Near-arcsecond resolution observations of the hot corino of the solar type protostar IRAS 16293-2422

Complex organic molecules have previously been discovered in solar type protostars, raising the questions of where and how they form in the envelope. Possible formation mechanisms include grain mantle evaporation, interaction of the outflow with its surroundings or the impact of UV/X-rays inside the cavities. In this Letter we present the first interferometric observations of two complex molecules, CH3CN and HCOOCH3, towards the solar type protostar IRAS16293-2422. The images show that the emission originates from two compact regions centered on the two components of the binary system. We discuss how these results favor the grain mantle evaporation scenario and we investigate the implications of these observations for the chemical composition and physical and dynamical state of the two components.Comment: 5 pages (apjemulate), 2 figures; accepted by ApJ

The census of complex organic molecules in the solar type protostar IRAS16293-2422

Complex Organic Molecules (COMs) are considered crucial molecules, since they are connected with organic chemistry, at the basis of the terrestrial life. More pragmatically, they are molecules in principle difficult to synthetize in the harsh interstellar environments and, therefore, a crucial test for astrochemical models. Current models assume that several COMs are synthesised on the lukewarm grain surfaces ($\gtrsim$30-40 K), and released in the gas phase at dust temperatures $\gtrsim$100 K. However, recent detections of COMs in $\lesssim$20 K gas demonstrate that we still need important pieces to complete the puzzle of the COMs formation. We present here a complete census of the oxygen and nitrogen bearing COMs, previously detected in different ISM regions, towards the solar type protostar IRAS16293-2422. The census was obtained from the millimeter-submillimeter unbiased spectral survey TIMASSS. Six COMs, out of the 29 searched for, were detected: methyl cyanide, ketene, acetaldehyde, formamide, dimethyl ether, and methyl formate. The multifrequency analysis of the last five COMs provides clear evidence that they are present in the cold ($\lesssim$30 K) envelope of IRAS16293-2422, with abundances 0.03-2 $\times 10^{-10}$. Our data do not allow to support the hypothesis that the COMs abundance increases with increasing dust temperature in the cold envelope, as expected if COMs were predominately formed on the lukewarm grain surfaces. Finally, when considering also other ISM sources, we find a strong correlation over five orders of magnitude, between the methyl formate and dimethyl ether and methyl formate and formamide abundances, which may point to a link between these two couples of species, in cold and warm gas

The Foggy Disks Surrounding Herbig Ae Stars: a Theoretical Study of the H2O Line Spectra

Water is a key species in many astrophysical environments, but it is particularly important in proto-planetary disks. So far,observations of water in these objects have been scarce, but the situation should soon change thanks to the Herschel satellite. We report here a theoretical study of the water line spectrum of a proto-planetary disk surrounding Ae stars. We show that several lines will be observable with the HIFI instrument onboard the Herschel Space Observatory. We predict that some maser lines could also be observable with ground telescopes and we discuss how the predictions depend not only on the adopted physical and chemical model but also on the set of collisional coefficients used and on the H2 ortho to para ratio through its effect on collisional excitation. This makes the water lines observations a powerful, but dangerous -if misused- diagnostic tool.Comment: Accepted for publication in ApJ Letter

First measurements of 15N fractionation in N2H+ toward high-mass star forming cores

We report on the first measurements of the isotopic ratio 14N/15N in N2H+ toward a statistically significant sample of high-mass star forming cores. The sources belong to the three main evolutionary categories of the high-mass star formation process: high-mass starless cores, high-mass protostellar objects, and ultracompact HII regions. Simultaneous measurements of 14N/15N in CN have been made. The 14N/15N ratios derived from N2H+ show a large spread (from ~180 up to ~1300), while those derived from CN are in between the value measured in the terrestrial atmosphere (~270) and that of the proto-Solar nebula (~440) for the large majority of the sources within the errors. However, this different spread might be due to the fact that the sources detected in the N2H+ isotopologues are more than those detected in the CN ones. The 14N/15N ratio does not change significantly with the source evolutionary stage, which indicates that time seems to be irrelevant for the fractionation of nitrogen. We also find a possible anticorrelation between the 14N/15N (as derived from N2H+) and the H/D isotopic ratios. This suggests that 15N enrichment could not be linked to the parameters that cause D enrichment, in agreement with the prediction by recent chemical models. These models, however, are not able to reproduce the observed large spread in 14N/15N, pointing out that some important routes of nitrogen fractionation could be still missing in the models.Comment: 2 Figures, accepted for publication in ApJ

