1,037 research outputs found
Thermal control of transparent elements onboard artificial satellites
Temperature control of transparent elements onboard artificial satellite
Measurement and Optimisation of the PS-SPS Transfer Line Optics
The beam optics of the PS-SPS transfer line at CERN has been studied and optimised for a variety of beams. Betatron and dispersion matching has been performed for the fixed-target proton and ion beams as well as for the future LHC proton beam. The techniques applied to the measurement of the optical parameters in the transfer line are discussed and experimental results are presented
A paper-based device for glyphosate electrochemical detection in human urine: A case study to demonstrate how the properties of the paper can solve analytical issues
In the ever-growing demand for agricultural production, the use of pesticides and the consequential health risks is an issue that remains in the spotlight. The biomonitoring of pesticides in biological matrices is a mandatory task to point out the adverse effects on those people that are particularly exposed (i.e., occupational exposure) and to customize the use of pesticides for safer and more aware agricultural practices (i.e., precision agriculture). To overcome the bottleneck of costs and long sample treatments, we conceived a paper-based analytical device for the fast and smart detection of glyphosate in human urines, which is still the most widespread pesticide. Importantly, we demonstrate how to face the analytical interference given by uric acid to develop an electrochemical sensor for glyphosate detection using paper as a multifunctional material. To this purpose, a sample treatment was pointed out and integrated into a paper strip to decrease the level of uric acid in urines, finally delivering a ready-to-use device that combines lateral and vertical flow. The effective decrease of uric acid after the paper-integrated treatment is verified by direct oxidation in differential pulse voltammetry, whereas glyphosate detection can be carried out by enzyme inhibition assay in chronoamperometry. The system showed a limit of detection for glyphosate of 75 ÎĽg/L and a linear range of 100 - 700 ÎĽg/L. Additionally, the sustainability of the paper device was assessed and compared with reference chromatographic methods. Overall, this work provides an example of how to design green sensing solutions for addressing analytical challenges in line with the White Analytical Chemistry principle
The 27-28 October 1986 FIRE IFO cirrus case study: Comparison of satellite and aircraft derived particle size
Theoretical calculations predict that cloud reflectance in near infrared windows such as those at 1.6 and 2.2 microns should give lower reflectances than at visible wavelengths. The reason for this difference is that ice and liquid water show significant absorption at those wavelengths, in contrast to the nearly conservative scattering at wavelengths shorter than 1 micron. In addition, because the amount of absorption scales with the path length of radiation through the particle, increasing cloud particle size should lead to decreasing reflectances at 1.6 and 2.2 microns. Measurements at these wavelengths to date, however, have often given unpredicted results. Twomey and Cocks found unexpectedly high absorption (factors of 3 to 5) in optically thick liquid water clouds. Curran and Wu found expectedly low absorption in optically thick high clouds, and postulated the existence of supercooled small water droplets in place of the expected large ice particles. The implications of the FIRE data for optically thin cirrus are examined
Nominal LHC Beam Instability Observations in the CERN Proton Synchrotron
The nominal LHC beam has been produced successfully in the CERN Proton Synchrotron since 2003. However, after having restarted the CERN PS in spring 2006, the LHC beam was set-up and observed to be unstable on the 26 GeV/c extraction flat top. An intensive measurement campaign was made to understand the instability and to trace its source. This paper presents the observations, possible explanations and the necessary measures to be taken in order to avoid this instability in the future
The 27-28 October 1986 FIRE IFO Cirrus case study: Comparison of radiative transfer theory with observations by satellite and aircraft
Observations of cirrus and altocumulus clouds during the First International Satellite Cloud Climatology Project Regional Experiment (FIRE) are compared to theoretical models of cloud radiative properties. Three tests are performed. First, LANDSAT radiances are used to compare the relationship between nadir reflectance ot 0.83 micron and beam emittance at 11.5 microns with that predicted for model calculations using spherical and nonspherical phase functions. Good agreement is found between observations and theory when water droplets dominate. Poor agreement is found when ice particles dominate, especially using scattering phase functions for spherical particles. Even when compared to a laboratory measured ice particle phase function, the observations show increased side scattered radiation relative to the theoretical calculations. Second, the anisotropy of conservatively scattered radiation is examined using simultaneous multiple angle views of the cirrus from LANDSAT and ER-2 aircraft radiometers. Observed anisotropy gives good agreement with theoretical calculations using the laboratory measured ice particle phase function and poor agreement with a spherical particle phase function. Third, Landsat radiances at 0.83, 1.65, and 2.21 microns are used to infer particle phase and particle size. For water droplets, good agreement is found with King Air FSSP particle probe measurements in the cloud. For ice particles, the LANDSAT radiance observations predict an effective radius of 60 microns versus aircraft observations of about 200 microns. It is suggested that this descrepancy may be explained by uncertainty in the imaginary index of ice and by inadequate measurements of small ice particles by microphysical probes
