351 research outputs found
Effect of electric field on the photoluminescence of polymer-inorganic nanoparticles composites
We report on the effect of electric field on the photoluminescence, PL, from
a composite consisting of a conjugated polymer mixed with zinc oxide
nanoparticles. We have found that in the absence of electric field PL emission
from the composite film has two maxima in the blue and green-yellow regions.
Application of a voltage bias to planar gold electrodes suppresses the
green-yellow emission and shifts the only PL emission maximum towards the blue
region. Current-voltage characteristics of the polymer-nanoparticles composite
exhibit the non-linear behavior typical of non-homogeneous polymer-inorganic
structures. Generation of excited states in the composite structure implies the
presence of several radiative recombination mechanisms including formation of
polymer-nanoparticle complexes including exciplex states and charge transfer
between the polymer and nanoparticle that can be controlled by an electric
field.Comment: 5 pages, 5 figures. accepted for publication in Solid State
Communication
Exciton Regeneration at Polymeric Semiconductor Heterojunctions
Control of the band-edge offsets at heterojunctions between organic
semiconductors allows efficient operation of either photovoltaic or
light-emitting diodes. We investigate systems where the exciton is marginally
stable against charge separation, and show via E-field-dependent time-resolved
photoluminescence spectroscopy that excitons that have undergone charge
separation at a heterojunction can be efficiently regenerated. This is because
the charge transfer produces a geminate electron-hole pair (separation
2.2-3.1nm) which may collapse into an exciplex and then endothermically
(E=100-200meV) back-transfer towards the exciton.Comment: 10 pages, 4 figures. Manuscript in press in Phys. Rev. Let
Multiscale Modeling and Simulation of Organic Solar Cells
In this article, we continue our mathematical study of organic solar cells
(OSCs) and propose a two-scale (micro- and macro-scale) model of heterojunction
OSCs with interface geometries characterized by an arbitrarily complex
morphology. The microscale model consists of a system of partial and ordinary
differential equations in an heterogeneous domain, that provides a full
description of excitation/transport phenomena occurring in the bulk regions and
dissociation/recombination processes occurring in a thin material slab across
the interface. The macroscale model is obtained by a micro-to-macro scale
transition that consists of averaging the mass balance equations in the normal
direction across the interface thickness, giving rise to nonlinear transmission
conditions that are parametrized by the interfacial width. These conditions
account in a lumped manner for the volumetric dissociation/recombination
phenomena occurring in the thin slab and depend locally on the electric field
magnitude and orientation. Using the macroscale model in two spatial
dimensions, device structures with complex interface morphologies, for which
existing data are available, are numerically investigated showing that, if the
electric field orientation relative to the interface is taken into due account,
the device performance is determined not only by the total interface length but
also by its shape
Bicontinuous minimal surface nanostructures for polymer blend solar cells
This paper presents the first examination of the potential for bicontinuous structures such as the gyroid structure to produce high efficiency solar cells based on conjugated polymers. The solar cell characteristics are predicted by a simulation model that shows how the morphology influences device performance through integration of all the processes occurring in organic photocells in a specified morphology. In bicontinuous phases, the surface de. ning the interface between the electron and hole transporting phases divides the volume into two disjoint subvolumes. Exciton loss is reduced because the interface at which charge separation occurs permeates the device so excitons have only a short distance to reach the interface. As each of the component phases is connected, charges will be able to reach the electrodes more easily. In simulations of the current-voltage characteristics of organic cells with gyroid, disordered blend and vertical rod (rods normal to the electrodes) morphologies, we find that gyroids have a lower than anticipated performance advantage over disordered blends, and that vertical rods are superior. These results are explored thoroughly, with geminate recombination, i.e. recombination of charges originating from the same exciton, identified as the primary source of loss. Thus, if an appropriate materials choice could reduce geminate recombination, gyroids show great promise for future research and applications
Light-Emitting Devices with Conjugated Polymers
This article introduces a previous study and tremendous progress in basic theoretical modeling, material developments and device engineering for polymer light-emitting devices (PLEDs)
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