Isotopic Evidence of Hydrothermal Exchange and Seawater Ingress from Alteration Minerals in the Reykjanes Geothermal System: Results from the IDDP

ABSTRACT The primary economic objective of the Iceland Deep Drilling Project (IDDP) is to find 450-600°C supercritical geothermal fluids at drillable depths. The Reykjanes geothermal system is a seawater recharged hydrothermal system, although fluid composition has evolved through time as a result of changing proportions of meteoric water influx as well as differing pressure and temperature conditions imposed by glaciation (Arnorsson, 1995

Clear Lake sediments: Anthropogenic changes in physical sedimentology and magnetic response

We analyzed the sedimentological characteristics and magnetic properties of cores from the three basins of Clear Lake, California, USA, to assess the depositional response to a series of land use changes that occurred in the watershed over the 20th century. Results indicate that distinct and abrupt shifts in particle size, magnetic concentration/mineralogy, and redox conditions occur concurrently with a variety of ecological and chemical changes in lake bed sediments. This coincidence of events occurred around 1927, a datum determined by an abrupt increase in total mercury (Hg) in Clear Lake cores and the known initiation of open-pit Hg mining at the Sulphur Bank Mercury Mine, confirmed by ²¹⁰Pb dating. Ages below the 1927 horizon were determined by accelerator mass spectrometry on ¹⁴C of coarse organic debris. Calculated sedimentation rates below the 1927 datum are ~1 mm/yr, whereas rates from 1927 to 2000 are up to an order of magnitude higher, with averages of ~3.5–19 mm/yr. In both the Oaks and Upper Arms, the post-1927 co-occurrence of abrupt shifts in magnetic signatures with color differences indicative of changing redox conditions is interpreted to reflect a more oxygenated diagenetic regime and rapid burial of sediment below the depth of sulfate diffusion. Post-1927 in the Oaks Arm, grain size exhibits a gradual coarsening-upward pattern that we attribute to the input of mechanically deposited waste rock related to open-pit mining activities at the mine. In contrast, grain size in the Upper Arm exhibits a gradational fining-upward after 1927 that we interpret as human-induced erosion of fine-grained soils and chemically weathered rocks of the Franciscan Assemblage by heavy earthmoving equipment associated with a road- and home-building boom, exacerbated by stream channel mining and wetlands destruction. The flux of fine-grained sediment into the Upper Arm increased the nutrient load to the lake, and that in turn catalyzed profuse cyanobacterial blooms through the 20th century. The resulting organic biomass, in combination with the increased inorganic sediment supply, contributed to the abrupt increase in sedimentation rate after 1927.KEYWORDS: Clear Lake, California, USA, particle size trends, ¹⁴C, paleolimnology, late Holocene, land use patterns, Sulphur Bank Mercury Mine, mercury, magnetic dissolutio

Geology of the Alarcon Rise, Southern Gulf of California

Abstract Meter-scale AUV bathymetric mapping and ROV sampling of the entire 47 km-long Alarcon Rise between the Pescadero and Tamayo transforms show that the shallowest inflated portion of the segment hosts all four active hydrothermal vent fields and the youngest, hottest, and highest effusion rate lava flows. This shallowest inflated part is located ~1/3 of the way between the Tamayo and Pescadero transforms and is paved by a 16 km2 channelized flow that erupted from 9 km of en echelon fissures and is larger than historic flows on the East Pacific Rise or on the Gorda and Juan de Fuca Ridges. Starting ~5 km south of the Pescadero transform, 6.5 km of the Alarcon Rise is characterized by faulted ridges and domes of fractionated lavas ranging from basaltic andesite to rhyolite with up to 77.3 wt % SiO2. These are the first known rhyolites from the submarine global mid-ocean ridge system. Silicic lavas range from \u3e11.7 ka, to as young as 1.1 ka. A basalt-to-basaltic andesite sequence and an andesite-to-dacite-to-rhyolite sequence are consistent with crystal fractionation but some intermediate basaltic andesite and andesite formed by mixing basalt with dacite or rhyolite. Magmatism occurred along the bounding Tamayo and Pescadero transforms as extensive channelized flows. The flows erupted from ring faults surrounding uplifted sediment hills inferred to overlie sills. The transforms are transtensional to accommodate magma migration from the adjacent Alarcon Rise. Plain Language Summary This study combines 1 m resolution bathymetry collected using an autonomous underwater vehicle, with chemical compositions of precisely located lava samples and ages of lava flows determined from short sediment cores collected using a remotely operated vehicle. The objective was to determine the history of an entire 47 km long segment of the global mid-ocean ridge system. The ridge segment studied is named the Alarcon Rise and is located at the mouth of the Gulf of California. The Rise is bounded to the north and south by strike-slip faults that offset the Rise from adjacent segments of the spreading ridge system. Such faults are usually thought to be parallel to the direction of seafloor spreading, but these have an oblique component to their movement that makes space for magma to be injected along the faults where it uplifts hills of sediment and sometimes erupts. Most lavas erupted along midocean ridges are basalts, but some highly unusual silica-rich lavas were identified by their rough surface texture and sampled. These lavas include the most silica-rich ones found along the entire global submarine mid-ocean ridge system. They formed, not by melting of nearby continental crust, but from common basalt by extreme amounts of crystallization of minerals, leaving a small volume of remaining high-silica magma. The complete mapping and closely spaced sampling along the Rise show that old ideas indicating a central point of magma delivery from the underlying mantle for each ridge segment followed by shallow transport of the magmas along the ridge are supported by the central distribution of (1) hydrothermally active sites, (2) the youngest, hottest, most fluid lava flows, and (3) the most voluminous lava flows that accumulate to form the shallowest portion of the ridge segment. The study shows how magmas are transported at shallow depths along the ridge and even around the corners in the adjacent faults

