Re‐analysis of late Quaternary dust mass accumulation rates in Serbia using new luminescence chronology for loess–palaeosol sequence at Surduk

Despite numerous palaeoenvironmental investigations of loess–palaeosol sequences across the Carpathian Basin, well‐dated high‐resolution records are scarce. This paper presents a new high‐resolution chronology for the loess‐palaeosol sequence at Surduk (Serbia), based on optically stimulated luminescence (quartz) and post‐infrared infrared stimulated luminescence (polymineral) dating. The presented record spans 53–19 ka, with primary loess deposition occurring after 52±2 ka, and differs from previously published chronologies that relied on less precise and now superseded dating protocols. Based on the new chronology, mass accumulation rates (MAR s) for Surduk were constructed and compared with sites in the Carpathian Basin. The results demonstrate that accumulation periods across this area are not consistent in timing or rates. The high‐resolution dating strategy identifies a disturbance in sediment deposition that occurred after 45±2 ka and implies that site contains a hiatus. Finally, we show samples that failed routine dose recovery and preheat plateau tests, and had low fast ratios. Supported by bulk sample geochemical analysis it is proposed that a potential abrupt source shift, during the Last Glacial Maximum, may be the cause of the anomalous luminescence behaviour

Simultaneous and extensive removal of the East Asian lithospheric root

Much evidence points to a dramatic thinning of East Asian lithosphere during the Mesozoic, but with little precision on when, or over what time scale. Using geochemical constraints, we examine an extensive compilation of dated volcanic samples from Russia, Mongolia and North China to determine when the lithosphere thinned and how long that process took. Geochemical results suggest that magmatism before 107 Ma derived from metasomatised subcontinental lithospheric mantle (SCLM), whereas after 107 Ma, melt predominantly derived from an asthenospheric source. The switch to an asthenospheric magma source at ~107 Ma occurred in both Mongolia and North China (>1600 km apart), whereas in eastern Russia the switch occurred a little later (~85 Ma). Such a dramatic change to an asthenospheric contribution appears to have taken, from beginning to end, just ~30 Myrs, suggesting this is the duration for lithospheric mantle weakening and removal. Subsequent volcanism, through the Cenozoic in Mongolia and North China does not appear to include any contribution from the removed SCLM, despite melts predominantly deriving from the asthenosphere

Evidence for southward subduction of the Mongol-Okhotsk oceanic plate: Implications from Mesozoic adakitic lavas from Mongolia

A combination of new 40Ar/39Ar dating results, major- and trace-element data, plus Sr-Nd-Pb-Hf isotope data, are used to investigate the petrogenesis of Triassic high-Si adakite (HSA), Cretaceous low-Si adakite-like (LSA) lavas, and Cretaceous high-K and shoshonitic trachyandesite lavas, from eastern and south-central Mongolia. All samples are light rare-earth element and large-ion lithophile element enriched but depleted in some high-field strength elements (notably Nb, Ta and Ti). Two alternative models are proposed to explain the petrogenesis of the HSA samples. (1) A southward-subducting Mongol-Okhotsk slab underwent partial melting in the Triassic during the closure of the Mongol-Okhotsk Ocean, with the resultant melts assimilating mantle and crustal material. Alternatively (2), a basaltic underplate of thickened (>50 km; >1.5 GPa), eclogitic lower crust foundered into the underlying mantle, and underwent partial melting with minor contamination from mantle material and some shallow-level crustal contamination. The LSA samples are interpreted as melts derived from a lithospheric mantle wedge that was previously metasomatised by slab melts. Similarly, the trachyandesite lavas are interpreted as melts deriving from a subduction-enriched subcontinental lithospheric mantle. The spatial distribution of these samples implies that metasomatism likely occurred due to a southward-subducting Mongol-Okhotsk slab associated with the closure of the Mongol-Okhotsk Ocean. When this interpretation is combined with previous evidence for a northward-subducting Mongol-Okhotsk slab it advocates that the Mongol-Okhotsk Ocean closed with double-sided subduction

Vestiges of the proto-Caribbean seaway: origin of the San Souci Volcanic Group, Trinidad

