265 research outputs found
Catalytic molecularly imprinted polymer membranes: Development of the biomimetic sensor for phenols detection
Portable biomimetic sensor devices for the express control of phenols content in
water were developed. The synthetic binding sites mimicking active site of the
enzyme tyrosinase were formed in the structure of free-standing molecularly
imprinted polymer membranes. Molecularly imprinted polymer membranes with the
catalytic activity were obtained by co-polymerization of the complex Cu
(II)–catechol–urocanic acid ethyl ester with (tri)ethyleneglycoldimethacrylate,
and oligourethaneacrylate. Addition of the elastic component
oligourethaneacrylate provided formation of the highly cross-linked polymer with
the catalytic activity in a form of thin, flexible, and mechanically stable
membrane. High accessibility of the artificial catalytic sites for the
interaction with the analyzed phenol molecules was achieved due to addition of
linear polymer (polyethyleneglycol Mw 20,000) to the initial monomer mixture
before the polymerization. As a result, typical semi-interpenetrating polymer
networks (semi-IPNs) were formed. The cross-linked component of the semi-IPN was
represented by the highly cross-linked catalytic molecularly imprinted polymer,
while the linear one was represented by polyethyleneglycol Mw 20,000. Extraction
of the linear polymer from the fully formed semi-IPN resulted in formation of
large pores in the membranes’ structure. Concentration of phenols in the
analyzed samples was detected using universal portable device oxymeter with the
oxygen electrode in a close contact with the catalytic molecularly imprinted
polymer membrane as a transducer. The detection limit of phenols detection using
the developed sensor system based on polymers–biomimics with the optimized
composition comprised 0.063 mM, while the linear range of the sensor comprised
0.063–1 mM. The working characteristics of the portable sensor devices were
investigated. Storage stability of sensor systems at room temperature comprised
12 months (87%). As compared to traditional methods of phenols detection the
developed sensor system is characterized by simplicity of operation,
compactness, an
Isolation of Flow and Nonflow Correlations by Two- and Four-Particle Cumulant Measurements of Azimuthal Harmonics in 200 GeV Au+Au Collisions
A data-driven method was applied to measurements of Au+Au collisions at
200 GeV made with the STAR detector at RHIC to isolate
pseudorapidity distance -dependent and -independent
correlations by using two- and four-particle azimuthal cumulant measurements.
We identified a component of the correlation that is -independent,
which is likely dominated by anisotropic flow and flow fluctuations. It was
also found to be independent of within the measured range of
pseudorapidity . The relative flow fluctuation was found to be for particles of transverse momentum
less than GeV/. The -dependent part may be attributed to
nonflow correlations, and is found to be relative to the
flow of the measured second harmonic cumulant at
Measurements of and Production in + Collisions at = 200 GeV
We report measurements of charmed-hadron (, ) production cross
sections at mid-rapidity in + collisions at a center-of-mass energy of
200 GeV by the STAR experiment. Charmed hadrons were reconstructed via the
hadronic decays , and their charge conjugates,
covering the range of 0.62.0 GeV/ and 2.06.0 GeV/ for
and , respectively. From this analysis, the charm-pair production cross
section at mid-rapidity is = 170 45
(stat.) (sys.) b. The extracted charm-pair cross section is
compared to perturbative QCD calculations. The transverse momentum differential
cross section is found to be consistent with the upper bound of a Fixed-Order
Next-to-Leading Logarithm calculation.Comment: 15 pages, 16 figures. Revised version submitted to Phys. Rev.
Charged-to-neutral correlation at forward rapidity in Au+Au collisions at =200 GeV
Event-by-event fluctuations of the ratio of inclusive charged to photon
multiplicities at forward rapidity in Au+Au collision at =200
GeV have been studied. Dominant contribution to such fluctuations is expected
to come from correlated production of charged and neutral pions. We search for
evidences of dynamical fluctuations of different physical origins. Observables
constructed out of moments of multiplicities are used as measures of
fluctuations. Mixed events and model calculations are used as baselines.
