Cellular Adhesion to Carbon Nanotubes-anchored Oligonucleotide: Electro-chemical Detection

In the study a new biosensor contained an oligonucleotide-carbon nanotubes-stearic acid monocrystalline clusters in its sensitive coating has been developed. The electrochemical characteristics of sensors with different coatings distinguishing by content of oligonucleotide and cerium ions have been measured. It was found that the presence of Ce in the coating leads to decrease of sensor capacity changes at measurements in mediums of different content. The oligonucleotides anchored in sensor coating attenuate cell nonantisense adhesion to sensor surface. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3547

Price assymetry in the Dutch retail gasoline market

This paper analyses retail price adjustments in the Dutch gasoline market. We estimate an asymmetric error correction model on weekly price changes for the years 1996 to 2001. We construct five datasets, one for each working day. The conclusions on asymmetric pricing are shown to differ over these datasets, suggesting that the choice of the day for which prices are observed matters more than commonly believed. In our view, the insufficient robustness of outcomes might explain the mixed conclusions found in the literature. Using two approaches, we also show that the effect of asymmetry on Dutch consumer costs is negligible

Modeling of GERDA Phase II data

The GERmanium Detector Array (Gerda) experiment at the Gran Sasso underground laboratory (LNGS) of INFN is searching for neutrinoless double-beta (0\u3bd\u3b2\u3b2) decay of 76Ge. The technological challenge of Gerda is to operate in a \u201cbackground-free\u201d regime in the region of interest (ROI) after analysis cuts for the full 100 kg\ub7yr target exposure of the experiment. A careful modeling and decomposition of the full-range energy spectrum is essential to predict the shape and composition of events in the ROI around Q\u3b2\u3b2 for the 0\u3bd\u3b2\u3b2 search, to extract a precise measurement of the half-life of the double-beta decay mode with neutrinos (2\u3bd\u3b2\u3b2) and in order to identify the location of residual impurities. The latter will permit future experiments to build strategies in order to further lower the background and achieve even better sensitivities. In this article the background decomposition prior to analysis cuts is presented for Gerda Phase II. The background model fit yields a flat spectrum in the ROI with a background index (BI) of 16.04 120.85+0.78\ub710 123 cts/(keV\ub7kg\ub7yr) for the enriched BEGe data set and 14.68 120.52+0.47\ub710 123 cts/(keV\ub7kg\ub7yr) for the enriched coaxial data set. These values are similar to the one of Phase I despite a much larger number of detectors and hence radioactive hardware components

Direct detection of chlorosilylene and time resolved study of some of its reactions in the gas-phase using a new photochemical precursor

Chlorosilylene, ClSiH, was prepared by 193 nm laser flash photolysis of 1-chloro-1-silacyclopent-3-ene in the gas phase. ClSiH was monitored in real time at 457.9 nm using a CW argon ion laser. The kinetics of reactions of ClSiH with C2H4, CH2 = CHCMe3, C2H2, Me2O, SO2, HCl, MeSiH3, Me2SiH2, Me3SiH, MeGeH3, MeGeH3 and precursor have been studied at ambient temperatures for the first time. Addition reactions of ClSiH and reactions with lone pair donors are faster than insertion reactions. Surprisingly ClSiH inserts faster into Si-H than Ge-H bonds. ClSiH is intermediate in reactivity between SiH2 and SiCI2. Relative reactivities of CISiH and SiH2 vary considerably. (c) 2005 Elsevier B.V. All rights reserved

Upconversion of Reductants

International audienc

INVESTIGATION OF ELECTRICAL EXPLOSION OF CYLINDRICAL FOILS IN AIR. COAXIAL HIGH-CURRENT DISCHARGES

No abstract availabl

Direct time-resolved study of the gas-phase reactions of germylene with ethyl- and diethylgermane: absolute rate constants, temperature dependences, and mechanism

Time-resolved studies of germylene, GeH2, generated by the 193 nm laser flash photolysis of 3,4-dimethyl-1-germacyclopent-3-ene, have been carried out to obtain rate constants for its bimolecular reactions with ethyl- and diethylgermanes in the gas phase. The reactions were studied over the pressure range 1-100 Torr with SF6 as bath gas and at five temperatures in the range 297-564 K. Only slight pressure dependences were found for GeH2 + EtGeH3 (399, 486, and 564 K). The high pressure rate constants gave the following Arrhenius parameters: for GeH2 + EtGeH3, log A = -10.75 +/- 0.08 and E-a = -6.7 +/- 0.6 kJ mol(-1); for GeH2 + Et2GeH2, log A = -10.68 +/- 0.11 and E-a = -6.95 +/- 0.80 kJ mol(-1). These are consistent with fast, near collision-controlled, association processes at 298 K. RRKM modeling calculations are, for the most part, consistent with the observed pressure dependence of GeH2 + EtGeH3. The ethyl substituent effects have been extracted from these results and are much larger than the analogous methyl substituent effects in the SiH2 + methylsilane reaction series. This is consistent with a mechanistic model for Ge-H insertion in which the intermediate complex has a sizable secondary barrier to rearrangement