Outcrops of volcanic–hypabyssal rocks in Trinidad document the opening of the proto-Caribbean seaway during Jurassic–Cretaceous break-up of the Americas. The San Souci Group on the northern coast of Trinidad comprises the San Souci Volcanic Formation (SSVF) and passive margin sediments of the ~ 130–125 Ma Toco Formation. The Group was trapped at the leading edge of the Pacific-derived Caribbean Plate during the Cretaceous–Palaeogene, colliding with the para-autochthonous margin of Trinidad during the Oligocene–Miocene. In-situ U–Pb ion probe dating of micro-zircons from a mafic volcanic breccia reveal the SSVF crystallised at 135.0 ± 7.3 Ma. The age of the SSVF is within error of the age of the Toco Formation. Assuming a conformable contact, geodynamic models indicate a likely origin for the SSVF on the passive margin close to the northern tip of South America. Immobile element and Nd–Hf radiogenic isotope signatures of the mafic rocks indicate the SSVF was formed by ≪10% partial melting of a heterogeneous spinel peridotite source with no subduction or continental lithospheric mantle component. Felsic breccias within the SSVF are more enriched in incompatible elements, with isotope signatures that are less radiogenic than the mafic rocks of the SSVF. The felsic rocks may be derived from re-melting of mafic crust. Although geochemical comparisons are drawn here with proto-Caribbean igneous outcrops in Venezuela and elsewhere in the Caribbean more work is needed to elucidate the development of the proto-Caribbean seaway and its rifted margins. In particular, ion probe dating of micro-zircons may yield valuable insights into magmatism and metamorphism in the Caribbean, and in altered basaltic terranes more generally

Magmatic fluids implicated in the formation of propylitic alteration: oxygen, hydrogen, and strontium isotope constraints from the Northparkes porphyry Cu-Au district, New South Wales, Australia

In porphyry ore deposit models, the propylitic alteration facies is widely interpreted to be caused by convective circulation of meteoric waters. However, recent field-based and geochemical data suggest that magmatic-derived fluids are likely to contribute to development of the propylitic assemblage. In order to test this hypothesis, we determined the oxygen and hydrogen isotope compositions of propylitic mineral separates (epidote, chlorite, and quartz), selected potassic mineral separates (quartz and magnetite), and quartz-hosted fluid inclusions from around the E48 and E26 deposits in the Northparkes porphyry Cu-Au district, New South Wales, Australia. In addition, the strontium isotope composition of epidote was determined to test for the potential contribution of seawater in the Northparkes system given the postulated island-arc setting and submarine character of some country rocks. Oxygen isotope geothermometry calculations indicate potassic alteration occurred between ~600° and 700°C in magmatic/mineralized centers, persisting to ~450°C upon lateral transition into propylitic alteration. Across the propylitic facies, temperature progressively decreased outward to <250°C. These temperature estimates and additional data from chlorite geothermometry were utilized to calculate the oxygen and hydrogen isotope composition of the fluid in equilibrium with the sampled minerals. Results show that propylitic fluids spanned a range of compositions with δ18O between 0.5 and 3.7‰ and δD between –49 and –17‰. Comparison of these results with the modeled compositions of meteoric and/or magmatic fluids during their evolution and isotopic exchange with local country rocks shows that a magmatic fluid component must exist across the propylitic halo during its formation. Strontium isotope data from propylitic epidote provide initial (based on formation at ~450 Ma) 87Sr/86Sr values in the range of 0.704099 to 0.704354, ruling out the presence of seawater as a second fluid in the system. Although we cannot exclude magmatic-meteoric mixing, especially toward the fringes of the system, our results support a model in which magmatic-derived fluid is the primary driver of propylitic alteration as it undergoes cooling and chemical equilibration during outward infiltration into country rocks. This is consistent with chemical mass transfer calculations for Northparkes and published chemical-thermodynamic models that only require a magmatic fluid for the production of propylitic assemblages. In view of this and supporting data from other deposits, we suggest that magmatic fluids are essential drivers of propylitic alteration in porphyry systems

