Zonage du Bresil a partir d'une serie temporelle d'images modis.

Zoneamento do Brasil a partir de uma série temporal de imagens MODIS . A cartografia das paisagens envolvem geralmente a combinação de informações ambientais e informações sobre as atividades humanas. A qualidade da carta de paisagem resultante depende fortemente da expertise e do método utilizado, assim como da qualidade dos dados que foram usados na sua elaboração. As séries temporais das imagens de satélite aportam uma visão objetiva do território a diferentes datas. Estas imagens podem ser segmentadas para estratificar o espaço em zonas radiometricamente homogêneas. O objetivo deste trabalho é testar este método de estratificação a diferentes escalas espaciais, no Brasil e na região do estado do Maranhão e avaliar as estratificações de forma não supervisionada. Para tanto, uma segmentação orientada à objeto foi realizada utilizando-se o software eCognition a partir de valores dos índices de vegetação EVI (Enhaced Vegetation Index) e de índices de textura advindos de uma série temporal de imagens MODIS com resolução espacial de 250m. Diferentes variáveis radiométricas e diferentes escalas de segmentação foram testadas e avaliadas através de dois indicadores estatísticos. A segmentação obtida foi, então, comparada visualmente aos zoneamentos existentes (GAEZ da FAO e zoneamento agroecológico da Embrapa)

Hole Transport and Recombination in All-Solid Sb2S3-Sensitized TiO2 Solar Cells Using CuSCN As Hole Transporter

All-solid semiconductor-sensitized solar cells lack models allowing their characterization in terms of the fundamental processes of charge transport and recombination. Nanostructured TiO 2/Sb 2S 3/CuSCN solar cells were characterized by impedance spectroscopy, and a model was proposed for this type of cells. One important feature resulting from this analysis was the hole transport diffusion, which could be assimilated to a series resistance affecting the cell fill factor. The other important feature was the recombination rate, which could be described in a similar manner as other cells using nanostructured TiO 2 electrodes and which had an important impact on the open circuit. A simulation of the current-voltage curves using such model allowed us to get an approximate quantification of the losses caused by each process and to evaluate the possible improvements on the performance of this kind of cell

Crystalline-Size Dependence of Dual Emission Peak on Hybrid Organic Lead-Iodide Perovskite Films at Low Temperatures

In this work, we have investigated the crystalline-size dependence of optical absorption and photolumines-cence emission of CH3NH3PbI3 films, which is necessary to identify the potencial practical applications of the gadgets based on perovskite films. This study was carried out at low temperatures to minimize the extra complexity induced by thermal effects. The purpose was clarifying the origin of the dual emission peak previously reported in literature. We have found that the grain-size is responsible of the appearance or disappearance of this dual emission on CH3NH3PbI3 at low temperatures, whereas we have inferred that the thickness of the perovskite layer is a much more important factor than the size of the grains in the location of the energy of the bandgap. Moreover, the increase in the grain size allows slowing down the phase transition. Additionally, we evidence a decrease in the effective Rydberg energy of the exciton in several samples, from 23-25 meV at 7 K to 12-13 meV at 165 K, by fitting to Elliot-Toyozawa theory. We have extracted other im-portant physical parameters of perovskites from the photoluminescence-data deconvolution, such as bandgap, exciton-phonon interaction and exciton binding energy. A new phase transition at 45.5 K was determined by the temperature dependence of full width at half maximum and integrated intensity of the photoluminescence, and it was confirmed by the radiative lifetime obtained from the time-resolved photoluminescence emission by mean of time-correlated single photon counting at different temperatures, excitation fluencies and emission energies

Effects of Frequency Dependence of the External Quantum Efficiency of Perovskite Solar Cells

Perovskite solar cells are known to show very long response time scales, on the order of milliseconds to seconds. This generates considerable doubt over the validity of the measured external quantum efficiency (EQE) and consequently the estimation of the short-circuit current density. We observe a variation as high as 10% in the values of the EQE of perovskite solar cells for different optical chopper frequencies between 10 and 500 Hz, indicating a need to establish well-defined protocols of EQE measurement. We also corroborate these values and obtain new insights regarding the working mechanisms of perovskite solar cells from intensity-modulated photocurrent spectroscopy measurements, identifying the evolution of the EQE over a range of frequencies, displaying a singular reduction at very low frequencies. This reduction in EQE is ascribed to additional resistive contributions hindering charge extraction in the perovskite solar cell at short-circuit conditions, which are delayed because of the concomitant large low-frequency capacitance

How the Charge-Neutrality Level of Interface States Controls Energy Level Alignment in Cathode Contacts of Organic Bulk-Heterojunction Solar Cells