Geology of the Alarcon Rise, Southern Gulf of California

Meter‐scale AUV bathymetric mapping and ROV sampling of the entire 47 km‐long Alarcon Rise between the Pescadero and Tamayo transforms show that the shallowest inflated portion of the segment hosts all four active hydrothermal vent fields and the youngest, hottest, and highest effusion rate lava flows. This shallowest inflated part is located ∼1/3 of the way between the Tamayo and Pescadero transforms and is paved by a 16 km2 channelized flow that erupted from 9 km of en echelon fissures and is larger than historic flows on the East Pacific Rise or on the Gorda and Juan de Fuca Ridges. Starting ∼5 km south of the Pescadero transform, 6.5 km of the Alarcon Rise is characterized by faulted ridges and domes of fractionated lavas ranging from basaltic andesite to rhyolite with up to 77.3 wt % SiO2. These are the first known rhyolites from the submarine global mid‐ocean ridge system. Silicic lavas range from \u3e11.7 ka, to as young as 1.1 ka. A basalt‐to‐basaltic andesite sequence and an andesite‐to‐dacite‐to‐rhyolite sequence are consistent with crystal fractionation but some intermediate basaltic andesite and andesite formed by mixing basalt with dacite or rhyolite. Magmatism occurred along the bounding Tamayo and Pescadero transforms as extensive channelized flows. The flows erupted from ring faults surrounding uplifted sediment hills inferred to overlie sills. The transforms are transtensional to accommodate magma migration from the adjacent Alarcon Rise

Geology of the Alarcon Rise, Southern Gulf of California

Meter‐scale AUV bathymetric mapping and ROV sampling of the entire 47 km‐long Alarcon Rise between the Pescadero and Tamayo transforms show that the shallowest inflated portion of the segment hosts all four active hydrothermal vent fields and the youngest, hottest, and highest effusion rate lava flows. This shallowest inflated part is located ∼1/3 of the way between the Tamayo and Pescadero transforms and is paved by a 16 km2 channelized flow that erupted from 9 km of en echelon fissures and is larger than historic flows on the East Pacific Rise or on the Gorda and Juan de Fuca Ridges. Starting ∼5 km south of the Pescadero transform, 6.5 km of the Alarcon Rise is characterized by faulted ridges and domes of fractionated lavas ranging from basaltic andesite to rhyolite with up to 77.3 wt % SiO2. These are the first known rhyolites from the submarine global mid‐ocean ridge system. Silicic lavas range from \u3e11.7 ka, to as young as 1.1 ka. A basalt‐to‐basaltic andesite sequence and an andesite‐to‐dacite‐to‐rhyolite sequence are consistent with crystal fractionation but some intermediate basaltic andesite and andesite formed by mixing basalt with dacite or rhyolite. Magmatism occurred along the bounding Tamayo and Pescadero transforms as extensive channelized flows. The flows erupted from ring faults surrounding uplifted sediment hills inferred to overlie sills. The transforms are transtensional to accommodate magma migration from the adjacent Alarcon Rise

Geochemical bias in drill cutting samples versus drill core samples returned from the Reykjanes Geothermal System, Iceland

