3,245 research outputs found
Models of genetic drift as limiting forms of the Lotka-Volterra competition model
The relationship between the Moran model and stochastic Lotka-Volterra
competition (SLVC) model is explored via timescale separation arguments. For
neutral systems the two are found to be equivalent at long times. For systems
with selective pressure, their behavior differs. It is argued that the SLVC is
preferable to the Moran model since in the SLVC population size is regulated by
competition, rather than arbitrarily fixed as in the Moran model. As a
consequence, ambiguities found in the Moran model associated with the
introduction of more complex processes, such as selection, are avoided.Comment: 5 pages, 4 figure
The surprising lability of bis(2,2’:6’,2’’-terpyridine)- chromium(III) complexes
The complex [Cr(tpy)(O3SCF3)3] (tpy = 2,2′:6′,2′′-terpyridine) is readily made from [Cr(tpy)Cl3] and is a convenient precursor to [Cr(tpy)2][PF6]3 and to [Cr(tpy)(4′-(4-tolyl)tpy)][PF6]3 and [Cr(tpy)(5,5′′-Me2tpy)][PF6]3 (4′-(4-tolyl)tpy = 4′-(4-tolyl)-2,2′:6′,2′′-terpyridine; 5,5′′-Me2tpy = 5,5′′-dimethyl-2,2′:6′,2′′-terpyridine); these are the first examples of heteroleptic bis(tpy) chromium(III) complexes. The single crystal structures of 2{[Cr(tpy)2][PF6]3}·5MeCN, [Cr(tpy)(4′-(4-tolyl)tpy)][PF6]3·3MeCN and [Cr(tpy)(5,5′′-Me2tpy)][PF6]3·3MeCN have been determined. Each cation contains the expected octahedral {Cr(tpy)2}3+ unit; in all three structures, the need to accommodate three anions per cation and the solvent molecules prevents the formation of a grid-like array of cations that is typical of many lattices containing {M(tpy)2}2+ motifs. Three reversible electrochemical processes are observed for [Cr(tpy)(4′-(4-tolyl)tpy)][PF6]3 and [Cr(tpy)(5,5′′-Me2tpy)][PF6]3, consistent with those documented for [Cr(tpy)2]3+. At pH 6.36, aqueous solutions of [Cr(tpy)2][PF6]3 are stable for at least two months. However, contrary to the expectations of the d3 Cr3+ ion being a kinetically inert metal centre, the tpy ligands in [Cr(tpy)2]3+are labile in the presence of base; absorption and 1H NMR spectroscopies have been used to monitor the effects of adding NaOH to aqueous and CD3OD solutions, respectively, of the homo- and heteroleptic complexes. Ligand dissociation is also observed when [Bu4N]F is added to CD3OD solutions of the complexes, but in aqueous solution, [Cr(tpy)2][PF6]3 is stable in the presence of fluoride ion
Decay Modes of Unstable Strings in Plane-Wave String Field Theory
The cubic interaction vertex of light-cone string field theory in the
plane-wave background has a simple effective form when considering states with
only bosonic excitations. This simple effective interaction vertex is used in
this paper to calculate the three string interaction matrix elements for states
of arbitrary bosonic excitation and these results are used to examine certain
decay modes on the mass-shell. It is shown that the matrix elements of one
string to two string decays involving only bosonic excitations will vanish to
all orders in 1/mu on the mass-shell when the number of excitations on the
initial string is less than or equal to two, but in general will not vanish
when the number of excitations is greater than two. Also, a truncated
calculation of the mass-shell matrix elements for one string to three string
decays of two excitation states is performed and suggests that these matrix
elements do not vanish on the mass-shell. There is, however, a quantitative
discrepancy between this last result and its (also non-vanishing) gauge theory
prediction from the BMN correspondence.Comment: 11 pages; v2: references added; v3: normalization of interaction
vertex and corresponding amplitudes changed by a factor of mu to reflect SFT
normalization (must now divide by mu to compare with BMN dual gauge theory),
and minor errors correcte
Predictions for PP-wave string amplitudes from perturbative SYM
The role of general two-impurity multi-trace operators in the BMN
correspondence is explored. Surprisingly, the anomalous dimensions of all
two-impurity multi-trace BMN operators to order g_2^2\lambda' are completely
determined in terms of single-trace anomalous dimensions. This is due to
suppression of connected field theory diagrams in the BMN limit and this fact
has important implications for some string theory processes on the PP-wave
