Laboratory mid-IR spectra of equilibrated and igneous meteorites. Searching for observables of planetesimal debris

Meteorites contain minerals from Solar System asteroids with different properties (like size, presence of water, core formation). We provide new mid-IR transmission spectra of powdered meteorites to obtain templates of how mid-IR spectra of asteroidal debris would look like. This is essential for interpreting mid-IR spectra of past and future space observatories, like the James Webb Space Telescope. We show that the transmission spectra of wet and dry chondrites, carbonaceous and ordinary chondrites and achondrite and chondrite meteorites are distinctly different in a way one can distinguish in astronomical mid-IR spectra. The two observables that spectroscopically separate the different meteorites groups (and thus the different types of parent bodies) are the pyroxene-olivine feature strength ratio and the peak shift of the olivine spectral features due to an increase in the iron concentration of the olivine

Quantum Key Recycling with 8-state encoding (The Quantum One-Time Pad is more interesting than we thought)

Perfect encryption of quantum states using the Quantum One-Time Pad (QOTP) requires two classical key bits per qubit. Almost-perfect encryption, with information-theoretic security, requires only slightly more than 1. We slightly improve lower bounds on the key length. We show that key length n+2log1ε n+2log1ε suffices to encrypt n n qubits in such a way that the cipherstate’s L 1 L1 -distance from uniformity is upperbounded by ε ε . For a stricter security definition involving the ∞ ∞ -norm, we prove sufficient key length n+logn+2log1ε +1+1n log1δ +logln21−ε n+logn+2log1ε+1+1nlog1δ+logln21−ε , where δ δ is a small probability of failure. Our proof uses Pauli operators, whereas previous results on the ∞ ∞ -norm needed Haar measure sampling. We show how to QOTP-encrypt classical plaintext in a nontrivial way: we encode a plaintext bit as the vector ±(1,1,1)∕3 – √ ±(1,1,1)∕3 on the Bloch sphere. Applying the Pauli encryption operators results in eight possible cipherstates which are equally spread out on the Bloch sphere. This encoding, especially when combined with the half-keylength option of QOTP, has advantages over 4-state and 6-state encoding in applications such as Quantum Key Recycling (QKR) and Unclonable Encryption (UE). We propose a key recycling scheme that is more efficient and can tolerate more noise than a recent scheme by Fehr and Salvail. For 8-state QOTP encryption with pseudorandom keys, we do a statistical analysis of the cipherstate eigenvalues. We present numerics up to nine qubits

The evolved circumbinary disk of AC Her: a radiative transfer, interferometric and mineralogical study

We aim to constrain the structure of the circumstellar material around the post-AGB binary and RV Tauri pulsator AC Her. We want to constrain the spatial distribution of the amorphous as well as of the crystalline dust. We present very high-quality mid-IR interferometric data that were obtained with MIDI/VLTI. We analyse the MIDI data and the full SED, using the MCMax radiative transfer code, to find a good structure model of AC Her's circumbinary disk. We include a grain size distribution and midplane settling of dust self-consistently. The spatial distribution of crystalline forsterite in the disk is investigated with the mid-IR features, the 69~$\mu$m band and the 11.3~$\mu$m signatures in the interferometric data. All the data are well fitted. The inclination and position angle of the disk are well determined at i=50+-8 and PA=305+-10. We firmly establish that the inner disk radius is about an order of magnitude larger than the dust sublimation radius. Significant grain growth has occurred, with mm-sized grains being settled to the midplane of the disk. A large dust mass is needed to fit the sub-mm fluxes. By assuming {\alpha}=0.01, a good fit is obtained with a small grain size power law index of 3.25, combined with a small gas/dust ratio <10. The resulting gas mass is compatible with recent estimates employing direct gas diagnostics. The spatial distribution of the forsterite is different from the amorphous dust, as more warm forsterite is needed in the surface layers of the inner disk. The disk in AC Her is very evolved, with its small gas/dust ratio and large inner hole. Mid-IR interferometry offers unique constraints, complementary to mid-IR features, for studying the mineralogy in disks. A better uv coverage is needed to constrain in detail the distribution of the crystalline forsterite in AC Her, but we find strong similarities with the protoplanetary disk HD100546.Comment: update with final version published in A&

Micron-sized forsterite grains in the pre-planetary nebula of IRAS 17150-3224 - Searching for clues on the mysterious evolution of massive AGB stars