The wholerock major and trace element composition of drill cutting samples are compared to drill core samples from adjacent depths in the seawater recharged Reykjanes geothermal system in Iceland. The first appearance of alteration minerals and lithologies in drill cutting samples is a useful tool for interpreting broad subsurface characteristics. However, use of drill cutting samples for determining igneous affinity and elemental exchanges during hydrothermal alteration is problematic. Samples recovered from immediately above and below the cored intervals in wells RN-17B and RN-30 demonstrate that drill-cutting samples are biased towards preservation of least altered primary igneous minerals and more resistant alteration minerals, including albite, quartz, and epidote, with preferential loss of finer-grained and less resistant minerals including chlorite and actinolite. This selective recovery obscures elemental exchanges resulting from hydrothermal alteration processes. For some elements, compositional variations (enrichments and depletions) measured from 9.5 m of core exceeds that observed in ~3000 m of cutting analyses. Concentration ratios of hydrothermally immobile elements including Zr, Nb, V, Y, HREE, Hf, Ta and Th in deep (>2245 m) spot drill core samples record bimodal, trace element-enriched and trace element-depleted precursor compositions similar to subaerial Reykjanes Peninsula basalts. The same elements in nearly 3000 m of drill cutting samples from well RN-17 overwhelmingly reflect the more common trace element-enriched igneous precursor, demonstrating that mixing of drill cutting samples obscures details of their igneous affinity. A new and different drill rig was used to deepen well RN-17 below 2266 m in a sidetrack hole (RN-17ST), which resulted in a change in drilling conditions, accompanied with an increased well deviation angle from ~0° to ~4°. Wholerock geochemical results for drill cutting samples from RN-17ST are homogenous for virtually every element; suggesting the change in drilling conditions resulted in extreme mixing of the drill cuttings. Anomalously high concentrations of Cu, Ni, Cr and Ta in some drill cutting samples likely reflects contamination of drill cutting samples by metal alloys used in drill bits and drill collars or more resistant spinel and sulfide phases

(Table 3) Sulfur and oxygen isotopic composition of cold water soluble sulfate, and strontium content and isotopic composition of upper Miocene evaporite samples recovered from DSDP Site 23-227

The origin of three Red Sea submarine brine pools was investigated by analysis of the S and O isotope ratios of dissolved sulfate and Sr isotope ratios of dissolved Sr in the brines. Sulfur and O isotope ratios of sulfate and Sr isotope ratios of evaporitic source rocks for the brines were measured for comparison. The S, O and Sr isotope ratios of evaporites recovered from DSDP site 227 are consistent with an upper Miocene evaporites age. The Valdivia Deep brine formed by karstic dissolution of Miocene evaporites by overlying seawater and shows no signs of hydrothermal input. The Suakin Deep brines are derived from, or have isotopically exchanged with Miocene or older evaporites. There has been only minor dilution of the brine by overlying seawater. Strontium isotope ratios of Suakin brine may indicate addition of a minor (15%) amount of volcanic Sr to the brine, but there is no evidence of high temperature brine-rock interaction. The sulfate in the Atlantis II brine was apparently derived from seawater. The O isotope ratio of sulfate in the present Atlantis II brine could reflect isotopic exchange between seawater sulfate and the brine at approximately 255°C. Approximately 30% of the Sr in the Atlantis II brine is derived from the underlying basalt, probably by hydrothermal leaching. Atlantis II brine is the only known example from the Red Sea which has a significant high-temperature hydrothermal history

Reconnaissance of Acid Drainage Sources and Preliminary Evaluation of Remedial Alternatives at the Copper Bluff Mine, Hoopa Valley Reservation, California

