312 research outputs found
On the origin of intrinsic alignment in cosmic shear measurements: an analytic argument
Galaxy intrinsic alignment can be a severe source of error in weak-lensing
studies. The problem has been widely studied by numerical simulations and with
heuristic models, but without a clear theoretical justification of its origin
and amplitude. In particular, it is still unclear whether intrinsic alignment
of galaxies is dominated by formation and accretion processes or by the effects
of the instantaneous tidal field acting upon them. We investigate this question
by developing a simple model of intrinsic alignment for elliptical galaxies,
based on the instantaneous tidal field. Making use of the galaxy stellar
distribution function, we estimate the intrinsic alignment signal and find that
although it has the expected dependence on the tidal field, it is too weak to
account for the observed signal. This is an indirect validation of the standard
view that intrinsic alignment is caused by formation and/or accretion
processes.Comment: 11 pages, 4 figures, accepted for publication on Astronomy &
Astrophysic
Disk formation in the collapse of supramassive neutron stars
Short gamma-ray bursts (sGRBs) show a large diversity in their properties.
This suggests that the observed phenomenon can be caused by different "central
engines" or that the engine produces a variety of outcomes depending on its
parameters, or possibly both. The most popular engine scenario, the merger of
two neutron stars, has received support from the recent Fermi and INTEGRAL
detection of a burst of gamma rays (GRB170817A) following the neutron star
merger GW170817, but at the moment it is not clear how peculiar this event
potentially was. Several sGRBs engine models involve the collapse of a
supramassive neutron star that produces a black hole plus an accretion disk. We
study this scenario for a variety of equations of states both via angular
momentum considerations based on equilibrium models and via fully dynamical
Numerical Relativity simulations. We obtain a broader range of disk forming
configurations than earlier studies but we agree with the latter that none of
these configurations is likely to produce a phenomenon that would be classified
as an sGRB.Comment: accepted by MNRA
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Studies toward the synthesis of celastrol and the late-stage hydroxylation of arenes mediated by 4,5-dichlorophthaloyl peroxide
textThe natural product celastrol (1) possesses a wide array of promising biological activities related to diseases characterized by protein misfolding including those associated with neuronal degradation, inflammation, and cancer. Relevant to cancer, celastrol functions as a non-ATP-competitive inhibitor of heat shock protein-90, providing a potential lead for the development of new inhibitors with improved pharmacology. A laboratory preparation of the small molecule was undertaken to provide access to the unnatural enantiomer of celastrol. The lack of understanding of the chemistry and biology of the growing class of celastroids is attributed to the incompatibility of biologically inspired polyene cyclization strategies to assemble friedelin triterpenoids. As a result of these problems residing at the interface of chemistry and biology, a purely synthesis-based strategy for polyene cyclizations to rapidly construct the pentacyclic core of the friedelin and celastroid natural products has been developed. This efficient strategy is gram scalable culminating in the first total synthesis of wilforic acid (127) and an advanced intermediate capable of delivering celastrol (1) as well as numerous celastroid natural products. Phenols possess broad utility serving as key materials in all facets of chemical industries, especially the pharmaceutical industry. The ideal synthesis of a phenolic compound entails the direct oxidation of an aryl C-H bond remains to be a difficult synthetic challenge. Following our initial report describing the hydroxylation of arenes using phthaloyl peroxide, new peroxide derivatives were investigated to probe their reactivity in an effort to hydroxylate aromatics which were previously unreactive. Electronically poor to moderately rich arenes were successfully hydroxylated with a broad functional group tolerance using 4,5-dichlorophthaloyl peroxide. This protocol has been applied toward the rapid synthesis of phenolic analogs and metabolites of current pharmaceuticals as well as biocides. Mechanistic studies using kinetic isotope effect, competition, and benzylic oxidation experiments indicate that a novel diradical reverse-rebound mechanism is the likely pathway. Further examination of the transition-state using linear free energy relationships with sigma vs. sigma+ values established a linear trend with a low negative rho value (- 3.92) corresponding best using sigma values supporting a diradical reverse-rebound addition.Chemistr
Early evolution of newly born proto-neutron stars
A proto-neutron star (PNS) is the first phase of life of a neutron star, and is likely to origin from a core-collapse supernova. After about 200 ms from core-collapse, the PNS evolution may be modeled as a sequence of quasi-stationary configurations. These configurations depend on the PNS thermodynamic profiles, whose evolution largely depends upon the neutrino diffusion.
We developed a new PNS evolutionary code that solves by iteration the neutrino number and energy transport equations together with the relativistic stellar structure equations assuming spherical symmetry. The neutrino cross sections are determined consistently with the underlying equation of state (EoS). To include the EoSs in the evolution, we devised and tested a new fitting formula for the interacting part of the baryon free-energy, valid at finite temperature and arbitrary degeneracy.
