4,678 research outputs found
Density functional theory of superconductivity in doped tungsten oxides
We apply density functional theory for superconductors (SCDFT) to doped tungsten oxide in three forms: electrostatically doped WO3, perovskite WO3−xFx, and hexagonal CsxWO3. We achieve a consistent picture in which the experimental superconducting transition temperature Tc is reproduced, and superconductivity is understood as a weak-coupling state sustained by soft vibrational modes of the WO6 octahedra. SCDFT simulations of CsxWO3 allow us to explain the anomalous Tc behavior observed in most tungsten bronzes, where Tc decreases with increasing carrier density. Here, the opening of structural channels to host Cs atoms induces a softening of strongly coupled W-O modes. By increasing the Cs content, these modes are screened and Tc is strongly reduced
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Nucleate pool boiling investigation on a silicon test section with micro-fabricated cavities
The basic mechanisms of nucleate boiling are still not completely understood, in spite of the many numerical and experimental studies dedicated to the topic. The use of a hybrid code allows reasonable computational times for simulations of a solid plate with a large population of artificial micro-cavities with fixed distribution. This paper analyses the guidelines for the design, through numerical simulations, of the location and sizes of micro-fabricated cavities on a new silicon test section immersed in FC-72 at the saturation temperature for different pressures with an imposed heat flux applied at the back of the plate. Particular focus is on variations of wall temperature around nucleation sites
Automated analysis of quantitative image data using isomorphic functional mixed models, with application to proteomics data
Image data are increasingly encountered and are of growing importance in many
areas of science. Much of these data are quantitative image data, which are
characterized by intensities that represent some measurement of interest in the
scanned images. The data typically consist of multiple images on the same
domain and the goal of the research is to combine the quantitative information
across images to make inference about populations or interventions. In this
paper we present a unified analysis framework for the analysis of quantitative
image data using a Bayesian functional mixed model approach. This framework is
flexible enough to handle complex, irregular images with many local features,
and can model the simultaneous effects of multiple factors on the image
intensities and account for the correlation between images induced by the
design. We introduce a general isomorphic modeling approach to fitting the
functional mixed model, of which the wavelet-based functional mixed model is
one special case. With suitable modeling choices, this approach leads to
efficient calculations and can result in flexible modeling and adaptive
smoothing of the salient features in the data. The proposed method has the
following advantages: it can be run automatically, it produces inferential
plots indicating which regions of the image are associated with each factor, it
simultaneously considers the practical and statistical significance of
findings, and it controls the false discovery rate.Comment: Published in at http://dx.doi.org/10.1214/10-AOAS407 the Annals of
Applied Statistics (http://www.imstat.org/aoas/) by the Institute of
Mathematical Statistics (http://www.imstat.org
Momentum-driven outflow emission from an O-type YSO: Comparing the radio jet with the molecular outflow
Aims: We want to study the physical properties of the ionized jet emission in
the vicinity of an O-type young stellar object (YSO), and estimate how
efficient is the transfer of energy and momentum from small- to large-scale
outflows. Methods: We conducted Karl G. Jansky Very Large Array (VLA)
observations, at both 22 and 45 GHz, of the compact and faint radio continuum
emission in the high-mass star-forming region G023.01-00.41, with an angular
resolution between 0.3" and 0.1", and a thermal rms of the order of 10
uJy/beam. Results: We discovered a collimated thermal (bremsstrahlung) jet
emission, with a radio luminosity (L_rad) of 24 mJy kpc^2 at 45 GHz, in the
inner 1000 AU from an O-type YSO. The radio thermal jet has an opening angle of
44 degrees and brings a momentum rate of 8 10^-3 M_sun yr^-1 km/s. By combining
the new data with previous observations of the molecular outflow and water
maser shocks, we can trace the outflow emission from its driving source through
the molecular clump, across more than two order of magnitude in length (500
AU-0.2 pc). We find that the momentum-transfer efficiency, between the inner
jet emission and the extended outflow of entrained ambient gas, is near unity.
This result suggests that the large-scale flow is swept-up by the mechanical
force of the radio jet emission, which originates in the inner 1000 AU from the
high-mass YSO.Comment: 5 pages, 2 figures, 2 tables, accepted by Astronomy & Astrophysic
Evidence for impurity-induced frustration in La2CuO4
Zero-field muon spin rotation and magnetization measurements were performed
in La2Cu{1-x}MxO4, for 0<x< 0.12, where Cu2+ is replaced either by M=Zn2+ or by
M=Mg2+ spinless impurity. It is shown that while the doping dependence of the
sublattice magnetization (M(x)) is nearly the same for both compounds, the
N\'eel temperature (T_N(x)) decreases unambiguously more rapidly in the
Zn-doped compound. This difference, not taken into account within a simple
dilution model, is associated with the frustration induced by the Zn2+ impurity
onto the Cu2+ antiferromagnetic lattice. In fact, from T_N(x) and M(x) the spin
stiffness is derived and found to be reduced by Zn doping more significantly
than expected within a dilution model. The effect of the structural
modifications induced by doping on the exchange coupling is also discussed.Comment: 4 pages, 4 figure
The virial theorem and exact properties of density functionals for periodic systems
In the framework of density functional theory, scaling and the virial theorem
are essential tools for deriving exact properties of density functionals.