We study the grain properties and location of the forsterite crystals in the circumstellar environment of the pre-planetary nebula (PPN) IRAS 17150-3224 in order to learn more about the as yet poorly understood evolutionary phase prior to the PPN. We use the best-fit model for IRAS 17150-3224 of Meixner et al. (2002) and add forsterite to this model. We investigate different spatial distributions and grain sizes of the forsterite crystals in the circumstellar environment. We compare the spectral bands of forsterite in the mid-infrared and at 69 micrometre in radiative transport models to those in ISO-SWS and Herschel/PACS observations. We can reproduce the non-detection of the mid-infrared bands and the detection of the 69 micrometre feature with models where the forsterite is distributed in the whole outflow, in the superwind region, or in the AGB-wind region emitted previous to the superwind, but we cannot discriminate between these three models. To reproduce the observed spectral bands with these three models, the forsterite crystals need to be dominated by a grain size population of 2 micrometre up to 6 micrometre. We hypothesise that the large forsterite crystals were formed after the superwind phase of IRAS 17150-3224, where the star developed an as yet unknown hyperwind with an extremely high mass-loss rate (10^-3 Msol/yr). The high densities of such a hyperwind could be responsible for the efficient grain growth of both amorphous and crystalline dust in the outflow. Several mechanisms are discussed that might explain the lower-limit of 2 micrometre found for the forsterite grains, but none are satisfactory. Among the mechanisms explored is a possible selection effect due to radiation pressure based on photon scattering on micron-sized grains.Comment: Accepted by A&

Modification of the simple mass balance equation for calculation of critical loads of acidity.

Over the last few years, the simple mass balance equation for the calculation of critical loads of acidity has been gradually modified as the underlying critical load concepts have developed and as problems with particular forms of the equation have been identified, through application in particular countries. The first major update of the equation took place following a workshop held in Vienna, Austria (Hojesky et al. 1993). The workshop was held to discuss problems which had been identified when the then current form of the equation was applied in countries with high rainfall. The problems had largely arisen because of simplifications and assumptions incorporated into the early formulation of the equation. The equation was reformulated to overcome the problems identified at the workshop. However, further problems were identified when the reformulated equation was applied in the UK in situations with a combination of high rainfall, large marine inputs and widespread occurrence of organic soils. A small workshop was, therefore held in Grange-over-Sands, UK in late 1993 to dicuss the problems and to further re-evaluate the equation. The problems had arisen in the UK because of simplifications and assumptions made in the formulation concerning, in particular, cation leaching and uptake. As a result, a more rigorous treatment of these variables was incorporated into the equation. The reformulation of the equation, as derived at the September 1993 workshop is described below

Location and sizes of forsterite grains in protoplanetary disks: interpretation from the Herschel DIGIT programme

The spectra of protoplanetary disks contain mid- and far- infrared emission features produced by forsterite dust grains. The spectral features contain information about the forsterite temperature, chemical composition and grain size. We aim to characterize how the 23 and 69 micron features can be used to constrain the physical locations of forsterite in disks. We check for consistency between two independent forsterite temperature measurements: the 23/69 feature strength ratio and the shape of the 69 micron band. We performed radiative transfer modeling to study the effect of disk properties to the forsterite spectral features. Temperature-dependent forsterite opacities were considered in self-consistent models to compute forsterite emission from protoplanetary disks. Modelling grids are presented to study the effects of grain size, disk gaps, radial mixing and optical depth to the forsterite features. Independent temperature estimates derived from the 23/69 feature strength ratio and the 69 micron band shape are most inconsistent for HD141569 and Oph IRS 48. A case study of the disk of HD141569 shows two solutions to fit the forsterite spectrum. A model with T ~ 40 K, iron-rich (~0-1 % Fe) and 1 micron forsterite grains, and a model with warmer (T ~ 100 K), iron-free, and larger (10 micron) grains. We find that for disks with low upper limits of the 69 micron feature (most notably in flat, self-shadowed disks), the forsterite must be hot, and thus close to the star. We find no correlation between disk gaps and the presence or absence of forsterite features. We argue that the 69 micron feature of the evolved transitional disks HD141569 and Oph IRS 48 is most likely a tracer of larger (i.e. ~10 micron) forsterite grains.Comment: Accepted for publication in A&A. 14 pages, 9 figure

Dusty wind of W Hya. Multi-wavelength modelling of the present-day and recent mass-loss