background. We also make gauge theory predictions for the matrix elements of
the light-cone string field theory Hamiltonian in the two string-two string and
one string-three string sectors.Comment: 46 pages, 12 figures. V3:typos correcte
Recommended from our members
Complexation of lanthanides, actinides and transition metal cations with a 6-(1,2,4-triazin-3-yl)-2,2’:6’,2’’-terpyridine ligand: implications for actinide(III) /lanthanide(III) partitioning
The quadridentate N-heterocyclic ligand 6-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-yl)-2,2’:6’,2’’-terpyridine (CyMe4-hemi-BTBP) has been synthesized and its interactions with Am(III), U(VI), Ln(III) and some transition metal cations have been evaluated by X-ray crystallographic analysis, Am(III)/Eu(III) solvent extraction experiments, UV absorption spectrophotometry, NMR studies and ESI-MS. Structures of the 1:1 complexes with Eu(III), Ce(III) and the linear uranyl (UO22+) ion were obtained by X-ray crystallographic analysis, and showed similar coordination behavior to related BTBP complexes. In methanol, the stability constants of the Ln(III) complexes are slightly lower than those of the analogous quadridentate bis-triazine BTBP ligands, while the stability constant for the Yb(III) complex is higher. 1H NMR titrations and ESI-MS with lanthanide nitrates showed that the ligand forms only 1:1 complexes with Eu(III), Ce(III) and Yb(III), while both 1:1 and 1:2 complexes were formed with La(III) and Y(III) in acetonitrile. A mixture of isomeric chiral 2:2 helical complexes was formed with Cu(I), with a slight preference (1.4:1) for a single directional isomer. In contrast, a 1:1 complex was observed with the larger Ag(I) ion. The ligand was unable to extract Am(III) or Eu(III) from nitric acid solutions into 1-octanol, except in the presence of a synergist at low acidity. The results show that the presence of two outer 1,2,4-triazine rings is required for the efficient extraction and separation of An(III) from Ln(III) by quadridentate N-donor ligand
A Calculation of the plane wave string Hamiltonian from N=4 super-Yang-Mills theory
Berenstein, Maldacena, and Nastase have proposed, as a limit of the strong
form of the AdS/CFT correspondence, that string theory in a particular plane
wave background is dual to a certain subset of operators in the N=4
super-Yang-Mills theory. Even though this is a priori a strong/weak coupling
duality, the matrix elements of the string theory Hamiltonian, when expressed
in gauge theory variables, are analytic in the 't Hooft coupling constant. This
allows one to conjecture that, like the masses of excited string states, these
can be recovered using perturbation theory in Yang-Mills theory.
In this paper we identify the difference between the generator of scale
transformations and a particular U(1) R-symmetry generator as the operator dual
to the string theory Hamiltonian for nonvanishing string coupling. We compute
its matrix elements and find that they agree with the string theory prediction
provided that the state-operator map is modified for nonvanishing string
coupling. We construct this map explicitly and calculate the anomalous
dimensions of the new operators. We identify the component arising from the
modification of the state-operator map with the contribution of the string
theory contact terms to the masses of string states.Comment: 38 pages, Latex; v2: Comparison with string theory changed in light
of corrections to string theory results in hep-th/0206073 v3; state-operator
map modified; Physical interpretation and conclusions unchange
[Ir(C^N)2(N^N)]+ emitters containing a naphthalene unit within a linker between the two cyclometallating ligands