Beam Scraping for LHC Injection
Operation of the LHC will require injection of very high intensity beams from the SPS to the LHC. Fast scrapers have been installed and will be used in the SPS to detect and remove any existing halo before beams are extracted, to minimize the probability for quenching of superconducting magnets at injection in the LHC. We briefly review the functionality of the scraper system and report about measurements that have recently been performed in the SPS on halo scraping and re-population of tails
Nonlinear analysis of a simple model of temperature evolution in a satellite
We analyse a simple model of the heat transfer to and from a small satellite
orbiting round a solar system planet. Our approach considers the satellite
isothermal, with external heat input from the environment and from internal
energy dissipation, and output to the environment as black-body radiation. The
resulting nonlinear ordinary differential equation for the satellite's
temperature is analysed by qualitative, perturbation and numerical methods,
which show that the temperature approaches a periodic pattern (attracting limit
cycle). This approach can occur in two ways, according to the values of the
parameters: (i) a slow decay towards the limit cycle over a time longer than
the period, or (ii) a fast decay towards the limit cycle over a time shorter
than the period. In the first case, an exactly soluble average equation is
valid. We discuss the consequences of our model for the thermal stability of
satellites.Comment: 13 pages, 4 figures (5 EPS files
Chiral biobased ionic liquids with cations or anions including bile acid building blocks as chiral selectors in voltammetry
Chiral ionic liquids (CILs), or ionic liquids (ILs) with chiral additives, are very attractive chiral media for enantioselective electroanalysis, on account of their high chiral structural order at the electrochemical interphase. A family of molecular salts with CIL properties is now introduced, based on the chiral steroid building block of deoxycholic acid implemented either in the anion or cation. Testing them as chiral additives in a commercial achiral IL, they enable voltammetric discrimination of the enantiomers of a model chiral probe on disposable screen-printed electrodes in terms of peak potential differences, which is the most desirable transduction mode of the enantiorecognition event. The probe enantiomer sequence is the same for all selectors, consistent with their sharing the same chiral building block configuration. This proof-of-concept widens the application fields of bile acid derivatives as chiral selectors, while also enriching the still very few CIL families so far explored for applications in chiral electroanalysis
Nonalcoholic fatty liver disease and increased risk of 1-year all-cause and cardiac hospital readmissions in elderly patients admitted for acute heart failure
Nonalcoholic fatty liver disease (NAFLD) is an emerging risk factor for heart failure (HF). Although some progress has been made in improving survival among patients admitted for HF, the rates of hospital readmissions and the related costs continue to rise dramatically. We sought to examine whether NAFLD and its severity (diagnosed at hospital admission) was independently associated with a higher risk of 1-year all-cause and cardiac re-hospitalization in patients admitted for acute HF. We studied 212 elderly patients who were consecutively admitted with acute HF to the Hospital of Negrar (Verona) over a 1-year period. Diagnosis of NAFLD was based on ultrasonography, whereas the severity of advanced NAFLD fibrosis was based on the fibrosis (FIB)-4 score and other non-invasive fibrosis scores. Patients with acute myocardial infarction, severe valvular heart diseases, endstage renal disease, cancer, known liver diseases or decompensated cirrhosis were excluded. Cox regression was used to estimate hazard ratios (HR) for the associations between NAFLD and the outcome(s) of interest. The cumulative rate of 1-year all-cause re-hospitalizations was 46.7% (n = 99, mainly due to cardiac causes). Patients with NAFLD (n = 109; 51.4%) had remarkably higher 1-year all-cause and cardiac re-hospitalization rates compared with their counterparts without NAFLD. Both event rates were particularly increased in those with advanced NAFLD fibrosis. NAFLD was associated with a 5-fold increased risk of 1-year all-cause re-hospitalization (adjusted-hazard ratio 5.05, 95% confidence intervals 2.78-9.10, p<0.0001) after adjustment for established risk factors and potential confounders. Similar results were found for 1-year cardiac re-hospitalization (adjusted-hazard ratio 8.05, 95% confidence intervals 3.77-15.8, p<0.0001). In conclusion, NAFLD and its severity were strongly and independently associated with an increased risk of 1-year all-cause and cardiac re-hospitalization in elderly patients admitted with acute HF
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