Soils of Boone county

"May, 1951.""Prepared by University of Missouri, College of Agriculture, Dept. of Soils.

Graphitization of small carbonate samples for paleoceanographic research at the godwin radiocarbon laboratory, University of Cambridge

AbstractA new radiocarbon preparation facility was set up in 2010 at the Godwin Laboratory for Palaeoclimate Research, at the University of Cambridge. Samples are graphitized via hydrogen reduction on an iron powder catalyst before being sent to the Chrono Centre, Belfast, or the Australian National University for accelerator mass spectrometry (AMS) analysis. The experimental setup and procedure have recently been developed to investigate the potential for running small samples of foraminiferal carbonate. By analyzing background values of samples ranging from 0.04 to 0.6 mg C along with similar sized secondary standards, the setup and experimental procedures were optimized for small samples. “Background” modern 14C contamination has been minimized through careful selection of iron powder, and graphitization has been optimized through the use of “small volume” reactors, allowing samples containing as little as 0.08 mg C to be graphitized and accurately dated. Graphitization efficiency/fractionation is found not to be the main limitation on the analysis of samples smaller than 0.07 mg C, which rather depends primarily on AMS ion beam optics, suggesting further improvements in small sample analysis might yet be achieved with our methodology.We would like to thank James Rolfe for running the stable isotope measurements, as well as the Royal Society and NERC grant NE/L006421/1 for research support.This is the author accepted manuscript. The final version is available from Cambridge University Press via http://dx.doi.org/10.1017/RDC.2015.

Radiocarbon constraints on the glacial ocean circulation and its impact on atmospheric CO2

While the ocean’s large-scale overturning circulation is thought to have been significantly different under the climatic conditions of the Last Glacial Maximum (LGM), the exact nature of the glacial circulation and its implications for global carbon cycling continue to be debated. Here we use a global array of ocean–atmosphere radiocarbon disequilibrium estimates to demonstrate a ∼689±53 14C-yr increase in the average residence time of carbon in the deep ocean at the LGM. A predominantly southern-sourced abyssal overturning limb that was more isolated from its shallower northern counterparts is interpreted to have extended from the Southern Ocean, producing a widespread radiocarbon age maximum at mid-depths and depriving the deep ocean of a fast escape route for accumulating respired carbon. While the exact magnitude of the resulting carbon cycle impacts remains to be confirmed, the radiocarbon data suggest an increase in the efficiency of the biological carbon pump that could have accounted for as much as half of the glacial–interglacial CO2 change

Atlantic Ocean ventilation changes across the last deglaciation and their carbon cycle implications

Changes in ocean ventilation, controlled by both overturning rates and air‐sea gas exchange, are thought to have played a central role in atmospheric CO2 rise across the last deglaciation. Here we constrain the nature of Atlantic Ocean ventilation changes over the last deglaciation using radiocarbon and stable carbon isotopes from two depth transects in the Atlantic basin. Our findings broadly cohere with the established pattern of deglacial Atlantic overturning change, and underline the existence of active northern sourced deep‐water export at the Last Glacial Maximum (LGM). We find that the western Atlantic was less affected by incursions of southern‐sourced deep water, as compared to the eastern Atlantic, despite both sides of the basin being strongly influenced by the air‐sea equilibration of both northern‐ and southern deep‐water end‐members. Ventilation at least as strong as modern is observed throughout the Atlantic during the Bølling‐Allerød (BA), implying a ‘flushing’ of the entire Atlantic water column that we attribute to the combined effects of AMOC reinvigoration and increased air‐sea equilibration of southern sourced deep‐water. This ventilation ‘overshoot’ may have counteracted a natural atmospheric CO2 decline during interstadial conditions, helping to make the BA a ‘point of no return’ in the deglacial process. While the collected data emphasize a predominantly indirect AMOC contribution to deglacial atmospheric CO2 rise, via far field impacts on convection in the Southern Ocean and/or North Pacific during HS1 and the YD, the potential role of the AMOC in centennial CO2 pulses emerges as an important target for future work

Intra-trackway morphological variations due to substrate consistency: the El Frontal dinosaur tracksite (Lower Cretaceous, Spain).

An ichnological and sedimentological study of the El Frontal dinosaur tracksite (Early Cretaceous, Cameros basin, Soria, Spain) highlights the pronounced intra-trackway variation found in track morphologies of four theropod trackways. Photogrammetric 3D digital models revealed various and distinct intra-trackway morphotypes, which reflect changes in footprint parameters such as the pace length, the track length, depth, and height of displacement rims. Sedimentological analyses suggest that the original substrate was non-homogenous due to lateral changes in adjoining microfacies. Multidata analyses indicate that morphological differences in these deep and shallow tracks represent a part of a continuum of track morphologies and geometries produced by a gradient of substrate consistencies across the site. This implies that the large range of track morphologies at this site resulted from similar trackmakers crossing variable facies. The trackways at the El Frontal site present an exemplary case of how track morphology, and consequently potential ichnotaxa, can vary, even when produced by a single trackmaker