PRIVAFRAME: A Frame-Based Knowledge Graph for Sensitive Personal Data

The pervasiveness of dialogue systems and virtual conversation applications raises an important theme: the potential of sharing sensitive information, and the consequent need for protection. To guarantee the subject’s right to privacy, and avoid the leakage of private content, it is important to treat sensitive information. However, any treatment requires firstly to identify sensitive text, and appropriate techniques to do it automatically. The Sensitive Information Detection (SID) task has been explored in the literature in different domains and languages, but there is no common benchmark. Current approaches are mostly based on artificial neural networks (ANN) or transformers based on them. Our research focuses on identifying categories of personal data in informal English sentences, by adopting a new logical-symbolic approach, and eventually hybridising it with ANN models. We present a frame-based knowledge graph built for personal data categories defined in the Data Privacy Vocabulary (DPV). The knowledge graph is designed through the logical composition of already existing frames, and has been evaluated as background knowledge for a SID system against a labeled sensitive information dataset. The accuracy of PRIVAFRAME reached 78%. By comparison, a transformer-based model achieved 12% lower performance on the same dataset. The top-down logical-symbolic frame-based model allows a granular analysis, and does not require a training dataset. These advantages lead us to use it as a layer in a hybrid model, where the logical SID is combined with an ANNs SID tested in a previous study by the authors

Decoherence window and electron-nuclear cross-relaxation in the molecular magnet V 15

Rabi oscillations in the V_15 Single Molecule Magnet (SMM) embedded in the surfactant DODA have been studied at different microwave powers. An intense damping peak is observed when the Rabi frequency Omega_R falls in the vicinity of the Larmor frequency of protons w_N, while the damping time t_R of oscillations reaches values 10 times shorter than the phase coherence time t_2 measured at the same temperature. The experiments are interpreted by the N-spin model showing that t_R is directly associated with the decoherence via electronic/nuclear spin cross-relaxation in the rotating reference frame. It is shown that this decoherence is accompanied with energy dissipation in the range of the Rabi frequencies w_N - sigma_e < Omega_R < w_N, where sigma_e is the mean super-hyperfine field (in frequency units) induced by protons at SMMs. Weaker damping without dissipation takes place outside this dissipation window. Simple local field estimations suggest that this rapid cross-relaxation in resonant microwave field observed for the first time in SMMV_15 should take place in other SMMs like Fe_8 and Mn_12 containing protons, too

Spin-to-charge conversion using Rashba coupling at the interface between non-magnetic materials

The Rashba effect is an interaction between the spin and the momentum of electrons induced by the spin-orbit coupling (SOC) in surface or interface states. Its potential for conversion between charge and spin currents has been theoretically predicted but never clearly demonstrated for surfaces or interfaces of metals. Here we present experiments evidencing a large spin-charge conversion by the Bi/Ag Rashba interface. We use spin pumping to inject a spin current from a NiFe layer into a Bi/Ag bilayer and we detect the resulting charge current. As the charge signal is much smaller (negligible) with only Bi (only Ag), the spin-to-charge conversion can be unambiguously ascribed to the Rashba coupling at the Bi/Ag interface. This result demonstrates that the Rashba effect at interfaces can be used for efficient charge-spin conversion in spintronics

Crossover from spin accumulation into interface states to spin injection in the germanium conduction band

Electrical spin injection into semiconductors paves the way for exploring new phenomena in the area of spin physics and new generations of spintronic devices. However the exact role of interface states in spin injection mechanism from a magnetic tunnel junction into a semiconductor is still under debate. In this letter, we demonstrate a clear transition from spin accumulation into interface states to spin injection in the conduction band of $n$-Ge. We observe spin signal amplification at low temperature due to spin accumulation into interface states followed by a clear transition towards spin injection in the conduction band from 200 K up to room temperature. In this regime, the spin signal is reduced down to a value compatible with spin diffusion model. More interestingly, we demonstrate in this regime a significant modulation of the spin signal by spin pumping generated by ferromagnetic resonance and also by applying a back-gate voltage which are clear manifestations of spin current and accumulation in the germanium conduction band.Comment: 5 pages, 4 figure

Quantum simulations and experiments on Rabi oscillations of spin qubits: intrinsic {\sl vs} extrinsic damping

Electron Paramagnetic Resonance experiments show that the decay of Rabi oscillations of ensembles of spin qubits depends noticeably on the microwave power and more precisely on the Rabi frequency, an effect recently called "driven decoherence". By direct numerical solution of the time-dependent Schr\"odinger equation of the associated many-body system, we scrutinize the different mechanisms that may lead to this type of decoherence. Assuming the effects of dissipation to be negligible ($T_1=\infty$), it is shown that a system of dipolar-coupled spins with -- even weak-- random inhomogeneities is sufficient to explain the salient features of the experimental observations. Some experimental examples are given to illustrate the potential of the numerical simulation approach.Comment: Accepted for publication in Physical Review

Environmental effects on quantum relaxation and coherent dynamics in rare-earths ions

