Millennial-scale fluctuations in Saharan dust supply across the decline of the African Humid Period

The Sahara is the world's largest dust source with significant impacts on trans-Atlantic terrestrial and large-scale marine ecosystems. Contested views about a gradual or abrupt onset of Saharan aridity at the end of the African Humid Period dominate the current scientific debate about the Holocene Saharan desiccation. In this study, we present a 19.63 m sediment core sequence from Lake Sidi Ali (Middle Atlas, Morocco) at the North African desert margin. We reconstruct the interaction between Saharan dust supply and Western Mediterranean hydro-climatic variability during the last 12,000 yr based on analyses of lithogenic grain-sizes, XRF geochemistry and stable isotopes of ostracod shells. A robust chronological model based on AMS 14C dated pollen concentrates supports our multi-proxy study. At orbital-scale there is an overall increase in southern dust supply from the Early Holocene to the Late Holocene, but our Northern Saharan dust record indicates that a gradual Saharan desiccation was interrupted by multiple abrupt dust increases before the ‘southern dust mode‘ was finally established at 4.7 cal ka BP. The Sidi Ali record features millennial peaks in Saharan dust increase at about 11.1, 10.2, 9.4, 8.2, 7.3, 6.6, 6.0, and 5.0 cal ka BP. Early Holocene Saharan dust peaks coincide with Western Mediterranean winter rain minima and North Atlantic cooling events. In contrast, Late Holocene dust peaks correspond mostly with prevailing positive phases of the North Atlantic Oscillation. By comparing with other North African records, we suggest that increases in Northern Saharan dust supply do not solely indicate sub-regional to regional aridity in Mediterranean Northwest Africa but might reflect aridity at a trans-Saharan scale. In particular, our findings support major bimillennial phases of trans-Saharan aridity at 10.2, 8.2, 6.0 and 4.2 cal ka BP. These phases coincide with North Atlantic cooling and a weak African monsoon.Christoph Zielhofer, Steffen Mischke and William Fletcher as principal investigators thank the German Research Foundation (DFG, ZI 721/9-1), the Federal Ministry of Education and Research (BMBF, 01DH17020) and the Natural Environment Research Council (New Investigator Award to W Fletcher, NE/K000608/1, and NERC RCF dating awards, 1765.1013 and 1809.0414) for generous funding of the fieldwork and lab analyses.Peer Reviewe

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Approaching Immobilization of Enzymes onto Open Porous Basotect®

For the first time, commercial macroporous melamine formaldehyde foam Basotect® (BT) was used as a basic carrier material for both adsorptive and covalent enzyme immobilization. In order to access inherent amino groups, the Basotect® surface was pretreated with hydrochloric acid. The resulting material revealed 6 nmol of superficial amino groups per milligram Basotect®. Different optimized strategies for tethering the laccase from Trametes versicolor and the lipase from Thermomyces lanuginosus onto the pre-treated Basotect® surface were studied. Particularly, for covalent immobilization, two different strategies were pursued: lipase was tethered via a cross-linking method using 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide, and laccase was bound after functionalizing Basotect® with hydrophilic copolymer poly(ethylene-alt-maleic anhydride) (PEMA). Prior to laccase immobilization, the PEMA coating of Basotect® was verified by ATR-FTIR analysis. Subsequent quantification of available high-reactive PEMA anhydride moieties revealed an amount of 1028 ± 73 nmol per mg Basotect®. The surface-bound enzyme amounts were quantified as 4.1–5.8 μg per mg Basotect®. A theoretical surface-covered enzyme mass for the ideal case that an enzyme monolayer was immobilized onto the Basotect® surface was calculated and compared to the amount of adsorptive and covalently bound enzymes before and after treatment with SDS. Furthermore, the enzyme activities were determined for the different immobilization approaches, and the stability during storage over time and against sodium dodecyl sulfate treatment was monitored. Additionally, PEMA-BT-bound laccase was tested for the elimination of anthropogenic micropollutant bisphenol A from contaminated water in a cost-effective and environmentally-friendly way and resulted in a degradation rate higher than 80%

Aeolian sediments on the north-eastern Tibetan Plateau

Aeolian sediments on the Tibetan Plateau are an important archive of palaeoclimatic information. This study presents a detailed analysis of sediments from the Donggi Cona catchment on the north-eastern part of the Tibetan Plateau. Long- and short-distance sediment transport leads to a complex pattern of aeolian sediment deposition that depends on climatic changes as well as on the availability of sediments. Based on the largest dataset of OSL datings (51) from a single catchment on the Tibetan Plateau so far, different periods of increased sediment transport have been reconstructed. Increased aeolian deposition in this high elevation environment started in the early Holocene with the accumulation of sands from around 10.5 to 7 ka. Loess sediments have been preserved from a period from 10.5 to 7.5 ka. Both archives are related to the strengthening of the Asian summer monsoons characterized by wetter and warmer climate. This change in climate supported the trapping of aeolian sediments. Under full monsoon conditions from around 9 ka onwards fluvial processes resulted in erosion of the aeolian archives and the formation of colluvial sediments until 6 ka. A dry and cooler climate resulted in the reactivation of dune sands from 3 ka to present, possibly in combination with stronger human influence. Aeolian sediments on the Tibetan Plateau therefore indicate two different climatic modes. During the early Holocene wetter conditions were favourable to retain aeolian sediments. The reactivation of sediment in the late Holocene due to small-scale disturbances in the vegetation cover, points to a cooler and drier climate