Using our code, we provide estimates for the neutrino signal in the Super-Kamiokande III detector and the frequencies of the gravitational waves due to stellar oscillations, for three stellar masses and three nucleonic EoSs. For the first time we evolve a PNS with a nuclear many-body theory EoS in a consistent way, that is, we take into account realistic nuclear interactions in the computation of the neutrino cross sections. By including rotation in an effective way, we have also determined the time variation of the rotation frequency due to PNS contraction and neutrino angular momentum loss, and the gravitational wave signal due to rotation. We find that the mass shedding limit restricts the initial angular momentum. Consequently, the final rotation frequency has to be smaller than about 300 Hz for a PNS of about 1.6 solar masses whose EoS is described by the GM3 mean-field model
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Cyber-Physical Vulnerabilities in Additive Manufacturing Systems
One of the key advantages of additive manufacturing (AM) is its digital thread, which allows
for rapid communication, iteration, and sharing of a design model and its corresponding physical
representation. While this enables a more efficient design process, it also presents opportunities
for cyber-attacks to impact the physical word. In this paper the authors examine potential attack
vectors along the Additive Manufacturing process chain. Specifically, the effects of cyber-physical attacks, and potential means for detecting them, are explored. Based on the results of
this study, recommendations are presented for preventing and detecting cyber-physical attacks on
AM processes.Mechanical Engineerin
Taxonomies for Reasoning About Cyber-physical Attacks in IoT-based Manufacturing Systems
The Internet of Things (IoT) has transformed many aspects of modern manufacturing, from design to production to quality control. In particular, IoT and digital manufacturing technologies have substantially accelerated product development- cycles and manufacturers can now create products of a complexity and precision not heretofore possible. New threats to supply chain security have arisen from connecting machines to the Internet and introducing complex IoT-based systems controlling manufacturing processes. By attacking these IoT-based manufacturing systems and tampering with digital files, attackers can manipulate physical characteristics of parts and change the dimensions, shapes, or mechanical properties of the parts, which can result in parts that fail in the field. These defects increase manufacturing costs and allow silent problems to occur only under certain loads that can threaten safety and/or lives. To understand potential dangers and protect manufacturing system safety, this paper presents two taxonomies: one for classifying cyber-physical attacks against manufacturing processes and another for quality control measures for counteracting these attacks. We systematically identify and classify possible cyber-physical attacks and connect the attacks with variations in manufacturing processes and quality control measures. Our taxonomies also provide a scheme for linking emerging IoT-based manufacturing system vulnerabilities to possible attacks and quality control measures
Using ion beams to tune the nanostructure and optical response of co-deposited Ag : BBBN thin films
The present study is devoted to co-deposited Ag : BN nanocermet thin films and is focused on the influence of ion irradiation conditions on their structural and linear optical properties. Ion irradiation was performed in situ during the growth of the nanocermets using a 50 eV assistance beam (nitrogen/argon or nitrogen-ion assistance) and ex situ on as-grown films using a 120 keV argon-ion beam (post-irradiation). Grazing incidence small-angle x-ray scattering measurements show that (i) as-grown N-assisted films contain prolate spheroidal clusters (height-to-diameter ratio H/D ≈ 1.8), (ii) N/Ar-ion assistance leads to the formation of more elongated clusters (H/D ≈ 2.1) and (iii) post-irradiation leads to a decrease of H/D to a value close to 1. These results are discussed on the basis of atomic diffusion processes involved during the growth of the nanocermets and during the post-irradiation. The optical transmittance spectra of these films measured at normal incidence display one absorption band, due to the excitation of the (1,1) plasmon mode of the clusters. In the case of the as-grown films, an additional band appears at oblique incidence for P-polarized light, as a consequence of the excitation of the (1,0) plasmon mode of the clusters. Our results show that the spectral position of the absorption bands (which can be tuned in the 400-600 nm range) depends on the H/D ratio of the clusters, in good agreement with calculations of optical transmittance considering the nanocomposite layer as a uniaxial anisotropic medium whose dielectric tensor is described by an anisotropic Maxwell-Garnett model. © 2007 IOP Publishing Ltd.The authors would like to thank CNRS-CSIC and Picasso programmes for financial support which permitted the collaboration between the Instituto de Ciencia de Materiales de Sevilla (Spain) and the Laboratoire de Metallurgie Physique ´ de Poitiers (France). The authors also thank J P Simon and the D2AM staff at the ESRF for their support during the GISAXS measurements.Peer Reviewe
Internal alignments of red versus blue discs in dark matter haloes
Large surveys have shown that red galaxies are preferentially aligned with their haloes, while blue galaxies have a more isotropic distribution. Since haloes generally align with their filaments, this introduces a bias in the measurement of the cosmic shear from weak lensing. It is therefore vitally important to understand why this difference arises. We explore the stability of different disc orientations within triaxial haloes. We show that, in the absence of gas, the disc orientation is most stable when its spin is along the minor axis of the halo. Instead when gas cools on to a disc, it is able to form in almost arbitrary orientation, including off the main planes of the halo (but avoiding an orientation perpendicular to the halo's intermediate axis). Substructure helps gasless galaxies reach alignment with the halo faster, but has less effect on galaxies when gas is cooling on to the disc. Our results provide a novel and natural interpretation for why red, gas poor galaxies are preferentially aligned with their halo, while blue, star-forming, galaxies have nearly random orientations, without requiring a connection between galaxies' current star formation rate and their merger history
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