Results are compared to the dynamical net-charge fluctuations measured in the
same acceptance. A non-zero statistically significant signal of dynamical
fluctuations is observed in excess to the model prediction when charged
particles and photons are measured in the same acceptance. We find that, unlike
dynamical net-charge fluctuation, charge-neutral fluctuation is not dominated
by correlation due to particle decay. Results are compared to the expectations
based on the generic production mechanism of pions due to isospin symmetry, for
which no significant (<1%) deviation is observed.Comment: 14 pages, 6 figure
Inclusive charged hadron elliptic flow in Au + Au collisions at = 7.7 - 39 GeV
A systematic study is presented for centrality, transverse momentum ()
and pseudorapidity () dependence of the inclusive charged hadron elliptic
flow () at midrapidity() in Au+Au collisions at
= 7.7, 11.5, 19.6, 27 and 39 GeV. The results obtained with
different methods, including correlations with the event plane reconstructed in
a region separated by a large pseudorapidity gap and 4-particle cumulants
(), are presented in order to investigate non-flow correlations and
fluctuations. We observe that the difference between and
is smaller at the lower collision energies. Values of , scaled by
the initial coordinate space eccentricity, , as a function
of are larger in more central collisions, suggesting stronger collective
flow develops in more central collisions, similar to the results at higher
collision energies. These results are compared to measurements at higher
energies at the Relativistic Heavy Ion Collider ( = 62.4 and 200
GeV) and at the Large Hadron Collider (Pb + Pb collisions at =
2.76 TeV). The values for fixed rise with increasing collision
energy within the range studied (). A comparison to
viscous hydrodynamic simulations is made to potentially help understand the
energy dependence of . We also compare the results to UrQMD
and AMPT transport model calculations, and physics implications on the
dominance of partonic versus hadronic phases in the system created at Beam
Energy Scan (BES) energies are discussed.Comment: 20 pages, 12 figures. Version accepted by PR
Beam energy dependent two-pion interferometry and the freeze-out eccentricity of pions in heavy ion collisions at STAR
We present results of analyses of two-pion interferometry in Au+Au collisions
at = 7.7, 11.5, 19.6, 27, 39, 62.4 and 200 GeV measured in the
STAR detector as part of the RHIC Beam Energy Scan program. The extracted
correlation lengths (HBT radii) are studied as a function of beam energy,
azimuthal angle relative to the reaction plane, centrality, and transverse mass
() of the particles. The azimuthal analysis allows extraction of the
eccentricity of the entire fireball at kinetic freeze-out. The energy
dependence of this observable is expected to be sensitive to changes in the
equation of state. A new global fit method is studied as an alternate method to
directly measure the parameters in the azimuthal analysis. The eccentricity
shows a monotonic decrease with beam energy that is qualitatively consistent
with the trend from all model predictions and quantitatively consistent with a
hadronic transport model.Comment: 27 pages; 27 figure
Measurements of Dihadron Correlations Relative to the Event Plane in Au+Au Collisions at GeV
Dihadron azimuthal correlations containing a high transverse momentum (\pt)
trigger particle are sensitive to the properties of the nuclear medium created
at RHIC through the strong interactions occurring between the traversing parton
and the medium, i.e. jet-quenching. Previous measurements revealed a strong
modification to dihadron azimuthal correlations in Au+Au collisions with
respect to \pp\ and \dAu\ collisions. The modification increases with the
collision centrality, suggesting a path-length dependence to the jet-quenching
effect. This paper reports STAR measurements of dihadron azimuthal correlations
in mid-central (20-60\%) Au+Au collisions at \snn=200~GeV as a function of
the trigger particle's azimuthal angle relative to the event plane,
\phis=|\phit-\psiEP|. The azimuthal correlation is studied as a function of
both the trigger and associated particle \pt. The subtractions of the
combinatorial background and anisotropic flow, assuming Zero Yield At Minimum
(\zyam), are described. The away-side correlation is strongly modified, and the
modification varies with \phis, which is expected to be related to the
path-length that the away-side parton traverses. The pseudo-rapidity (\deta)
dependence of the near-side correlation, sensitive to long range \deta
correlations (the ridge), is also investigated. The ridge and jet-like
components of the near-side correlation are studied as a function of \phis.
The ridge appears to drop with increasing \phis while the jet-like component
remains approximately constant. ...Comment: 50 pages, 39 figures, 6 table
Measurement of longitudinal spin asymmetries for weak boson production in polarized proton-proton collisions at RHIC
We report measurements of single- and double- spin asymmetries for
and boson production in longitudinally polarized collisions
at GeV by the STAR experiment at RHIC. The asymmetries for
were measured as a function of the decay lepton pseudorapidity, which
provides a theoretically clean probe of the proton's polarized quark
distributions at the scale of the mass. The results are compared to
theoretical predictions, constrained by recent polarized deep inelastic
scattering measurements, and show a preference for a sizable, positive up
antiquark polarization in the range .Comment: 7 pages, 5 figures, Submitted to Physical Review Letters; replaced
with published versio
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