The effect of water absorption on the dielectric properties of epoxy nanocomposites

In this research, the influence of water absorption on the dielectric properties of epoxy resin and epoxy micro-composites and nano-composites filled with silica has been studied. Nanocomposites were found to absorb significantly more water than unfilled epoxy. However, the microcomposite absorbed less water than unfilled epoxy: corresponding to reduced proportion of the epoxy in this composite. The glass transition temperatures of all the samples were measured by both differential scanning calorimetry and dielectric spectroscopy. The Tg decreased as the water absorption increased and, in all cases, corresponded to a drop of approximately 20K as the humidity was increased from 0% to 100%. This implied that for all the samples, the amount of water in the resin component of the composites was almost identical. It was concluded that the extra water found in the nanocomposites was located around the surface of the nanoparticles. This was confirmed by measuring the water uptake, and the swelling and density change, as a function of humidity as water was absorbed. The water shell model, originally proposed by Lewis and developed by Tanaka, has been further developed to explain low frequency dielectric spectroscopy results in which percolation of charge carriers through overlapping water shells was shown to occur. This has been discussed in terms of a percolation model. At 100% relative humidity, water is believed to surround the nanoparticles to a depth of approximately 5 monolayers. A second layer of water is proposed that is dispersed by sufficiently concentrated to be conductive; this may extend for approximately 25 nm. If all the water had existed in a single layer surrounding a nanoparticle, this layer would have been approximately 3 to 4 nm thick at 100%. This "characteristic thickness" of water surrounding a given size of nanoparticle appeared to be independent of the concentration of nanoparticles but approximately proportional to water uptake. Filler particles that have surfaces that are functionalized to be hydrophobic considerably reduce the amount of water absorbed in nanocomposites under the same conditions of humidity. Comments are made on the possible effect on electrical aging

A "water shell" model for the dielectric properties of hydrated silica-filled epoxy nano-composites

The electrical properties of epoxy resin have been studied as a function of hydration. The epoxy was studied in an un-filled state, filled with 40 µm SiO2 particles, and filled with 50 nm SiO2 particles. The relative humidity was controlled by saturated salt solutions at ambient temperatures from 298-353 K. Measurements were made using dielectric spectroscopy over the frequency range 10-3-105 Hz. The hydration isotherm (i.e. the mass uptake of water) was established by measuring the mass as a function of relative humidity (RH). It was found that the nanocomposites absorb up to 60% more water than the unfilled and micro-filled epoxies. Dielectric spectroscopy shows different conduction and quasi-DC behaviours at very low frequencies (<10-2 Hz) with activation energies dependent on the hydration and temperature. These observations have led to the development of a “water shell” model to explain this phenomenon

Influence of absorbed water on the dielectric properties and glass-transition temperature of silica-filled epoxy nanocomposites

Work on dielectric spectroscopy of epoxy resin filled with nano-SiO2 at different relative humidities and temperatures is reported. Above the glass-transition temperature (Tg), dc-like imperfect charge transport (QDC or LFD) dominates the low frequency dielectric spectrum. Another mid-frequency relaxation process was found in the non-dried composites. Water also induces glass-transition temperature decreases, which can be measured both by dielectric spectroscopy and DSC. Both theory and experiment demonstrated that a higher water content could exist in nanocomposites than unfilled epoxy suggesting a bigger free volume when nanostructured. In our system, the hydrophilic surface of silica is likely to cause water to surround and lead to delamination of the epoxy from SiO2. This is a potential mechanical and dielectric weakness in the nanocomposites, which may lead to an ageing phenomenon. Hydrophobic surface group may reduce the water adsorption in nanocomposites

Spectrum of low-lying s3QQˉs^{3}Q\bar{Q} configurations with negative parity

Spectrum of low-lying five-quark configurations with strangeness quantum number $S=-3$ and negative parity is studied in three kinds of constituent quark models, namely the one gluon exchange, Goldstone Boson exchange, and instanton-induced hyperfine interaction models, respectively. Our numerical results show that the lowest energy states in all the three employed models are lying at $\sim$1800 MeV, about 200 MeV lower than predictions of various quenched three-quark models. In addition, it is very interesting that the state with the lowest energy in one gluon exchange model is with spin 3/2, but 1/2 in the other two models.Comment: Version published in Phys. Rev.

Thermophysical Phenomena in Metal Additive Manufacturing by Selective Laser Melting: Fundamentals, Modeling, Simulation and Experimentation

Among the many additive manufacturing (AM) processes for metallic materials, selective laser melting (SLM) is arguably the most versatile in terms of its potential to realize complex geometries along with tailored microstructure. However, the complexity of the SLM process, and the need for predictive relation of powder and process parameters to the part properties, demands further development of computational and experimental methods. This review addresses the fundamental physical phenomena of SLM, with a special emphasis on the associated thermal behavior. Simulation and experimental methods are discussed according to three primary categories. First, macroscopic approaches aim to answer questions at the component level and consider for example the determination of residual stresses or dimensional distortion effects prevalent in SLM. Second, mesoscopic approaches focus on the detection of defects such as excessive surface roughness, residual porosity or inclusions that occur at the mesoscopic length scale of individual powder particles. Third, microscopic approaches investigate the metallurgical microstructure evolution resulting from the high temperature gradients and extreme heating and cooling rates induced by the SLM process. Consideration of physical phenomena on all of these three length scales is mandatory to establish the understanding needed to realize high part quality in many applications, and to fully exploit the potential of SLM and related metal AM processes