This work provides new developments of the field of spin dynamics in mesoscopic systems. We first discuss, by a few examples, how environmental degrees of freedom affect tunneling and subsequent slow quantum relaxation of large molecule spins (such as Mn 12-AC) or rare-earth (RE) spins (such as Ho diluted in YLiF 4) showing two different facets of the spin bath model. The case of low molecule spins (V 15) is also considered. Then we discuss AC-susceptibility experiments performed on YLiF 4:Ho 3+ allowing to clarify the roles played by the phonon and the spin baths on single-ion and two-ion electro-nuclear tunneling. In the last part, we extend these quantum dynamical studies to the case of Er diluted in CaWO 4 where the spin and phonon baths are weak enough to allow fast and coherent quantum dynamics with the observation of Rabi oscillations. The angular momentum and magnetic moment of Er, J=15/2and 9 μ B, are comparable to those of large molecule spins, implying easy manipulations of potential RE solid-state qubits. © 2006 Elsevier B.V. All rights reserved

Spin-pumping into surface states of topological insulator {\alpha}-Sn, spin to charge conversion at room temperature

We present experimental results on the conversion of a spin current into a charge current by spin pumping into the Dirac cone with helical spin polarization of the elemental topological insulator (TI) {\alpha}-Sn[1-3]. By angle-resolved photoelectron spectroscopy (ARPES) we first confirm that the Dirac cone at the surface of {\alpha}-Sn (0 0 1) layers subsists after covering with Ag. Then we show that resonant spin pumping at room temperature from Fe through Ag into {\alpha}-Sn layers induces a lateral charge current that can be ascribed to the Inverse Edelstein Effect[4-5]. Our observation of an Inverse Edelstein Effect length[5-6] much longer than for Rashba interfaces[5-10] demonstrates the potential of the TI for conversion between spin and charge in spintronic devices. By comparing our results with data on the relaxation time of TI free surface states from time-resolved ARPES, we can anticipate the ultimate potential of TI for spin to charge conversion and the conditions to reach it.Comment: 14 pages, 5 figure

Pliocene colonization of the Mediterranean by Great White Shark inferred from fossil records, historical jaws, phylogeographic and divergence time analyses

Aim: Determine the evolutionary origin of the heretofore poorly characterized contemporary Great White Shark (GWS; Carcharodon carcharias) of the Mediterranean Sea, using phylogenetic and dispersal vicariance analyses to trace back its global palaeo-migration pattern. Location: Mediterranean Sea. Taxon: Carcharodon carcharias. Methods: We have built the largest mitochondrial DNA control region (CR) sequence dataset for the Mediterranean GWS from referenced historical jaws spanning the 19th and 20th centuries. Mediterranean and global GWS CR sequences were analysed for genetic diversity, phylogenetic relationships and divergence time. A Bayes factor approach was used to assess two scenarios of GWS lineage divergence and emergence of the Mediterranean GWS line using fossil records and palaeo-geographical events for calibration of the molecular clock. Results: The results confirmed a closer evolutionary relationship between Mediterranean GWS and populations from Australia–New Zealand and the North-eastern Pacific coast rather than populations from South African and North-western Atlantic. The Mediterranean GWS lineage showed the lowest genetic diversity at the global level, indicating its recent evolutionary origin. An evaluation of various divergence scenarios determined the Mediterranean GWS lineage most likely appeared some 3.23 million years ago by way dispersal/vicariance from Australian/Pacific palaeo-populations. Main conclusion: Based on the fossil records, phylogeographic patterns and divergence time, we revealed that the Mediterranean GWS population originated in the Pliocene following the Messinian Salinity Crisis. Colonization of the Mediterranean by GWS likely occurred via an eastward palaeo-migration of Australian/eastern Pacific elements through the Central American Seaway, before the complete closure of the Isthmus of Panama. This Pliocene origin scenario contrasts with a previously proposed scenario in which Australian GWS colonized the Mediterranean via antipodean northward migration resulting from navigational errors from South Africa during Quaternary climatic oscillations

Decoherence window and electron-nuclear cross relaxation in the molecular magnet V 15

Rabi oscillations in the V 15 single molecule magnet embedded in the surfactant (CH 3) 2[CH 3(CH 2) 16CH 2] 2N + have been studied at different microwave powers. An intense damping peak is observed when the Rabi frequency Ω R falls in the vicinity of the Larmor frequency of protons ω N. The experiments are interpreted by a model showing that the damping (or Rabi) time τ R is directly associated with decoherence caused by electron-nuclear cross relaxation in the rotating reference frame. This decoherence induces energy dissipation in the range ω N-σ e<Ω R<ω N, where σ e is the mean superhyperfine field induced by protons at V 15. Weaker decoherence without dissipation takes place outside this window. Specific estimations suggest that this rapid cross relaxation in a resonant microwave field, observed for the first time in V 15, should also take place, e.g., in Fe 8 and Mn 12. © 2012 American Physical Society