Thermodynamic Simulation of Carbonate Cements-Water-Carbon Dioxide Equilibrium in Sandstone for Prediction of Precipitation/Dissolution of Carbonate Cements

Carbonate cements, such as calcite, dolomite, ferrocalcite and ankerite, play important roles in the formation of pores in sandstones: precipitation of carbonate cements modifies pores and inhibits compaction, while dissolution creates secondary pores. This work proposed a precipitation-dissolution model for carbonate cements-CO2-H2O system by means of ion equilibrium concentration ([M2+], M = Ca, Mg, Fe or Mn) with different factors, such as temperature, depth, pH, [Formula: see text], variable rock composition and overpressure. Precipitation-dissolution reaction routes were also analyzed by minimization of the total Gibbs free energy (ΔG). Δ[M2+], the variation of [Ca2+], [Fe2+], [Mg2+] or [Mn2+] for every 100 m of burial depths, is used to predict precipitation or dissolution. The calculation results indicate that the increasing temperature results in decrease of equilibrium constant of reactions, while the increasing pressure results in a relatively smaller increase of equilibrium constant; As a result, with increasing burial depth, which brings about increase of both temperature and pressure, carbonate cements dissolve firstly and produces the maximal dissolved amounts, and then precipitation happens with further increasing depth; For example, calcite is dissolving from 0.0 km to 3.0 km with a maximal value of [Ca2+] at depth of 0.8 km, and then precipitates with depth deeper than 3.0 km. Meanwhile, with an increasing CO2 mole fraction in the gaseous phase from 0.1% to 10.0% in carbonate systems, the aqueous concentration of metal ions increases, e.g., dissolved amount of CaFe0.7Mg0.3(CO3)2 increases and reaches maximum of 1.78 mmol·L-1 and 8.26 mmol·L-1 at burial depth of 0.7 km with CO2 mole fraction of 0.1% and 10.0%, respectively. For the influence of overpressure in the calcite system, with overpressure ranging from 36 MPa to 83 MPa, pH reaches a minimum of 6.8 at overpressure of 51 MPa; meanwhile, Δ[Ca2+] increases slightly from -2.24 mmol·L-1 to -2.17 mmol·L-1 and remains negative, indicating it is also a precipitation process at burial depth of 3.9 km where overpressure generated. The method used in this study can be applied in assessing burial precipitation-dissolution processes and predicting possible pores in reservoirs with carbonate cement-water-carbon dioxide

Ibex: Privacy-preserving ad conversion tracking and bidding (full version)

This paper introduces Ibex, an advertising system that reduces the amount of data that is collected on users while still allowing advertisers to bid on real-time ad auctions and measure the effectiveness of their ad campaigns. Specifically, Ibex addresses an issue in recent proposals such as Google’s Privacy Sandbox Topics API in which browsers send information about topics that are of interest to a user to advertisers and demand-side platforms (DSPs). DSPs use this information to (1) determine how much to bid on the auction for a user who is interested in particular topics, and (2) measure how well their ad campaign does for a given audience (i.e., measure conversions). While Topics and related proposals reduce the amount of user information that is exposed, they still reveal user preferences. In Ibex, browsers send user information in an encrypted form that still allows DSPs and advertisers to measure conversions, compute aggregate statistics such as histograms about users and their interests, and obliviously bid on auctions without learning for whom they are bidding. Our implementation of Ibex shows that creating histograms is 1.7–2.5× more expensive for browsers than disclosing user information, and Ibex’s oblivious bidding protocol can finish auctions within 550 ms. We think this makes Ibex capable of preserving a good experience while improving user privacy

Incremental Offline/Online PIR (extended version)

Recent private information retrieval (PIR) schemes preprocess the database with a query-independent offline phase in order to achieve sublinear computation during a query-specific online phase. These offline/online protocols expand the set of applications that can profitably use PIR, but they make a critical assumption: that the database is immutable. In the presence of changes such as additions, deletions, or updates, existing schemes must preprocess the database from scratch, wasting prior effort. To address this, we introduce incremental preprocessing for offline/online PIR schemes, allowing the original preprocessing to continue to be used after database changes, while incurring an update cost proportional to the number of changes rather than the size of the database. We adapt two offline/online PIR schemes to use incremental preprocessing and show how it significantly improves the throughput and reduces the latency of applications where the database changes over time

