabrication of highly reproducible PSCs

Hydrophobicity properties of graphite and reduced graphene oxide of the polysulfone (PSf) mixed matrix membrane

Hydrophobicity properties of graphite and reduced graphene oxide (rGO) (from exfoliated graphite/rGO) towards PSf polymer membrane characteristic and properties at different additives weight concentrations (1, 2, 3, 4 and 5 wt. %) were investigated. Both PSF/graphite and PSf/rGO membranes were characterized in term of hydrophobicity, surface bonding, surface roughness and porosity. FTIR peaks revealed that membrane with graphite and reduced graphene oxide nearly diminished their O-H bonding which was opposite to the graphene oxide peak that shows a strong O-H bonding as increased exfoliated times. These results were in line with the contact angle results that showed strong hydrophobicity of graphite and reduced graphene oxide membranes as increased these additives concentration. The effect of strong hydrophobicity in these membranes also has resulted in smoother surface roughness compared to pristine PSf membrane. Further investigation of the performance of water flux also proved that both above membranes have strong hydrophobic effect, with the lowest pure water flux rate (L/m2h) was given by PSf/rGO 3% membrane at 19.2437 L/m2h