1,591 research outputs found
Few layer graphene on SiC, pyrolitic graphite and graphene: a Raman scattering study
The results of micro-Raman scattering measurements performed on three
different ``graphitic'' materials: micro-structured disks of highly oriented
pyrolytic graphite, graphene multi-layers thermally decomposed from carbon
terminated surface of 4H-SiC and an exfoliated graphene monolayer are
presented. Despite its multi-layer character, most parts of the surface of the
graphitized SiC substrates shows a single-component, Lorentzian shape, double
resonance Raman feature in striking similarity to the case of a single graphene
monolayer. Our observation suggests a very weak electronic coupling between
graphitic layers on the SiC surface, which therefore can be considered to be
graphene multi-layers with a simple (Dirac-like) band structure.Comment: 4 pages, 3 Figures Structure of the paper strongly modified, small
changes in Fig 2 and 3. Same interpretation and same result
Plasmon assisted transport through disordered array of quantum wires
Phononless plasmon assisted thermally activated transport through a long
disordered array of finite length quantum wires is investigated analytically.
Generically strong electron plasmon interaction in quantum wires results in a
qualitative change of the temperature dependence of thermally activated
resistance in comparison to phonon assisted transport. At high temperatures,
the thermally activated resistance is determined by the Luttinger liquid
interaction parameter of the wires.Comment: 7 pages, 1 figure, final version as publishe
Microscopic correlation between chemical and electronic states in epitaxial graphene on SiC(000-1)
We present energy filtered electron emission spectromicroscopy with spatial
and wave-vector resolution on few layer epitaxial graphene on SiC$(000-1) grown
by furnace annealing. Low energy electron microscopy shows that more than 80%
of the sample is covered by 2-3 graphene layers. C1s spectromicroscopy provides
an independent measurement of the graphene thickness distribution map. The work
function, measured by photoelectron emission microscopy (PEEM), varies across
the surface from 4.34 to 4.50eV according to both the graphene thickness and
the graphene-SiC interface chemical state. At least two SiC surface chemical
states (i.e., two different SiC surface structures) are present at the
graphene/SiC interface. Charge transfer occurs at each graphene/SiC interface.
K-space PEEM gives 3D maps of the k_|| pi - pi* band dispersion in micron scale
regions show that the Dirac point shifts as a function of graphene thickness.
Novel Bragg diffraction of the Dirac cones via the superlattice formed by the
commensurately rotated graphene sheets is observed. The experiments underline
the importance of lateral and spectroscopic resolution on the scale of future
electronic devices in order to precisely characterize the transport properties
and band alignments
Highly-ordered graphene for two dimensional electronics
With expanding interest in graphene-based electronics, it is crucial that
high quality graphene films be grown. Sublimation of Si from the 4H-SiC(0001)
Si-terminated) surface in ultrahigh vacuum is a demonstrated method to produce
epitaxial graphene sheets on a semiconductor. In this paper we show that
graphene grown from the SiC (C-terminated) surface are of higher
quality than those previously grown on SiC(0001). Graphene grown on the C-face
can have structural domain sizes more than three times larger than those grown
on the Si-face while at the same time reducing SiC substrate disorder from
sublimation by an order of magnitude.Comment: Submitted to Appl. Phys. Let
Symmetry breaking in commensurate graphene rotational stacking; a comparison of theory and experiment
Graphene stacked in a Bernal configuration (60 degrees relative rotations
between sheets) differs electronically from isolated graphene due to the broken
symmetry introduced by interlayer bonds forming between only one of the two
graphene unit cell atoms. A variety of experiments have shown that non-Bernal
rotations restore this broken symmetry; consequently, these stacking varieties
have been the subject of intensive theoretical interest. Most theories predict
substantial changes in the band structure ranging from the development of a Van
Hove singularity and an angle dependent electron localization that causes the
Fermi velocity to go to zero as the relative rotation angle between sheets goes
to zero. In this work we show by direct measurement that non-Bernal rotations
preserve the graphene symmetry with only a small perturbation due to weak
effective interlayer coupling. We detect neither a Van Hove singularity nor any
significant change in the Fermi velocity. These results suggest significant
problems in our current theoretical understanding of the origins of the band
structure of this material.Comment: 7 pages, 6 figures, submitted to PR
Chest pain, depression and anxiety in coronary heart disease:Consequence or cause? A prospective clinical study in primary care
Objective
To examine if chest pain increases the risk of depression and anxiety, or, on the other hand, depression and anxiety increase the risk of chest pain onset in patients with coronary heart disease (CHD).
Design
Prospective clinical study.
Setting
16 general practices in the Greater London Primary Care Research Network.
Participants
803 participants with a confirmed diagnosis of CHD at baseline on the Quality and Outcomes Framework (QOF) CHD registers.