Hf- and O-isotope data from detrital and granitoid zircons reveal characteristics of the Permian–Triassic magmatic belt along the Antarctic sector of Gondwana

Permian–Triassic strata in the Transantarctic Mountains and West Antarctica carry a significant detrital component derived from a contemporaneous magmatic belt along the Gondwana margin. Hf- and O-isotope characteristics were determined for near-contemporaneous (as shown by U-Pb zircon geochronology) detrital igneous zircons in Upper Permian and Triassic sandstones. Zircons from six granitoids in the contemporaneous magmatic belt were also analyzed for Hf and O isotopes in order to gain insight into the potential detrital zircon sources. Although the ages of these granitoids only loosely correspond with the depositional ages of the sandstones, the initial εHf and δ18O isotope compositions for these igneous zircon grains, in general, overlap those recorded for the detrital igneous zircon grains. Results demonstrate a range of εHf and δ18O values. Features of particular interest are the very low δ18O values in two of the granitoids, and similar low values also recorded in the detrital igneous zircons in two sandstones. The distribution of Permian–Triassic granitoids must be much greater than is apparent from the existing outcrops in the extensively ice-covered region. The Permian and one of the Triassic granitoids have Hf-isotope characteristics similar to the Cretaceous granites and Devonian–Carboniferous plutons of West Antarctica, whereas the other Triassic granite differs from both. Importantly, the zircon isotopic data from the Permian–Triassic rocks suggest that an Hf-defined Upper Mesoproterozoic lithosphere underlies much of the magmatic belt

Caledonian hot zone magmatism in the “Newer Granites”: insight from the Cluanie and Clunes plutons, Northern Scottish Highlands

Scottish “Newer” Granites record the evolution of the Caledonides resulting from Iapetus subduction and slab breakoff during the Silurian-Devonian Scandian Orogeny, but relationships between geodynamics, petrogenesis and emplacement are incomplete. Laser ablation U-Pb results from magmatic zircons at the Cluanie Pluton (Northern Highlands) identify clusters of concordant Silurian data points. A cluster with a weighted mean 206Pb/238U age of 431.6 ± 1.3 Ma (2 confidence interval, n = 6) records emplacement whilst older points (clustered at 441.8 ± 2.3 Ma, n = 9) record deep crustal hot zone magmatism prior to ascent. The Cluanie Pluton, and its neighbour the ∼428 Ma Clunes tonalite, have adakite-like high Na, Sr/Y, La/Yb and low Mg, Ni and Cr characteristics, and lack mafic facies common in other “Newer Granites”. These geochemical signatures indicate the tapping of batches of homogenised, evolved magma from the deeper crust. The emplacement age of the Cluanie Pluton confirms volumetrically modest subduction-related magmatism occurred beneath the Northern Highlands before slab breakoff, probably as a result of crustal thickening during the ∼450 Ma Grampian 2 event. Extensive new in-situ geochemical-geochronological studies for this terrane may further substantiate the deep crustal hot zone model and the association between Caledonian magmatism and potentially metallogenesis. The term “Newer Granites” is outdated as it ignores the demonstrated relationships between magmatism, Scandian orogenesis and slab breakoff. Hence, “Caledonian intrusions” would be a more appropriate generic term to cover those bodies related to either Iapetus subduction or to slab breakoff

A mantle plume origin for the Palaeoproterozoic Circum-Superior Large Igneous Province

