Banana starch and molecular shear fragmentation dramatically increase structurally driven slowly digestible starch in fully gelatinized bread crumb

The role of native (NB) and extruded (EB) banana starch, and a 1:1 native:extruded banana starch composite (MB), in slowing down the starch digestibility of bread crumb and crust was investigated. During extrusion, the molecular weight of banana starch was reduced from 2.75x108 to 4.48x106 g/mol (HPSEC-MALS-RI). Results showed a slowly digestible starch (SDS) increase from 1.09 % (control) to 4.2, 6.6, and 7.76 % in NB, MB and EB crumbs (fully gelatinized), respectively. DSC data attributed this occurrence to the formation of supramolecular structures upon storage involving amylopectin branches (especially those from fragmented amylopectin in EB). The hedonic sensory test showed no differences in overall liking between MB, EB and control, validating feasibility of including banana in the formulation. For the first time, this study shows a molecular size reduction as a strategy to manufacture selected starches that result in highly gelatinized baked products rich in structurally driven SDS.European Regional Development Fund (FEDER) and the Spanish Ministry of Economy and Competitiveness (Project AGL2014-52928-C2

Point defects on graphene on metals

Understanding the coupling of graphene with its local environment is critical to be able to integrate it in tomorrow's electronic devices. Here we show how the presence of a metallic substrate affects the properties of an atomically tailored graphene layer. We have deliberately introduced single carbon vacancies on a graphene monolayer grown on a Pt(111) surface and investigated its impact in the electronic, structural and magnetic properties of the graphene layer. Our low temperature scanning tunneling microscopy studies, complemented by density functional theory, show the existence of a broad electronic resonance above the Fermi energy associated with the vacancies. Vacancy sites become reactive leading to an increase of the coupling between the graphene layer and the metal substrate at these points; this gives rise to a rapid decay of the localized state and the quenching of the magnetic moment associated with carbon vacancies in free-standing graphene layers

Más allá del acceso : ¿qué puede hacer la Internet por una mayor equidad social?

Texto paralelo en español y en inglé

Beyond connectivity : new information and communication technologies for social development

Parallel text in English and Spanis

Impact of the vine water status on the berry and seed phenolic composition of 'Merlot' (Vitis vinifera L.) cultivated in a warm climate: Consequence for the style of wine

During 2005 and 2006 four irrigation treatments were assayed in a vineyard growing 'Merlot' grapes located in a warm climate region. The treatments were kept for two years and the wine was produced the second year so that the response of the wines to water constraint was consistent. The phenolic parameters of the wines were analysed. The phenolic composition of the seeds was studied for both years and more significant differences were observed in the second. The results showed that when the deficiency increased, so did the concentration of total polyphenols, flavan-3-ols and tannins in the seeds. Pre-dawn leaf water constraint integrals between 20 and 24 Mpa as opposed to levels of 9 to 14 caused statistically significant increases in total polyphenols, flavan-3-ols and the colour index of the wine. These differences were manifested in sensory terms by significant intensification of the colour and body of the wines.

Lorentz invariance violation and the CPT-odd electromagnetic response of a tilted anisotropic Weyl semimetal

We derive the electromagnetic response of a particular fermionic sector in the minimal QED contribution to the Standard Model Extension (SME), which can be physically realized in terms of a model describing a tilted and anisotropic Weyl semimetal (WSM). The contact is made through the identification of the Dirac-like Hamiltonian resulting from the SME with that corresponding to the WSM in the linearized tight-binding approximation. We first calculate the effective action by computing the non-perturbative vacuum polarization tensor using thermal field theory techniques, focusing upon the corrections at finite chemical potential and zero temperature. Next, we confirm our results by a direct calculation of the anomalous Hall current within a chiral kinetic theory approach. In an ideal Dirac cone picture of the WSM (isotropic and non-tilted) such response is known to be governed by axion electrodynamics, with the space-time dependent axion angle $\Theta (\mathbf{r},t) = 2 (\mathbf{b} \cdot \mathbf{r} - b _{0} t)$, being $2 \mathbf{b}$ and $2b _{0}$ the separation of the Weyl nodes in momentum and energy, respectively. In this paper we demonstrate that the node tilting and the anisotropies induce novel corrections at a finite density which however preserve the structure of the axionic field theory. We apply our results to the ideal Weyl semimetal $\mathrm{EuCd}_{2}\mathrm{As}_{2}$ and to the highly anisotropic and tilted monopnictide $\mathrm{TaAs}$

Transcultural adaptation and validation of the Spanish language version of the questionnaire OQLQ for the assessment of quality of life in orthognathic patients

Orthognathic surgery is the cornerstone of the treatment of dentofacial deformities, which have a great psychological and social impact on the life of the patient. Patient satisfaction and the impact on quality of life have recently become clinical parameters of growing importance. The aim of this study was to undertake a transcultural adaptation, translation to Spanish and validation of this version of the questionnaire OQLQ, used to measure quality of life in the context of Spanish culture. Validation of the OQLQ questionnaire to the Spanish language was carried out through the methodology of translation and back translation, conceptual equivalence and piloting. The Spanish version was applied through a cross-sectional study to a total of 50 patients undergoing orthognathic surgery. The adapted and validated version showed adequate metric properties of reliability, change sensitivity and validity. In this study, a positive impact of orthognathic surgery on the specific quality of life was evident in 96% of patients, with an average improvement of 58% with respect to the initial score. Dentofacial deformities have a marked negative impact on the lives of patients, with orthognathic surgery being a therapeutic tool of great value in improving the quality of life in social, functional and aesthetic terms. The pilot test of this Spanish language version of the OQLQ proved valid for the assessment of quality of life in Spanish-speaking orthognathic patients or those with a Spanish culture

40Ar/39Ar laserprobe dating of mylonitic fabrics in a polyorogenic terrane of NW Iberia

The tectonothermal evolution of a polyorogenic terrane in the Variscan belt of NW Spain has been constrained by 40Ar/39Ar laserprobe incremental heating experiments on mylonitic fabrics developed in major structures. Transitional levels between HP–HT and IP upper units in the O´ rdenes Complex where metamorphic and structural records demonstrate two cycles of burial and exhumation were selected for dating. Two groups of ages have been defined: (1) Silurian–Early Devonian, obtained from mylonites of the Forna´s extensional detachment, here considered as the minimum age for the start of tectonic exhumation of the HP– HT units and an upper age-limit for the HP–HT event itself; (2) Early to Mid-Devonian, from structures related to the Variscan convergence in the area, which include top-to-the-east thrusts and extensional detachments. A single, younger Carboniferous age obtained from the uppermost allochthonous sequences possibly reflects the final stages of emplacement of the allochthonous complexes. Our data indicate a polyorogenic character for a part of the Iberian allochthonous complexes, including Variscan (sensu stricto) and Early Variscan convergence, as well as an older, Early Palaeozoic cycle