Hyperentanglement witness

A new criterium to detect the entanglement present in a {\it hyperentangled state}, based on the evaluation of an entanglement witness, is presented. We show how some witnesses recently introduced for graph states, measured by only two local settings, can be used in this case. We also define a new witness $W_3$ that improves the resistance to noise by increasing the number of local measurements.Comment: 6 pages, 2 figures, RevTex. v2: new title, minor changes in the explanation of the witness for hyperentangled states, more comments in the conclusions sectio

The L1157-B1 astrochemical laboratory: testing the origin of DCN

L1157-B1 is the brightest shocked region of the large-scale molecular outflow, considered the prototype of chemically rich outflows, being the ideal laboratory to study how shocks affect the molecular gas. Several deuterated molecules have been previously detected with the IRAM 30m, most of them formed on grain mantles and then released into the gas phase due to the shock. We aim to observationally investigate the role of the different chemical processes at work that lead to formation the of DCN and test the predictions of the chemical models for its formation. We performed high-angular resolution observations with NOEMA of the DCN(2-1) and H13CN(2-1) lines to compute the deuterated fraction, Dfrac(HCN). We detected emission of DCN(2-1) and H13CN(2-1) arising from L1157-B1 shock. Dfrac(HCN) is ~4x10$^{-3}$ and given the uncertainties, we did not find significant variations across the bow-shock. Contrary to HDCO, whose emission delineates the region of impact between the jet and the ambient material, DCN is more widespread and not limited to the impact region. This is consistent with the idea that gas-phase chemistry is playing a major role in the deuteration of HCN in the head of the bow-shock, where HDCO is undetected as it is a product of grain-surface chemistry. The spectra of DCN and H13CN match the spectral signature of the outflow cavity walls, suggesting that their emission result from shocked gas. The analysis of the time dependent gas-grain chemical model UCL-CHEM coupled with a C-type shock model shows that the observed Dfrac(HCN) is reached during the post-shock phase, matching the dynamical timescale of the shock. Our results indicate that the presence of DCN in L1157-B1 is a combination of gas-phase chemistry that produces the widespread DCN emission, dominating in the head of the bow-shock, and sputtering from grain mantles toward the jet impact region.Comment: Accepted for publication in A&A. 7 pages, 5 Figures, 1 Tabl

Gas phase formation of the prebiotic molecule formamide: insights from new quantum computations

New insights into the formation of interstellar formamide, a species of great relevance in prebiotic chemistry, are provided by electronic structure and kinetic calculations for the reaction NH2 + H2CO -> NH2CHO + H. Contrarily to what previously suggested, this reaction is essentially barrierless and can, therefore, occur under the low temperature conditions of interstellar objects thus providing a facile formation route of formamide. The rate coefficient parameters for the reaction channel leading to NH2CHO + H have been calculated to be A = 2.6x10^{-12} cm^3 s^{-1}, beta = -2.1 and gamma = 26.9 K in the range of temperatures 10-300 K. Including these new kinetic data in a refined astrochemical model, we show that the proposed mechanism can well reproduce the abundances of formamide observed in two very different interstellar objects: the cold envelope of the Sun-like protostar IRAS16293-2422 and the molecular shock L1157-B2. Therefore, the major conclusion of this Letter is that there is no need to invoke grain-surface chemistry to explain the presence of formamide provided that its precursors, NH2 and H2CO, are available in the gas-phase.Comment: MNRAS Letters, in pres

H2_2D+^+ line emission in Proto-Planetary Disks

%Context: {Previous studies have indicated that the 372.4 GHz ground transition of ortho-H$_2$D$^+$ might be a powerful probe of Proto-Planetary Disks. The line could be especially suited for study of the disk mid-plane, where the bulk of the mass resides and where planet formation takes place.} %Aims: {Provide detailed theoretical predictions for the line intensity, profile and maps expected for representative disk models.} %Methods: {We determine the physical and chemical structure of the disks from the model developed by Ceccarelli & Dominik (2005). The line emission is computed with the new radiative transfer method developed recently by Elitzur & Asensio Ramos (2006).} %Results: {We present intensity maps convolved with the expected ALMA resolution, which delineate the origin of the H$_2$D$^+$ 372.4 GHz line. In the disk inner regions, the line probes the conditions in the mid-plane out to radial distances of a few tens of AU, where Solar-like planetary systems might form. In the disk outermost regions, the line originates from slightly above the mid-plane. When the disk is spatially resolved, the variation of line profile across the image provides important information about the velocity field. Spectral profiles of the entire disk flux show a double peak shape at most inclination angles.} %Conclusions: {Our study confirms that the 372.4 GHz H$_2$D$^+$ line provides powerful diagnostics of the mid-plane of Proto-Planetary Disks. Current submillimeter telescopes are capable of observing this line, though with some difficulties. The future ALMA interferometer will have the sensitivity to observe and even spatially resolve the H$_2$D$^+$ line emission.}Comment: To appear in A&