Quantum dynamics of the Li+HF-->H+LiF reaction at ultralow temperatures

Quantum mechanical calculations are reported for the Li+HF(v=0,1,j=0)-->H+LiF(v',j') bimolecular scattering process at low and ultralow temperatures. Calculations have been performed for zero total angular momentum using a recent high accuracy potential energy surface for the X 2A' electronic ground state. For Li+HF(v=0,j=0), the reaction is dominated by resonances due to the decay of metastable states of the Li...F-H van der Waals complex. Assignment of these resonances has been carried out by calculating the eigenenergies of the quasibound states. We also find that while chemical reactivity is greatly enhanced by vibrational excitation the resonances get mostly washed out in the reaction of vibrationally excited HF with Li atoms. In addition, we find that at low energies, the reaction is significantly suppressed due to the formation of rather deeply bound van der Waals complexes and the less efficient tunneling of the relatively heavy fluorine atom.Comment: 24 pages, 8 figures, 1 table, submitted to J. Chem. Phy

Spiral-like structure in nearby clusters of galaxies

X-ray data analysis have found that fairly complex structures at cluster centres are more common than expected. Many of these structures have similar morphologies, which exhibit spiral-like substructure. It is not yet well known how these structures formed or are maintained. Understanding the origin of these spiral-like features at the centre of some clusters is the major motivation behind this work. We analyse deep \textit{Chandra} observations of 15 nearby galaxy clusters (0.01 $< z <$ 0.06), and use X-ray temperature and substructure maps to detect small features at the cores of the clusters. We detect spiral-like features at the centre of 7 clusters: A85, A426, A496, Hydra A cluster, Centaurus, Ophiuchus, and A4059. These patterns are similar to those found in numerical hydrodynamic simulations of cluster mergers with non-zero impact parameter. In some clusters of our sample, a strong radio source also occupies the inner region of the cluster, which indicates a possible connection between the two. Our investigation implies that these spiral-like structures may be caused by off-axis minor mergers. Since these features occur in regions of high density, they may confine radio emission from the central galaxy producing, in some cases, unusual radio morphology.Comment: 14 pages, 3 figures, accepted for publication in A&A (Nov 17, 2009

XMM-Newton/SDSS: star formation efficiency in galaxy clusters and constraints on the matter density parameter

It is believed that the global baryon content of clusters of galaxies is representative of the matter distribution of the universe, and can, therefore, be used to reliably determine the matter density parameter Omega_m. This assumption is challenged by the growing evidence from optical and X-ray observations that the total baryon mass fraction increases towards rich clusters. In this context, we investigate the dependence of stellar, and total baryon mass fractions as a function of mass. To do so, we used a subsample of nineteen clusters extracted from the X-ray flux limited sample HIFLUGCS that have available DR-7 Sloan Digital Sky Survey (SDSS) data. From the optical analysis we derived the stellar masses. Using XMM-Newton we derived the gas masses. Then, adopting a scaling relation we estimate the total masses. Adding the gas and the stellar mass fractions we obtain the total baryonic content that we find to increase with cluster mass, reaching 7-year Wilkinson Microwave Anisotropy Probe (WMAP-7) prediction for clusters with M_500 = 1.6 x 10^{15} M_sun. We observe a decrease of the stellar mass fraction (from 4.5% to ~1.0%) with increasing total mass where our findings for the stellar mass fraction agree with previous studies. This result suggests a difference in the number of stars formed per unit of halo mass, though with a large scatter for low-mass systems. That is, the efficiency of star formation varies on cluster scale that lower mass systems are likely to have higher star formation efficiencies. It follows immediately that the dependence of the stellar mass fraction on total mass results in an increase of the mass-to-light ratio from lower to higher mass systems. We also discuss the consequences of these results in the context of determining the cosmic matter density parameter Omega_m.Comment: Accepted for publication in ApJ, 11 pages, 5 figures. http://stacks.iop.org/0004-637X/743/1

Earl Smith v. Paul Lagana

USDC for the District of New Jerse

The optical/X-ray connection: ICM iron content and galaxy optical luminosity in 20 galaxy clusters

X-ray observations of galaxy clusters have shown that the intra-cluster gas has iron abundances of about one third of the solar value. These observations also show that part (if not all) of the intra-cluster gas metals were produced within the member galaxies. We present a systematic analysis of 20 galaxy clusters to explore the connection between the iron mass and the total luminosity of early-type and late-type galaxies, and of the brightest cluster galaxies (BCGs). From our results, the intra-cluster medium (ICM) iron mass seems to correlate better with the luminosity of the BCGs than with that of the red and blue galaxy populations. As the BCGs cannot produce alone the observed amount of iron, we suggest that ram-pressure plus tidal stripping act together to enhance, at the same time, the BCG luminosities and the iron mass in the ICM. Through the analysis of the iron yield, we have also estimated that SN Ia are responsible for more than 50% of the total iron in the ICM. This result corroborates the fact that ram-pressure contributes to the gas removal from galaxies to the inta-cluster medium, being very efficient for clusters in the temperature range 2 < kT (keV)< 10Comment: Accepted for publication in MNRAS (11 pg, 9 figures and 3 tables