The Circum-Superior Large Igneous Province (LIP) consists predominantly of ultramafic-mafic lavas and sills with minor felsic components, distributed as various segments along the margins of the Superior Province craton. Ultramafic-mafic dykes and carbonatite complexes of the LIP also intrude the more central parts of the craton. Most of this magmatism occurred 1880 Ma. Previously a wide range of models have been proposed for the different segments of the CSLIP with the upper mantle as the source of magmatism. New major and trace element and Nd-Hf isotopic data reveal that the segments of the CSLIP can be treated as a single entity formed in a single tectonomagmatic environment. In contrast to most previous studies that have proposed a variety of geodynamic settings, the CSLIP is interpreted to have formed from a single mantle plume. Such an origin is consistent with the high MgO and Ni contents of the magmatic rocks, trace element signatures that similar to oceanic-plateaus and ocean island basalts and eNd-eHf isotopic signatures which are each more negative than those of the estimated depleted upper mantle at 1880 Ma. Further support for a mantle plume origin comes from calculated high degrees of partial melting, mantle potential temperatures significantly greater than estimated ambient Proterozoic mantle and the presence of a radiating dyke swarm. The location of most of the magmatic rocks along the Superior Province margins probably represents the deflection of plume material by the thick cratonic keel towards regions of thinner lithosphere at the craton margins. The primary magmas, generated by melting of the heterogeneous plume head, fractionated in magma chambers within the crust, and assimilated varying amounts of crustal material in the process

Volcanological and environmental controls on the Snowdon mineralization, North Wales, UK: a failed volcanogenic massive sulfide system in the Avalon Zone of the British Caledonides

The Snowdon caldera of North Wales is host to base metal sulfide-bearing veins and stockworks, mineralized breccias, disseminated sulfides, and localized zones of semi-massive to massive sulfide, with subordinate magnetite-rich veins. The late Ordovician host volcanic sequence accumulated in a shallow marine, back-arc environment in the Welsh Basin, which forms part of the Avalon Zone of the British and Irish Caledonides. New field evidence, sulfur isotopes, and U-Pb dating indicate that the Snowdon mineralization is genetically and temporally related to Late Ordovician magmatism and caldera formation. It is interpreted to represent volcanogenic pipe-style sulfide mineralization, resulting from focused hydrothermal fluids moving along caldera-related faults and simultaneous dispersal of fluids through the volcaniclastic pile. Sulfur isotope data suggest that, whilst a limited contribution of magmatic S cannot be ruled out, thermochemical reduction of contemporaneous Ordovician seawater sulfate was the dominant mechanism for sulfide production in the Snowdon system, resulting in a mean value of about 12‰ in both the host volcanic strata and the mineralized veins. Despite the tectonic setting being prospective for VMS deposits, strata-bound sulfide accumulations are absent in the caldera. This is attributed to the shallow water depths, which promoted boiling and the formation of sub-seafloor vein-type mineralization. Furthermore, the tectonic instability of the caldera and the high energy, shallow marine environment would have limited preservation of any seafloor deposits. The new U-Pb dates for the base (454.26 ± 0.35 Ma) and top (454.42 ± 0.45 Ma) of the host volcanic rocks, indicate that the Snowdon magmatic activity was short lived, which is likely to have limited the duration and areal extent of the ore-forming system. The absence of massive sulfide mineralization is consistent with the general paucity of economic VMS deposits in the Avalon Zone. Despite the highly prospective geological setting this study further illustrates the importance of volcanic facies mapping and associated paleo-environmental interpretations in VMS exploration

SUBA: the Arabidopsis Subcellular Database

Knowledge of protein localisation contributes towards our understanding of protein function and of biological inter-relationships. A variety of experimental methods are currently being used to produce localisation data that need to be made accessible in an integrated manner. Chimeric fluorescent fusion proteins have been used to define subcellular localisations with at least 1100 related experiments completed in Arabidopsis. More recently, many studies have employed mass spectrometry to undertake proteomic surveys of subcellular components in Arabidopsis yielding localisation information for ∼2600 proteins. Further protein localisation information may be obtained from other literature references to analysis of locations (AmiGO: ∼900 proteins), location information from Swiss-Prot annotations (∼2000 proteins); and location inferred from gene descriptions (∼2700 proteins). Additionally, an increasing volume of available software provides location prediction information for proteins based on amino acid sequence. We have undertaken to bring these various data sources together to build SUBA, a SUBcellular location database for Arabidopsis proteins. The localisation data in SUBA encompasses 10 distinct subcellular locations, >6743 non-redundant proteins and represents the proteins encoded in the transcripts responsible for 51% of Arabidopsis expressed sequence tags. The SUBA database provides a powerful means by which to assess protein subcellular localisation in Arabidopsis ()