Acidic drainage from the inactive Copper Bluff mine cascades down a steep embankment into the Trinity River, on the Hoopa Valley Reservation in northern California. The Copper Bluff mine produced about 100,000 tons of sulfide-bearing copper-zinc-gold-silver ore during 1957–1962. This report summarizes the results of a water-resources investigation begun by the U.S. Geological Survey in 1994 with the overall objective of gathering sufficient geochemical, hydrologic, and geologic information so that a sound remediation strategy for the Copper Bluff mine could be selected and implemented by the Hoopa Valley Tribe. This study had the following specific objectives: (1) monitor the quality and quantity of the mine discharge, (2) determine seasonal variability of metal concentrations and loads, (3) map and sample the underground mine workings to determine sources of flow and suitability of mine plugging options, and (4) analyze the likely consequences of various remediation and treatment options. Analysis of weekly water samples of adit discharge over parts of two wet seasons (January to July 1995 and October 1995 to May 1996) shows that dissolved copper (Cu) and zinc (Zn) concentrations (in samples filtered with 0.20-micrometer membranes) varied systematically in a seasonal pattern. Metal concentrations increased dramatically in response to the first increase in discharge, or first flush, early in the wet season. The value of Zn/Cu in the adit discharge exhibited systematic seasonal variations; an annual Zn/Cu cycle was observed, beginning with values between 3 and 5 during the main part of the wet season, rising to values between 6 and 10 during the period of lowest discharge late in the dry season, and then dropping dramatically to values less than 3 during the firstflush period. Values of pH were fairly constant in the range of 3.1 to 3.8 throughout the wet season and into the beginning of the dry season, but rose to values between 4.5 and 5.6 during the period of lowest discharge, from October to early December 1995. Underground reconnaissance was conducted once during dry-season conditions (September 1995) and twice during wet-season conditions (March 1995 and March 1996). The main tunnel was accessed to a distance of about 600 feet from the portal entrance. Water samples were collected at nine locations along the floor of the main tunnel and from several ore shoots to evaluate the contributions of water and dissolved constituents from different portions of the mine. Values of pH ranged from 2.5 to 6.4 at different underground locations, concentrations of copper ranged from 0.020 to 44 mg/L (milligram per liter), zinc from 6.3 to 160 mg/L, and cadmium from 0.010 to 0.47 mg/L. Discharge from the ore shoots ranged from less than 1 gallon per minute to more than30 gallons per minute and was always a small component of the total mine flow compared with the tunnel floor drainage. During March 1996, the main flow originated in the northernmost portion of the underground workings (inaccessible) and mixed with an unknown quantity of water upwelling from flooded lower workings. High-water marks observed on the tunnel walls indicate that past blockages impounded more than 100,000 gallons of water. Sudden release of a large volume of metal-rich water could have serious effects on fish and other aquatic resources in the Trinity River. Because of the hydrogeologic setting, mine plugging is not likely to offer an effective longterm solution to the problem of acid mine drainage at the Copper Bluff mine. The underground workings are close to a state highway and underlie a 500-foot-high bluff with highly fractured rocks that seep during the wet season. Total plugging likely would result in additional uncontrolled seepage and could potentially destabilize the highway. Partial plugging to restrict flow during periods of highest discharge may provide benefits in terms of reduced risk of catastrophic release without the additional risks associated with total plugging. Passive water treatment methods such as wetlands or anoxic limestone drains are unlikely to succeed at the Copper Bluff mine because of the lack of available space. A covered conveyance for the discharge directly from the mine portal to the Trinity River is a low-cost remedial alternative that would not reduce metal loadings to the Trinity River, but would reduce pathways of metal exposure to humans and wildlife. Lime neutralization or innovative, active water treatment methods such as bioreactors represent high-cost remedial alternatives that likely would be successful if sufficient resources were available for adequate design, testing, construction, long-term maintenance, and sludge disposal

Diversity of Dissimilatory Sulfite Reductase Genes (dsrAB) in a Salt Marsh Impacted by Long-Term Acid Mine Drainage▿ †

Sulfate-reducing bacteria (SRB) play a major role in the coupled biogeochemical cycling of sulfur and chalcophilic metal(loid)s. By implication, they can exert a strong influence on the speciation and mobility of multiple metal(loid) contaminants. In this study, we combined DsrAB gene sequencing and sulfur isotopic profiling to identify the phylogeny and distribution of SRB and to assess their metabolic activity in salt marsh sediments exposed to acid mine drainage (AMD) for over 100 years. Recovered dsrAB sequences from three sites sampled along an AMD flow path indicated the dominance of a single Desulfovibrio species. Other major sequence clades were related most closely to Desulfosarcina, Desulfococcus, Desulfobulbus, and Desulfosporosinus species. The presence of metal sulfides with low δ34S values relative to δ34S values of pore water sulfate showed that sediment SRB populations were actively reducing sulfate under ambient conditions (pH of ∼2), although possibly within less acidic microenvironments. Interestingly, δ34S values for pore water sulfate were lower than those for sulfate delivered during tidal inundation of marsh sediments. 16S rRNA gene sequence data from sediments and sulfur isotope data confirmed that sulfur-oxidizing bacteria drove the reoxidation of biogenic sulfide coupled to oxygen or nitrate reduction over a timescale of hours. Collectively, these findings imply a highly dynamic microbially mediated cycling of sulfate and sulfide, and thus the speciation and mobility of chalcophilic contaminant metal(loid)s, in AMD-impacted marsh sediments