Electronic equilibration at the metal–organic interface, leading to equalization of the Fermi levels, is a key process in organic optoelectronic devices. How the energy levels are set across the interface determines carrier extraction at the contact and also limits the achievable open-circuit voltage under illumination. Here, we report an extensive investigation of the cathode energy equilibration of organic bulk-heterojunction solar cells. We show that the potential to balance the mismatch between the cathode metal and the organic layer Fermi levels is divided into two contributions: spatially extended band bending in the organic bulk and voltage drop at the interface dipole layer caused by a net charge transfer. We scan the operation of the cathode under a varied set of conditions, using metals of different work functions in the range of 2 eV, different fullerene acceptors, and several cathode interlayers. The measurements allow us to locate the charge-neutrality level within the interface density of sates and calculate the corresponding dipole layer strength. The dipole layer withstands a large part of the total Fermi level mismatch when the polymer:fullerene blend ratio approaches 1:1, producing the practical alignment between the metal Fermi level and the charge-neutrality level. Origin of the interface states is linked with fullerene reduced molecules covering the metal contact. The dipole contribution, and consequently the band bending, is highly sensitive to the nature and amount of fullerene molecules forming the interface density of states. Our analysis provides a detailed picture of the evolution of the potentials in the bulk and the interface of the solar cell when forward voltage is applied or when photogeneration takes place

Recycled Photons Traveling Several Millimeters in Waveguides Based on CsPbBr3 Perovskite Nanocrystals

Reabsorption and reemission of photons, or photon recycling (PR) effect, represents an outstanding mechanism to enhance the carrier and photon densities in semiconductor thin films. This work demonstrates the propagation of recycled photons over several mm by integrating a thin film of CsPbBr3 nanocrystals into a planar waveguide. An experimental set-up based on a frequency modulation spectroscopy allows to characterize the PR effect and the determination of the effective decay time of outcoupled photons. A correlation between the observed photoluminescence redshift and the increase of the effective decay time is demonstrated, which grows from 3.5 to near 9 ns in the best device. A stochastic Monte Carlo model reproduces these experimental results and allows the extraction of the physical mechanisms involved. In the waveguide under study recycled photons follow a drift (directional enhancement) velocity ≈5.7 × 105 m s−1, dominating over the diffusive regime observed in a standard thin film (D ≈ 420 m2 s−1). This means that recycled photons propagate mm-distances in shorter traveling times in the waveguide (≈5 ns) as compared to the film (>20 ns). These results are expected to pave the road for exploiting the PR effect in future optoelectronic and photonic devices

Surface Recombination and Collection Efficiency in Perovskite Solar Cells from Impedance Analysis

The large diffusion lengths recurrently measured in perovskite single crystals and films signal small bulk nonradiative recombination flux and locate the dominant carrier recombination processes at the outer interfaces. Surface recombination largely determines the photovoltaic performance, governing reductions under short-circuit current and open-circuit voltage. Quantification of recombination losses is necessary to reach full understanding of the solar cell operating principles. Complete impedance model is given, which connects capacitive and resistive processes to the electronic kinetics at the interfaces. Carrier collection losses affecting the photocurrent have been determined to equal 1%. Photovoltage loss is linked to the decrease in surface hole density, producing 0.3 V reduction with respect to the ideal radiative limit. Our approach enables a comparison among different structures, morphologies, and processing strategies of passivation and buffer layers.We acknowledge financial support by Ministerio de Economía y Competitividad (MINECO) of Spain under project (MAT2016-76892-C3-1-R) and Generalitat Valenciana (Prometeo/2014/020). SCIC at UJI is also acknowledged

Water oxidation at hematite photoelectrodes: the role of surface states

Hematite (α-Fe2O3) constitutes one of the most promising semiconductor materials for the conversion of sunlight into chemical fuels by water splitting. Its inherent drawbacks related to the long penetration depth of light and poor charge carrier conductivity are being progressively overcome by employing nanostructuring strategies and improved catalysts. However, the physical–chemical mechanisms responsible for the photoelectrochemical performance of this material (J(V) response) are still poorly understood. In the present study we prepared thin film hematite electrodes by atomic layer deposition to study the photoelectrochemical properties of this material under water-splitting conditions. We employed impedance spectroscopy to determine the main steps involved in photocurrent production at different conditions of voltage, light intensity, and electrolyte pH. A general physical model is proposed, which includes the existence of a surface state at the semiconductor/liquid interface where holes accumulate. The strong correlation between the charging of this state with the charge transfer resistance and the photocurrent onset provides new evidence of the accumulation of holes in surface states at the semiconductor/electrolyte interface, which are responsible for water oxidation. The charging of this surface state under illumination is also related to the shift of the measured flat-band potential. These findings demonstrate the utility of impedance spectroscopy in investigations of hematite electrodes to provide key parameters of photoelectrodes with a relatively simple measurement