Proceedings IMWA 2010

Abstract A research-grade passive treatment system was constructed to receive 1000 L/minute of mine water from abandoned boreholes (pH 5.95, net alkalinity 29 mg/L CaCO₃, Fe 192 mg/L, Zn 11 mg/L, Cd 17 μg/L, Pb 60 μg/L and As 64 μg/L). The 2-ha system includes an oxidation pond followed by parallel treatment trains of aerobic wetlands, vertical flow bioreactors, re-aeration ponds, and horizontal-flow limestone beds and a final polishing wetland. Final effluent waters had pH >7 and contained < 1 mg/L total Fe and < 0.1 mg/L total Zn, with concentrations of Cd, Pb and As below detectable limits. Key Words hard rock mining, metal mining, acid mine drainage, natural treatment systems Introduction This paper describes the initial evaluation of an innovative, ecologically engineered passive system designed to treat abandoned ferruginous Pb-Zn mine waters at the Tar Creek Superfund Site, part of the historic Tri-State Mining District (TSMD) of Oklahoma, Kansas and Missouri, USA. Significant quantities of Pb and Zn were produced from the TSMD from the 1890s through the 1960s. By the early 1970s when mining ceased, two and nine million tons of Pb and Zn, respectively, had been produced During mining, large capacity dewatering operations pumped approximately 50,000 m³ d⁻¹ of water from the mines (Reed et al. 1955). Upon decline and cessation of mining, groundwater began to accumulate in the mine voids. By late 1979, metal-rich waters began to discharge via artesian pressure into Tar Creek and its tributaries. The first documented discharges of mine drainage were at a location near southeast Commerce, OK (Oklahoma Water Resources Board 1983) and were subsequently identified for passive treatment implementation Methods For this study, periodic water quality and quantity data collection efforts for the subject discharges began in 1998, with regular monthly sampling beginning in 2004 and continuing to the present. The targeted discharges have circum-neutral pH (5.96 ± 0.06), total alkalinity of 405 ± 13 mg/L as CaCO₃ and combined flow rates of up to 1000 L/minute. Metals and sulfate concentrations are elevated above expected levels and degrade the receiving waters ). Design and construction details for the passive treatment system are summarized in Sydney, NS IMWA 2010 "Mine Water and Innovative Thinking" Wolkersdorfer & Freund Results and Discussion In the year of operation, the passive treatment system performed as designed from a water quality perspective ( Other metals of specific interest in these waters were Cd, Pb, and As. All three were removed to below detection limits (0.64, 19.5 and 22 µg/L, respectively) before the outflow of the second process units, presumably through sorptive processes. Although the vertical-flow bioreactors were designed to remove Cd and Pb as well as Zn, Cd and Pb rarely remained in measureable concentrations at this stage of the treatment system. The other trace metal found in significant concentrations in these waters was Ni. A small percentage (<10%) of Ni was removed through co-precipitation and sorption in Cell 1. However, the majority of Ni (≈ 95%) was removed via re- IMWA 2010 Sydney, NS "Mine Water and Innovative Thinking&quot

Low temperature time resolved photoluminescence in ordered and disordered Cu2ZnSnS4 single crystals

International audienc

Effects of sulphur and tin disulphide vapour treatments of Cu2ZnSnS(Se)4 absorber materials for monograin solar cells

AbstractThe aim of this study was to find a heat-treatment procedure for monograin powders using a controllable reactive gas phase to improve the CZTS(Se) crystal surface for effectively working p-n junctions. The influence of an isothermal treatment in S and SnS2 vapour on the parameters of monograin layer solar cells is depending on the CZTS(Se) initial composition. The efficiencies of solar cells improve continuously with increasing temperatures of the absorber materials’ post-annealing from 823 to 973K under constant sulphur vapour pressure of 100 Torr. The highest values of Jsc= 18.4mA/cm2 and Voc= 720mV were obtained for a device made from CZTS powder annealed at 1013K in SnS2 vapour

Ligand-specific allosteric coupling controls G-protein-coupled receptor signaling

Allosteric coupling describes a reciprocal process whereby G-protein-coupled receptors (GPCRs) relay ligand-induced conformational changes from the extracellular binding pocket to the intracellular signaling surface. Therefore, GPCR activation is sensitive to both the type of extracellular ligand and intracellular signaling protein. We hypothesized that ligand-specific allosteric coupling may result in preferential (i.e., biased) engagement of downstream effectors. However, the structural basis underlying ligand-dependent control of this essential allosteric mechanism is poorly understood. Here, we show that two sets of extended muscarinic acetylcholine receptor M(1) agonists, which only differ in linker length, progressively constrain receptor signaling. We demonstrate that stepwise shortening of their chemical linker gradually hampers binding pocket closure, resulting in divergent coupling to distinct G-protein families. Our data provide an experimental strategy for the design of ligands with selective G-protein recognition and reveal a potentially general mechanism of ligand-specific allosteric coupling