Petrologic evidence for earliest Miocene tectonic mobility on eastern Taranaki Basin margin

At Gibsons Beach on the west coast of central North Island, the earliest Miocene (Waitakian) Otorohanga Limestone, the top-most formation in the Te Kuiti Group, is unconformably overlain on an undulating, locally channelised erosion surface by the Early Miocene (Otaian) Papakura Limestone at the base of the Waitemata Group. The basal facies of the Papakura Limestone is a conglomerate composed exclusively of tightly packed pebble- to cobble-sized clasts of skeletal limestone sourced from the underlying Otorohanga Limestone. This petrographic and geochemical study demonstrates that the Otorohanga Limestone was partially lithified during marine and shallow-burial cementation at subsurface depths down to a few tens of metres prior to uplift, erosion and cannibalisation of the limestone clasts into the Papakura Limestone. Strontium isotope dating of fossils from both the Otorohanga and Papakura Limestones at Gibsons Beach yield comparable ages of about 22 Ma, close to the Waitakian/Otaian boundary, indicating very rapid tectonic inversion and erosion of the section occurred in the earliest Miocene. We envisage the clasts of Otorohanga Limestone were sourced from a proximal shoreline position and redeposited westwards by episodic debris flows onto a shallow-shelf accumulating mixed siliciclastic-skeletal carbonate deposits of the Papakura Limestone. Subsequent burial of both limestones by rapidly accumulating Waitemata Group sandstone and flysch instigated precipitation of widespread burial cements from pressure dissolution of carbonate material at subsurface depths from about 100 m to 1.0 km. The vertical tectonic movements registered at Gibsons Beach can be related to the oblique compression associated with the development of the Australian-Pacific plate boundary through New Zealand at about this time and coincide with overthrusting of basement into Taranaki Basin between mid-Waitakian (earliest Miocene) and Altonian (late Early Miocene) times

Newspaper Clipping | Three obituaries for Martha Steele, May 1911

(1) Type-written copy of two obituaries for Martha Greer Steele [“known as Mat, sister of Mary Darthula Greer Caldwell] from the Alabama Courier and Limestone Democrat (2) Newspaper clipping of obituary from the Fayetteville Observer, May 24-25, 1911.https://digitalcommons.jsu.edu/lib_ac_caldwell/1253/thumbnail.jp

Contrasting carbonate depositional systems for Pliocene cool-water limestones cropping out in central Hawke's Bay, New Zealand

Pliocene limestone formations in central Hawke's Bay (eastern North Island, New Zealand) accumulated on and near the margins of a narrow forearc basin seaway within the convergent Australia/Pacific plate boundary zone. The active tectonic setting and varied paleogeographic features of the limestone units investigated, in association with probable glacioeustatic sea-level fluctuations, resulted in complex stratigraphic architectures and contrasting types of carbonate accumulation on either side of the seaway. Here, we recognise recurring patterns of sedimentary facies, and sequences and systems tracts bounded by key physical surfaces within the limestone sheets. The facies types range from Bioclastic (B) to Siliciclastic (S) end-members via Mixed (M) carbonate-siliciclastic deposits. Skeletal components are typical cool-water associations dominated by epifaunal calcitic bivalves, bryozoans, and especially barnacles. Siliciclastic contents vary from one formation to another, and highlight siliciclastic-rich limestone units in the western ranges versus siliciclastic-poor limestone units in the eastern coastal hills. Heterogeneities in facies types, stratal patterns, and also in diagenetic pathways between eastern and western limestone units are considered to originate in the coeval occurrence in different parts of the forearc basin of two main morphodynamic carbonate systems over time

Oolitic limestone and marine sandstone gravel aggregate Early life concrete and aggregate freeze/thaw test for durability

Oolitic limestone is one type of limestone which formed during the Jurassic period and can be found in large deposits in many areas of England. It can be used as coarse aggregate for concrete construction, however due to its porosity, it requires additional cement to maintain compressive strength, when compared to marine gravel (sandstone) concrete. Since freeze/thaw durability is one of the most common problems in temperate countries, this paper investigates the freeze/thaw resistance of Oolitic limestone itself and when used as a coarse aggregate in concrete. The washed oolitic limestone was freeze/thaw tested to BS EN 1367 -1 :2007 and conclusions were drawn. Sixteen concrete cubes (100 mm3) were made, 8 using Oolitic limestone as a coarse aggregate and another 8 using marine gravel. Two cubes (1 Oolitic limestone, 1 marine gravel aggregate concrete) were used in a compressive strength test after 3 days of curing, to establish the strength at which the concrete was subjected to freeze/thaw action and the remaining 14 cubes were subject to freeze/thaw cycles, to a maximum of 56 cycles as informed by BS CEN/TR 15177:2006. Compressive strength, percentage mass lost and pulse velocity were compared and the results showed an equal ability to resist freeze/thaw damage when comparing the marine aggregate and oolitic limestone. Normally, the main role of coarse aggregate in concrete is just to act as a filler which determines strength. However in the case of Oolitic limestone, which is composed mainly of calcite (calcium carbonate), further studies should be made both to determine the mineralogy and its behaviour chemically when exposed to cement paste

