Strain-gradient mediated local conduction in strained bismuth ferrite films

It has been recently shown that the strain gradient is able to separate the light-excited electron-hole pairs in semiconductors, but how it affects the photoelectric properties of the photo-active materials remains an open question. Here, we demonstrate the critical role of the strain gradient in mediating local photoelectric properties in the strained BiFeO3 thin films by systematically characterizing the local conduction with nanometre lateral resolution in both dark and illuminated conditions. Due to the giant strain gradient manifested at the morphotropic phase boundaries, the associated flexo-photovoltaic effect induces on one side an enhanced photoconduction in the R-phase, and on the other side a negative photoconductivity in the morphotropic [Formula: see text]-phase. This work offers insight and implication of the strain gradient on the electronic properties in both optoelectronic and photovoltaic devices

Mechanism of the photovoltaic effect in 2-6 compounds Progress report, 1 Oct. 1968 - 31 Mar. 1969

Heat treatment, illumination and darkness effects, and photovoltaic properties of Cu2S-CdS heterojunction

The use of power DC-DC converters and gyrator structures for energy processing

This article provides a classification of high efficiency switching power-gyrator structures and their use as cells for energy processing in photovoltaic solar facilities. Having into account the properties of these topologies presented in the article, their inclusion in solar facilities allows increasing the performance of the whole installation. Thus, the design, simulation and implementation of a G-type power gyrator are carried out throughout the text. In addition, in order to obtain the maximum power from the photovoltaic solar panel, a maximum power point tracking (MPPT) is mandatory in the energy processing path. Therefore, the practical implementation carried out includes a control loop of the power gyrator in order to track the aforementioned maximum power point of the photovoltaic solar panel.Postprint (published version

The use of power gyrator structures as energy processing cells in photovoltaic solar facilities

This paper will provide a classification of high efficiency switching power-gyrator structures and their use as cells for energy processing in photovoltaic solar facilities. Having into account the properties of these topologies presented in the article, their inclusion in solar facilities allows increasing the performance of the whole installation. Thus, the design, simulation and implementation of a G-type power gyrator are carried out throughout the text. In addition, in order to obtain the maximum power from the photovoltaic solar panel, a maximum power point tracking (MPPT) is mandatory in the energy processing path. Therefore, the practical implementation carried out includes a control loop of the power gyrator in order to track the aforementioned maximum power point of the photovoltaic solar panel.Postprint (published version

Enhancement of optical absorption in Ga-chalcopirite-based intermediate-band materials for high efficiency solar cells

We present absorption properties enhancement for two CuGaS2-based intermediate-band materials, as promising compounds for high efficiency, lower-cost photovoltaic devices. Previous band diagrams calculations predicted that these materials present a partially filled localized band within the band gap of the host semiconductor, which would increase the absorption of low-energy photons, creating additional electron–hole pairs respect to a conventional semiconductor. This could ideally result in an increase of the photocurrent of the cell without the fall of the open-circuit voltage. In this paper we show, using density functional methods, the effect of this intermediate band on the optical properties of the derived alloys. We highlight the significant enhancement of the absorption coefficient observed in the most intense range of the solar emission and we study the reflectance and transmittance properties of the materials in order to understand the effect of the thickness of the sample on the optical properties. We compare two different substituents of the Ga atoms in CuGaS2, namely, Ti and Cr atoms, able to form the intermediate-band material, and their interest for photovoltaic applications

Solar-cell performance at low temperatures and simulated solar intensities

Photovoltaic properties of cadmium sulfide and silicon solar cells at low temperatures and simulated solar intensitie

Thin film solar cells based on the ternary compound Cu2SnS3

Alongside with Cu2ZnSnS4 and SnS, the p-type semiconductor Cu2SnS3 also consists of only Earth abundant and low-cost elements and shows comparable opto-electronic properties, with respect to Cu2ZnSnS4 and SnS, making it a promising candidate for photovoltaic applications of the future. In this work, the ternary compound has been produced via the annealing of an electrodeposited precursor in a sulfur and tin sulfide environment. The obtained absorber layer has been structurally investigated by X-ray diffraction and results indicate the crystal structure to be monoclinic. Its optical properties have been measured via photoluminescence, where an asymmetric peak at 0.95 eV has been found. The evaluation of the photoluminescence spectrum indicates a band gap of 0.93 eV which agrees well with the results from the external quantum efficiency. Furthermore, this semiconductor layer has been processed into a photovoltaic device with a power conversion efficiency of 0.54%, a short circuit current of 17.1 mA/cm2, an open circuit voltage of 104 mV hampered by a small shunt resistance, a fill factor of 30.4%, and a maximal external quantum efficiency of just less than 60%. In addition, the potential of this Cu2SnS3 absorber layer for photovoltaic applications is discussed

Photovoltaic properties of molecules with internal charge transfer

Práce je zaměřena na studium donor-akceptorových molekul s vnitřním přenosem náboje z hlediska jejich použití v organických solárních článcích. V práci bude studován vliv změny chemické struktury těchto molekul na optické a optoelektrické vlastnosti. Dále budou z těchto materiálů připraveny solární články a studováno jejich fotovoltaické chování.The work is focused on the study of donor-acceptor molecules with internal charge transfer in terms of their use in organic solar cells. The work will be studied the effect of changes in the chemical structure of these molecules on the optical and optoelectronic properties. Furthermore, based on these materials prepared solar cells and photovoltaic studied their behavior.