Preexisting mathematical difficulties in deriving the virial theorem via
scaling for periodic systems are resolved via a particular scaling technique.
This methodology is employed to derive universal properties of the
exchange-correlation energy functional for periodic systems.Comment: Accepted in PRB(R) 201
Electronic, dynamical and superconducting properties of CaBeSi
We report first-principles calculations on the normal and superconducting
state of CaBe(x)Si(2-x) (x=1), in the framework of density functional theory
for superconductors (SCDFT). CaBeSi is isostructural and isoelectronic to MgB2
and this makes possible a direct comparison of the electronic and vibrational
properties and the electron-phonon interaction of the two materials. Despite
the many similarities with MgB2 (e.g. sigma bands at the Fermi level and a
larger Fermi surface nesting), according to our calculations CaBeSi has a very
low critical temperature (Tc ~ 0.4 K, consistent with the experiment). CaBeSi
exhibits a complex gap structure, with three gaps at Fermi level: besides the
two sigma and pi gaps, present also in MgB2, the appearance of a third gap is
related to the anisotropy of the Coulomb repulsion, acting in different way on
the bonding and antibonding electronic pi states.Comment: 6 pages, 5 figure
Evidence for impurity-induced frustration in La2CuO4
Zero-field muon spin rotation and magnetization measurements were performed
in La2Cu{1-x}MxO4, for 0<x< 0.12, where Cu2+ is replaced either by M=Zn2+ or by
M=Mg2+ spinless impurity. It is shown that while the doping dependence of the
sublattice magnetization (M(x)) is nearly the same for both compounds, the
N\'eel temperature (T_N(x)) decreases unambiguously more rapidly in the
Zn-doped compound. This difference, not taken into account within a simple
dilution model, is associated with the frustration induced by the Zn2+ impurity
onto the Cu2+ antiferromagnetic lattice. In fact, from T_N(x) and M(x) the spin
stiffness is derived and found to be reduced by Zn doping more significantly
than expected within a dilution model. The effect of the structural
modifications induced by doping on the exchange coupling is also discussed.Comment: 4 pages, 4 figure
A study on subarcsecond scales of the ammonia and continuum emission toward the G16.59-0.05 high-mass star-forming region
We wish to investigate the structure, velocity field, and stellar content of
the G16.59-0.05 high-mass star-forming region, where previous studies have
established the presence of two almost perpendicular (NE-SW and SE-NW), massive
outflows, and a rotating disk traced by methanol maser emission. We performed
Very Large Array observations of the radio continuum and ammonia line emission,
complemented by COMICS/Subaru and Hi-GAL/Herschel images in the mid- and
far-infrared (IR). Our centimeter continuum maps reveal a collimated radio jet
that is oriented E-W and centered on the methanol maser disk, placed at the SE
border of a compact molecular core. The spectral index of the jet is negative,
indicating non-thermal emission over most of the jet, except the peak close to
the maser disk, where thermal free-free emission is observed. We find that the
ammonia emission presents a bipolar structure consistent (on a smaller scale)
in direction and velocity with that of the NE-SW bipolar outflow detected in
previous CO observations. After analyzing our previous N2H+(1-0) observations
again, we conclude that two scenarios are possible. In one case both the radio
jet and the ammonia emission would trace the root of the large-scale CO bipolar
outflow. The different orientation of the jet and the ammonia flow could be
explained by precession and/or a non-isotropic density distribution around the
star. In the other case, the N2H+(1-0) and ammonia bipolarity is interpreted as
two overlapping clumps moving with different velocities along the line of
sight. The ammonia gas also seems to undergo rotation consistent with the maser
disk. Our IR images complemented by archival data allow us to derive a
bolometric luminosity of about 10^4 L_sun and to conclude that most of the
luminosity is due to the young stellar object associated with the maser disk.Comment: 11 pages, 12 figures, published in Astronomy and Astrophysic
Applicazioni della matematica fuzzy per la selezione dei progetti conservativi nei siti archeologici
The Authors deal with the problem of a standardised but clear and easily understood framework for the strategic decisions involved in the selection among the diverse projects for the conservation and cultural and economic enhancement of archaeological sites. The aim of the paper is to explore the possibility of the use of fuzzy logic to create a hierarchy among the different projects. We propose the use of fuzzy numbers mathematics for the joint treatment of technical, landscape impact, economic and humanistic aspects in selecting the best conservation projects. The basic elements for the definition and the arithmetic of fuzzy numbers are given and a procedure based on the ordering is implemented. Finally, an application relating to an archaeological site on the Mediterranean Sea (Nora, Sardinia) is presented
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