Influence of limestone filler and of the size of the aggregates on DEF

This experimental study aims to determine the effect of limestone filler on concrete expansion due to delayed ettringite formation (DEF). Different mortars made with different sizes and percentages of limestone filler and Portland cement CEM I 52.5N are conserved in water. The expansion of the specimens is measured. Results show that DEF is not inhibited by limestone filler. The kinetics and the amplitude of the swelling depend on the size of the limestone filler. The volume fraction of aggregates changes only the kinetics: the relation between swelling and water uptake depends only on the size of the aggregates.Comment: 16 pages, 9 figures, 4 table

The classification and management of limestone pavements - an endangered habitat

This thesis describes an in-depth study of limestone pavements across North West England and North Wales. The aim was to combine elements of geodiversity and biodiversity in order to create a holistic limestone pavement classification to inform future management. A field-based research protocol was used to assess a stratified random sample (46 pavements), accounting for approximately 10% of the limestone pavements in the geographical area. Detailed analyses of key elements are presented, along with important issues that continue to pose threats to this Annex One Priority Habitat. This research resulted in a comprehensive classification, using TWINSPAN analysis and Nonmetric Multidimensional Scaling, identifying six distinct holistic functional groups. The prime factors driving limestone pavement morphology, and hence the classification, were established to be lithology, proximity to structural fault, altitude and human intervention, particularly in terms of grazing intensity. Three upland, open limestone pavement classes were formed. Of these, the richest in terms of geodiversity and biodiversity was the group with the thickest bedding planes and hence the deepest grikes, typically greater than 1m. The class that was most species-poor was "at the highest altitude (above 450m), formed on the thin limestones of the Yoredales. These were characterised by shallow, wide grikes. The third upland limestone pavement group had mid-range grikes, generally 0.5-1m in depth, and small clints. Two wooded classes were identified. One was a lowland 'classic' wooded limestone pavement group with deep, narrow grikes and shallow soils. Indicator species included Juniperus communis and Taxus baccata. The second wooded group was situated proximal to a major structural fault. In this group the pavement dip ranged between 10°-40° with well-runnelled clints that were heavily moss-covered. The sixth group was low altitude, proximal to the coast, characterised by low moss growth, un-vegetated clints and the presence of Ulex europaeus. Conservation management was identified as key to the quality of the limestone pavement habitat and this thesis identifies best management practises and links these to the holistic limestone pavement classification. Finally, as a sample case study, this thesis presents mollusc species and diversity from eleven of the Yorkshire limestone pavements. Analysis establishes significant links between geodiversity and mollusc populations, with key drivers for mollusc communities echoing those of plant species on limestone pavement.Funded by the Yorkshire Dales National Park and the University of Chester

Early Neoproterozoic limestones from the Gwna Group, Anglesey

Limestone megaclasts up to hundreds of metres in size are present within the Gwna Group mélange, North Wales, UK. The mélange has been interpreted as part of a Peri-Gondwanan fore-arc accretionary complex although the age of deposition remains contentious, proposals ranging from Neoproterozoic to Early Ordovician. This paper uses strontium isotope chemostratigraphy to establish the age of the limestone blocks and thus provide a maximum age constraint on mélange formation. Results show that, although the carbonates are locally dolomitized, primary 87Sr/86Sr ratios can be identified and indicate deposition sometime between the late Tonian and earliest Cryogenian. This age is older than that suggested by stromatolites within the limestone and indicates that the limestone did not form as cap carbonate deposits

A study of nano-particle based silane consolidants for Globigerina limestone

This STEPS funded study focuses on the application of hybrid and nanoparticle loaded hybrid silane consolidants for the treatment of 'Franka' type Globigerina Limestone. Consolidants act by gluing the deteriorated stone material to the underlying healthy stone (Dukes, 1972; Gutt, 1973; Alessandrini et al., 1975; Garrod, 2001). The consolidants evaluated in this work were a laboratory prepared hybrid silane based on a mixture of tetraethylorthosilicate (TEOS) and 3-(glycidoxypropyl) trimethoxysilane (GPTMS), the same hybrid consolidant loaded with silica nanoparticles and GPTMS-modified silica nanoparticles. In addition, a consolidant based on the hydrolysis product of TEOS was also tested. Prepared consolidants were applied to Globigerina Limestone test blocks by complete immersion. Untreated stone block were used as benchmarks. Following application of the consolidants, half of the treated limestone blocks were subjected to accelerated weathering. Non-weathered and weathered limestone blocks were then characterised by optical and electron microscopy and the stone colour before and after treatment with consolidants was assessed by a colorimetric technique. The pore size distribution before and after application of the different consolidant treatments was assessed by Mercury Intrusion Porosimetry. A water absorption by capillarity technique was also carried out to assess how the water uptake rate into the limestone alters with the different treatments. The mechanical properties of the consolidated limestone blocks were assessed by resistance to sodium sulfate crystallisation. Microscopy observations showed that the consolidants penetrated the stone to different extents depending on the consolidant and the method of application. The hybrid consolidant on its own led to yellowing of the limestone but the addition of nanoparticles to the hybrid (modified or not) appeared to help restore the original colour of the stone. The porosity of the limestone was only marginally affected by the different treatments but the somewhat hydrophobic nature of the consolidants led to a disruption in the capillary flow of water into the limestone.peer-reviewe