55 research outputs found

    Factors Affecting the Emission of Monoterpenes from Red Pine ( Pinus densiflora

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    Clinical application of the Rey-Osterrieth Complex Figure Test for children with developmental disorders

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     本研究では,10 名の読みや書きなどの学習面に困難を抱える発達障害をともなう子ども にWechsler式知能検査およびRey-Osterrieth複雑図形検査(ROCF)を実施し,認知特性の 実態把握の過程におけるROCFの有用性を検討した。ROCFの記録には被検者の描画過程 をデータ化してパソコンに取り込むことのできるタッチペン (Inkling™) を用い,成績評価 には,描画の質的評価も含むBoston Qualitative Scoring System (BQSS) を用いた。 Wechsler式知能検査における知覚統合や知覚推理の下位検査の得点が良好であっても, ROCFにおいて構成力や描画過程に困難が少なからず認められ,これらは学習面における困 難の背景にある病態を反映したものと考えられた。また,本検査成績を検討する上で, BQSSの概要得点の1 つである組織構成,概要得点に含まれていないクラスター要素や細部 要素の配置の評価の重要性についても論じた

    A synthesis inversion to constrain global emissions of very short‐lived chlorocarbons, dichloromethane and perchloroethylene : dichloromethane, and perchloroethylene

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    Dichloromethane (CH2Cl2) and perchloroethylene (C2Cl4) are chlorinated very short lived substances (Cl-VSLS) with anthropogenic sources. Recent studies highlight the increasing influence of such compounds, particularly CH2Cl2, on the stratospheric chlorine budget and therefore on ozone depletion. Here, a multiyear global-scale synthesis inversion was performed to optimize CH2Cl2 (2006–2017) and C2Cl4 (2007–2017) emissions. The approach combines long-term surface observations from global monitoring networks, output from a three-dimensional chemical transport model (TOMCAT), and novel bottom-up information on prior industry emissions. Our posterior results show an increase in global CH2Cl2 emissions from 637 ± 36 Gg yr−1 in 2006 to 1,171 ± 45 Gg yr−1 in 2017, with Asian emissions accounting for 68% and 89% of these totals, respectively. In absolute terms, Asian CH2Cl2 emissions increased annually by 51 Gg yr−1 over the study period, while European and North American emissions declined, indicating a continental-scale shift in emission distribution since the mid-2000s. For C2Cl4, we estimate a decrease in global emissions from 141 ± 14 Gg yr−1 in 2007 to 106 ± 12 Gg yr−1 in 2017. The time-varying posterior emissions offer significant improvements over the prior. Utilizing the posterior emissions leads to modeled tropospheric CH2Cl2 and C2Cl4 abundances and trends in good agreement to those observed (including independent observations to the inversion). A shorter C2Cl4 lifetime, from including an uncertain Cl sink, leads to larger global C2Cl4 emissions by a factor of ~1.5, which in some places improves model-measurement agreement. The sensitivity of our findings to assumptions in the inversion procedure, including CH2Cl2 oceanic emissions, is discussed

    A global-scale map of isoprene and volatile organic iodine in surface seawater of the Arctic, Northwest Pacific, Indian, and Southern Oceans

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    Isoprene (C5H8) and three volatile organic iodine compounds (VOIs: CH3I, C2H5I, and CH2ClI) in surface seawater were measured in the western Arctic, Northwest Pacific, Indian, and Southern Oceans during the period 2008-2012. These compounds are believed to play an important role in the marine atmospheric chemistry after their emission. The measurements were performed with high time-resolution (1-6 h intervals) using an online equilibrator gas chromatography mass spectrometer. C5H8 was most abundant in high-productivity transitional waters and eutrophic tropical waters. The chlorophyll-a normalized production rates of C5H8 were high in the warm subtropical and tropical waters, suggesting the existence of a high emitter of C5H8 in the biological community of the warm waters. High concentrations of the three VOIs in highly productive transitional water were attributed to biological productions. For CH3I, the highest concentrations were widely distributed in the basin area of the oligotrophic subtropical NW Pacific, probably due to photochemical production and/or high emission rates from phytoplankton. In contrast, the lowest concentrations of C2H5I in subtropical waters were attributed to photochemical removal. Enhancement of CH2ClI concentrations in the shelf-slope areas of the Chukchi Sea and the transitional waters of the NW Pacific in winter suggested that vertical mixing with subsurface waters by regional upwelling or winter cooling acts to increase the CH2ClI concentrations in surface layer. Sea-air flux calculations revealed that the fluxes of CH2ClI were the highest among the three VOIs in shelf-slope areas; the CH3I flux was highest in basin areas
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