Isospin breaking and f0(980)f_0(980)-a0(980)a_0(980) mixing in the η(1405)→π0f0(980)\eta(1405) \to \pi^{0} f_0(980) reaction

We make a theoretical study of the $\eta(1405) \to \pi^{0} f_0(980)$ and $\eta(1405) \to \pi^{0} a_0(980)$ reactions with an aim to determine the isospin violation and the mixing of the $f_0(980)$ and $a_0(980)$ resonances. We make use of the chiral unitary approach where these two resonances appear as composite states of two mesons, dynamically generated by the meson-meson interaction provided by chiral Lagrangians. We obtain a very narrow shape for the $f_0(980)$ production in agreement with a BES experiment. As to the amount of isospin violation, or $f_0(980)$ and $a_0(980)$ mixing, assuming constant vertices for the primary $\eta(1405)\rightarrow \pi^{0}K\bar{K}$ and $\eta(1405)\rightarrow \pi^{0}\pi^{0}\eta$ production, we find results which are much smaller than found in the recent experimental BES paper, but consistent with results found in two other related BES experiments. We have tried to understand this anomaly by assuming an I=1 mixture in the $\eta(1405)$ wave function, but this leads to a much bigger width of the $f_0(980)$ mass distribution than observed experimentally. The problem is solved by using the primary production driven by $\eta' \to K^* \bar K$ followed by $K^* \to K \pi$, which induces an extra singularity in the loop functions needed to produce the $f_0(980)$ and $a_0(980)$ resonances. Improving upon earlier work along the same lines, and using the chiral unitary approach, we can now predict absolute values for the ratio $\Gamma(\pi^0, \pi^+ \pi^-)/\Gamma(\pi^0, \pi^0 \eta)$ which are in fair agreement with experiment. We also show that the same results hold if we had the $\eta(1475)$ resonance or a mixture of these two states, as seems to be the case in the BES experiment

Sigma_c Dbar and Lambda_c Dbar states in a chiral quark model

The S-wave Sigma_c Dbar and Lambda_c Dbar states with isospin I=1/2 and spin S=1/2 are dynamically investigated within the framework of a chiral constituent quark model by solving a resonating group method (RGM) equation. The results show that the interaction between Sigma_c and Dbar is attractive, which consequently results in a Sigma_c Dbar bound state with the binding energy of about 5-42 MeV, unlike the case of Lambda_c Dbar state, which has a repulsive interaction and thus is unbound. The channel coupling effect of Sigma_c Dbar and Lambda_c Dbar is found to be negligible due to the fact that the gap between the Sigma_c Dbar and Lambda_c Dbar thresholds is relatively large and the Sigma_c Dbar and Lambda_c Dbar transition interaction is weak.Comment: 7 pages,2 figures. arXiv admin note: text overlap with arXiv:nucl-th/0606056 by other author

The role of the N*(1535) resonance and the pi^- p --> KY amplitudes in the OZI forbidden pi N --> phi N reaction

We study the pi N --> phi N reaction close to the phi N threshold within the chiral unitary approach, by combining the pi^- p --> K^+ Sigma^-, pi^- p --> K^0 Sigma^0 and pi^- p --> K^0 Lambda amplitudes with the coupling of the phi to the K components of the final states of these reactions via quantum loops. We obtain a good agreement with experiment when the dominant pi^- p --> K^0 Lambda amplitude is constrained with its experimental cross section. We also evaluate the coupling of the N*(1535) to phi N and find a moderate coupling as a consequence of partial cancellation of the large KY components of the N*(1535). We also show that the N*(1535) pole approximation is too small to reproduce the measured cross section for the pi N --> phi N reaction.Comment: 10 pages, 6 figure

Drought events and their effects on vegetation productivity in China

Many parts of the world have experienced frequent and severe droughts during the last few decades. Most previous studies examined the effects of specific drought events on vegetation productivity. In this study, we characterized the drought events in China from 1982 to 2012 and assessed their effects on vegetation productivity inferred from satellite data. We first assessed the occurrence, spatial extent, frequency, and severity of drought using the Palmer Drought Severity Index (PDSI). We then examined the impacts of droughts on China\u27s terrestrial ecosystems using the Normalized Difference Vegetation Index (NDVI). During the period 1982–2012, China\u27s land area (%) experiencing drought showed an insignificant trend. However, the drought conditions had been more severe over most regions in northern parts of China since the end of the 1990s, indicating that droughts hit these regions more frequently due to the drier climate. The severe droughts substantially reduced annual and seasonal NDVI. The magnitude and direction of the detrended NDVI under drought stress varied with season and vegetation type. The inconsistency between the regional means of PDSI and detrended NDVI could be attributed to different responses of vegetation to drought and the timing, duration, severity, and lag effects of droughts. The negative effects of droughts on vegetation productivity were partly offset by the enhancement of plant growth resulting from factors such as lower cloudiness, warming climate, and human activities (e.g., afforestation, improved agricultural management practices)