Main outcome measures
Rose Angina Questionnaire, HADS depression and anxiety subscales and PHQ-9 were assessed at seven time points, each 6 months apart. Multi-Level Analysis (MLA) and Structural Equation Modelling (SEM) were applied.
Results
Chest pain predicts both more severe anxiety and depression symptoms at all time points until 30 months after baseline. However, although anxiety predicted chest pain in the short term with a strong association, this association did not last after 18 months. Depression had only a small, negative association with chest pain.
Conclusions
In persons with CHD, chest pain increases the risk of both anxiety and depression to a great extent. However, anxiety and depression have only limited effects on the risk for chest pain. This evidence suggests that anxiety and depression tend to be consequences rather than causes of cardiac chest pain. Intervention studies that support persons with CHD by providing this information should be devised and evaluated, thus deconstructing potentially catastrophic cognitions and strengthening emotional coping
The structural properties of the multi-layer graphene/4H-SiC(000-1) system as determined by Surface X-ray Diffraction
We present a structural analysis of the multi-layer graphene-4HSiC(000-1})
system using Surface X-Ray Reflectivity. We show for the first time that
graphene films grown on the C-terminated (000-1}) surface have a
graphene-substrate bond length that is very short (0.162nm). The measured
distance rules out a weak Van der Waals interaction to the substrate and
instead indicates a strong bond between the first graphene layer and the bulk
as predicted by ab-initio calculations. The measurements also indicate that
multi-layer graphene grows in a near turbostratic mode on this surface. This
result may explain the lack of a broken graphene symmetry inferred from
conduction measurements on this system [C. Berger et al., Science 312, 1191
(2006)].Comment: 9 pages with 6 figure
A wide band gap metal-semiconductor-metal nanostructure made entirely from graphene
A blueprint for producing scalable digital graphene electronics has remained
elusive. Current methods to produce semiconducting-metallic graphene networks
all suffer from either stringent lithographic demands that prevent
reproducibility, process-induced disorder in the graphene, or scalability
issues. Using angle resolved photoemission, we have discovered a unique one
dimensional metallic-semiconducting-metallic junction made entirely from
graphene, and produced without chemical functionalization or finite size
patterning. The junction is produced by taking advantage of the inherent,
atomically ordered, substrate-graphene interaction when it is grown on SiC, in
this case when graphene is forced to grow over patterned SiC steps. This
scalable bottomup approach allows us to produce a semiconducting graphene strip
whose width is precisely defined within a few graphene lattice constants, a
level of precision entirely outside modern lithographic limits. The
architecture demonstrated in this work is so robust that variations in the
average electronic band structure of thousands of these patterned ribbons have
little variation over length scales tens of microns long. The semiconducting
graphene has a topologically defined few nanometer wide region with an energy
gap greater than 0.5 eV in an otherwise continuous metallic graphene sheet.
This work demonstrates how the graphene-substrate interaction can be used as a
powerful tool to scalably modify graphene's electronic structure and opens a
new direction in graphene electronics research.Comment: 11 pages, 7 figure
Electronic structure of triangular, hexagonal and round graphene flakes near the Fermi level
The electronic shell structure of triangular, hexagonal and round graphene
quantum dots (flakes) near the Fermi level has been studied using a
tight-binding method. The results show that close to the Fermi level the shell
structure of a triangular flake is that of free massless particles, and that
triangles with an armchair edge show an additional sequence of levels ("ghost
states"). These levels result from the graphene band structure and the plane
wave solution of the wave equation, and they are absent for triangles with an
zigzag edge. All zigzag triangles exhibit a prominent edge state at the Fermi
level, and few low-energy conduction electron states occur both in triangular
and hexagonal flakes due to symmetry reasons. Armchair triangles can be used as
building blocks for other types of flakes that support the ghost states. Edge
roughness has only a small effect on the level structure of the triangular
flakes, but the effect is considerably enhanced in the other types of flakes.
In round flakes, the states near the Fermi level depend strongly on the flake
radius, and they are always localized on the zigzag parts of the edge
Multiple plasmon resonances in naturally-occurring multiwall nanotubes: infrared spectra of chrysotile asbestos
Chrysotile asbestos is formed by densely packed bundles of multiwall hollow
nanotubes. Each wall in the nanotubes is a cylindrically wrapped layer of . We show by experiment and theory that the infrared spectrum
of chrysotile presents multiple plasmon resonances in the Si-O stretching
bands. These collective charge excitations are universal features of the
nanotubes that are obtained by cylindrically wrapping an anisotropic material.
The multiple plasmons can be observed if the width of the resonances is
sufficiently small as in chrysotile.Comment: 4 pages, 5 figures. Revtex4 compuscript. Misprint in Eq.(6) correcte
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