The synthesis of four cyclometallated [Ir(C^N) 2 (N^N)][PF 6 ] compounds in which N^N is a substituted 2,2’- -bipyridine (bpy) ligand and the naphthyl-centred ligand 2,7-bis(2-(2-(4-(pyridin-2-yl)phenoxy)ethoxy) ethoxy)naphthalene provides the two cyclometallating C^N units is reported. The iridium( III ) complexes have been characterized by 1 H and 13 C NMR spectroscopies, mass spectrometry and elemental analysis, and their electrochemical and photophysical properties are described. Comparisons are made with a model [Ir(ppy) 2 (N^N)][PF 6 ] compound (Hppy = 2-phenylpyridine). The complexes containing the naphthyl-unit exhibit similar absorption spectra and excitation at 280 nm leads to an orange emission. The incorporation of the naphthalene unit does not lead to a desirable blue contribution to the emission. Density functional theory calculations were performed to investigate the geometries of the complexes in their ground and first triplet excited states, as well as the energies and compositions of the highestoccupied and lowest unoccupied molecular orbital (HOMO and LUMO) manifolds. Trends in the HOMO– LUMO gaps agree with those observed electrochemically. The energy difference between the LUMO and the lowest unoccupied MO located on the naphthyl unit (LUMO+7) is large enough to explain why there is no contribution from the naphthyl-centred triplet excited state to the phosphorescence emission. Singlet excited states were also investigated. Light-emitting electrochemical cells (LECs) using the [Ir(C^N) 2 (N^N)][PF 6 ] and [Ir(ppy) 2 (N^N)][PF 6 ] complexes in the emissive layer were made and evaluated. The presence of the naphthyl-bridge between the cyclometallating units does not significantly alter the device response
Non-Abelian BIonic Brane Intersections
We study "fuzzy funnel" solutions to the non-Abelian equations of motion of
the D-string. Our funnel describes n^6/360 coincident D-strings ending on n^3/6
D7-branes, in terms of a fuzzy six-sphere which expands along the string. We
also provide a dual description of this configuration in terms of the world
volume theory of the D7-branes. Our work makes use of an interesting non-linear
higher dimensional generalization of the instanton equations.Comment: 17 pages uses harvmac; v2: small typos corrected, refs adde
Shine bright or live long: substituent effects in [Cu(N^N)(P^P)]+-based light-emitting electrochemical cells where N^N is a 6-substituted 2,2'-bipyridine
We report [Cu(P^P)(N^N)][PF6] complexes with P^P = bis(2-(diphenylphosphino)phenyl)ether (POP) or 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (xantphos) and N^N = 6-methyl-2,2′-bipyridine (Mebpy), 6-ethyl-2,2′-bipyridine (Etbpy), 6,6′-dimethyl-2,2′-bipyridine (Me2bpy) or 6-phenyl-2,2′-bipyridine (Phbpy). The crystal structures of [Cu(POP)(Phbpy)][PF6]·Et2O, [Cu(POP)(Etbpy)][PF6]·Et2O, [Cu(xantphos)(Me2bpy)][PF6], [Cu(xantphos)(Mebpy)][PF6]·CH2Cl2·0.4Et2O, [Cu(xantphos)(Etbpy)][PF6]·CH2Cl2·1.5H2O and [Cu(xantphos)(Phbpy)][PF6] are described; each copper(I) centre is distorted tetrahedral. In the crystallographically determined structures, the N^N domain in [Cu(xantphos)(Phbpy)]+ and [Cu(POP)(Phbpy)]+ is rotated ∼180° with respect to its orientation in [Cu(xantphos)(Mebpy)]+, [Cu(POP)(Etbpy)]+ and [Cu(xantphos)(Etbpy)]+; in each complex containing xantphos, the xanthene ‘bowl’ retains the same conformation in the solid-state structures. The two conformers resulting from the 180° rotation of the N^N ligand were optimized at the B3LYP-D3/(6-31G**+LANL2DZ) level and are close in energy for each complex. Variable temperature NMR spectroscopy evidences the presence of two conformers of [Cu(xantphos)(Phbpy)]+ in solution which are related by inversion of the xanthene unit. The complexes exhibit MLCT absorption bands in the range 378 to 388 nm, and excitation into each MLCT band leads to yellow emissions. Photoluminescence quantum yields (PLQYs) increase from solution to thin-film and powder; the highest PLQYs are observed for powdered [Cu(xantphos)(Mebpy)][PF6] (34%), [Cu(xantphos)(Etbpy)][PF6] (37%) and [Cu(xantphos)(Me2bpy)][PF6] (37%) with lifetimes of 9.6–11 μs. Density functional theory calculations predict that the emitting triplet (T1) involves an electron transfer from the Cu–P^P environment to the N^N ligand and therefore shows a 3MLCT character. T1 is calculated to be ∼0.20 eV lower in energy than the first singlet excited state (S1). The [Cu(P^P)(N^N)][PF6] ionic transition-metal (iTMC) complexes were tested in light-emitting electrochemical cells (LECs). Turn-on times are fast, and the LEC with [Cu(xantphos)(Me2bpy)][PF6] achieves a maximum efficacy of 3.0 cd A−1 (luminance = 145 cd m−2) with a lifetime of 1 h; on going to the [Cu(xantphos)(Mebpy)][PF6]-based LEC, the lifetime exceeds 15 h but at the expense of the efficacy (1.9 cd A−1). The lifetimes of LECs containing [Cu(xantphos)(Etbpy)][PF6] and [Cu(POP)(Etbpy)][PF6] exceed 40 and 80 h respectively
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