Addax: A fast, private, and accountable ad exchange infrastructure

This paper proposes Addax, a fast, verifiable, and private online ad exchange. When a user visits an ad-supported site, Addax runs an auction similar to those of leading exchanges; Addax requests bids, selects the winner, collects payment, and displays the ad to the user. A key distinction is that bids in Addax’s auctions are kept private and the outcome of the auction is publicly verifiable. Addax achieves these properties by adding public verifiability to the affine aggregatable encodings in Prio (NSDI’17) and by building an auction protocol out of them. Our implementation of Addax over WAN with hundreds of bidders can run roughly half the auctions per second as a non-private and non-verifiable exchange, while delivering ads to users in under 600 ms with little additional bandwidth requirements. This efficiency makes Addax the first architecture capable of bringing transparency to this otherwise opaque ecosystem

Competition adsorption of malachite green and rhodamine B on polyethylene and polyvinyl chloride microplastics in aqueous environment

Microplastics (MPs) will cause compound pollution by combining with organic pollutants in the aqueous environment. It is important for environmental protection to study the adsorption mechanism of different MPs for pollutants. In this study, the adsorption behaviors of malachite green (MG) and rhodamine B (RhB) on polyethylene (PE) and polyvinyl chloride (PVC) were studied in single systems and binary systems, separately. The results show that in single system, the adsorptions of between MPs for pollutants (MG and RhB) are more consistent with the pseudo-second-order kinetics and Freundlich isotherm model, the adsorption capacity of both MPs for MG is greater than that of RhB. The adsorption capacities of MG and RhB were 7.68 mg/g and 2.83 mg/g for PVC, 4.52 mg/g and 1.27 mg/g for PE. In the binary system, there exist competitive adsorption between MG and RhB on MPs. And the adsorption capacities of PVC for the two dyes are stronger than those of PE. This is attributed to the strong halogen-hydrogen bond between the two dyes and PVC, and the larger specific surface area of PVC. This study revealed the interaction and competitive adsorption mechanism between binary dyes and MPs, which is of great significance for understanding the interactions between dyes and MPs in the multi-component systems.publishedVersio

The Impact of Self-Relevance on Preschool Children’s Sharing

This study was designed to investigate the impact of self-relevance between preschool children and recipients on children’s sharing behavior in dictator games using a forced-choice resource distribution paradigm. Experiment 1: A total of 75 children aged 3–6 years were evaluated in a first-party situation in which they were distributed as recipients and dictators and shared resources with distracting recipients with different extents of self-relevance under three different payoff structures, including non-costly, costly, and envy structures. Children could choose between a sharing option and a non-sharing option. The results showed that, in a first-party situation, children aged 3–6 years old typically share more resources with highly self-relevant recipients (friends) than with moderately self-relevant recipients (acquaintances) and lowly self-relevant recipients (strangers) and that they share more resources with moderately self-relevant recipients (acquaintances) than lowly self-relevant recipients (strangers). Experiment 2: A total of 62 children aged 3–6 years old were evaluated in a third-party situation in which they were distributed not as recipients but only dictators, making decisions between the options of sharing more or sharing less with distracting recipients who had different extents of self-relevance under three different payoff structures, such as non-bias, high self-bias, and low self-bias. The results showed that, in a third-party situation, children typically share in a similar manner to that of Experiment 1, meaning that children display selective generosity and that the self-relevance between the children and recipients played a key role. Across age groups, this study of preschool children (total N = 137) demonstrates a degree of effect of self-relevance on preschool children’s sharing in first-party and third-party situations, with highly self-relevant recipients receiving a more preferential share in the dictator game than those with low self-relevance, although this effect was stronger in the older preschool children