Low- and intermediate-mass stars go through a period of intense mass-loss at the end of their lives in a phase known as the asymptotic giant branch (AGB). During the AGB a significant fraction of their initial mass is expelled in a stellar wind. This process controls the final stages of their evolution and contributes to the chemical evolution of galaxies. However, the wind-driving mechanism of AGB stars is not yet well understood, especially so for oxygen-rich sources. Characterizing both the present-day mass-loss and wind structure and the evolution of the mass-loss rate of such stars is paramount to advancing our understanding of this processes. We modelled the dust envelope of W Hya using an advanced radiative transfer code. The dust model was analysed in the light of a previously calculated gas-phase wind model and compared to measurements available in the literature, such as infrared spectra, infrared images, and optical scattered light fractions. We find that the dust spectrum of W Hya can partly be explained by a gravitationally bound dust shell that probably is responsible for most of the amorphous Al$_2$O$_3$ emission. The composition of the large ($\sim$\,0.3\,$\mu$m) grains needed to explain the scattered light cannot be constrained, but probably is dominated by silicates. Silicate emission in the thermal infrared was found to originate from beyond 40 AU from the star and we find that they need to have substantial near-infrared opacities to be visible at such large distances. The increase in near-infrared opacity of the dust at these distances roughly coincides with a sudden increase in expansion velocity as deduced from the gas-phase CO lines. Finally, the recent mass loss of W Hya is confirmed to be highly variable and we identify a strong peak in the mass-loss rate that occurred about 3500 years ago and lasted for a few hundred years.Comment: 15 pages, 13 figure

Smart-BIM (Building Information Modeling)

Purpose: After a long period of international research and development, BIM has become mature. Many tools support the BIM process, or at least they claim. BIM not only offers opportunities for the Architectural Engineering and Construction industry, but also for the client. In this paper we don’t focus on the professional client, but on the client of a building assignment that act as the end-user. Involvement of the end user in the design process has been advocated by many scholars and designers, but has so far only marginally been adopted in practice. The importance of user participation is demonstrated by the lack of success of smart technologies in new housing or in renovation. Particularly elderly people resist accepting these technologies in their home environment, although they could benefit from these technologies to improve comfort and health care. As a result of poor understanding of these new technologies by both designers and end users, researchers observe that there is a mismatch between user demands and smart technology usability. Hence, this paper is an attempt to improve the role of users in the design process in two ways. Firstly, by adding the missing components of smart technology to current BIM model libraries. Secondly, by developing a virtual model in which users can interact with the smart technologies and configure their preferred layout. The final results are interesting not only for technology developers but also for housing designers who aim at improving the quality of life in future housing for aging society. Method: For a better understanding of BIM, a historical perspective is taken in this paper. The initiatives from different research institutes are discussed and how they affected each other. The up-take by the software industry is highlighted and their delicate relationship with science. In today’s design process BIM systems support spatial design that is accommodate by smart technology. Usually this smart technology is added after the spatial design in the final design stage by the installations expert. In our research we want to turn this process around; the smart technologies are accommodated by spatial design. Therefore we develop a design system with a library of smart components such as smart wall, smart kitchen and smart furniture. The difference between smart technologies and standard building components is that smart technologies interact with the building users. BIM allows for realistic visualization of designs in an early stage. In our prototype system, clients are presented a virtual space with a wide range of smart technologies. After being introduced to these technologies, the client expresses how these will fit within his/her activities. Following he/she can experience in the virtual model how smart technologies react when activities are executed. Results &amp; Discussion A prototype system is presented that allows clients such as elderly to experience smart technologies. In contrast with traditional design it does not start from the spatial layout but from the activities that should be accommodated supported by smart technologies. We expect that fundamentally different layout will emerge from this approach. Although no experimental data are available yet, some first experiences will be discussed

The problematically short superwind of OH/IR stars - Probing the outflow with the 69 {\mu}m spectral band of forsterite

Spectra of OH/IR stars show prominent spectral bands of crystalline olivine (Mg$_{(2-2x)}$Fe$_{(2x)}$SiO$_{4}$). To learn more about the timescale of the outflows of OH/IR stars, we study the spectral band of crystalline olivine at 69 {\mu}m. The 69 {\mu}m band is of interest because its width and peak wavelength position are sensitive to the grain temperature and to the exact composition of the crystalline olivine. With Herschel/PACS, we observed the 69 {\mu}m band in the outflow of 14 OH/IR stars. By comparing the crystalline olivine features of our sample with those of model spectra, we determined the size of the outflow and its crystalline olivine abundance. The temperature indicated by the observed 69 {\mu}m bands can only be reproduced by models with a geometrically compact superwind ($R_{\rm{SW}}\lesssim$ 2500 AU = 1400 R$_{*}$).This means that the superwind started less than 1200 years ago (assuming an outflow velocity of 10 km/s). The small amount of mass lost in one superwind and the high progenitor mass of the OH/IR stars introduce a mass loss and thus evolutionary problem for these objects, which has not yet been understood.Comment: Accepted by A&