Imaging through turbid media with a nonlinear-optical correlation time gate

Experiments directed towards a clinically useful optical imaging system use long-pulse near-infrared lasers and a correlation time gate based on degenerate four-wave mixing in a nonlinear medium

Comparison among five hydrodynamic codes with a diverging-converging nozzle experiment

A realistic open-cycle gas-core nuclear rocket simulation model must be capable of a self-consistent nozzle calculation in conjunction with coupled radiation and neutron transport in three spatial dimensions. As part of the development effort for such a model, five hydrodynamic codes were used to compare with a converging-diverging nozzle experiment. The codes used in the comparison are CHAD, FLUENT, KIVA2, RAMPANT, and VNAP2. Solution accuracy as a function of mesh size is important because, in the near term, a practical three-dimensional simulation model will require rather coarse zoning across the nozzle throat. In the study, four different grids were considered. (1) coarse, radially uniform grid, (2) coarse, radially nonuniform grid, (3) fine, radially uniform grid, and (4) fine, radially nonuniform grid. The study involves code verification, not prediction. In other words, the authors know the solution they want to match, so they can change methods and/or modify an algorithm to best match this class of problem. In this context, it was necessary to use the higher-order methods in both FLUENT and RAMPANT. In addition, KIVA2 required a modification that allows significantly more accurate solutions for a converging-diverging nozzle. From a predictive point of view, code accuracy with no tuning is an important result. The most accurate codes on a coarse grid, CHAD and VNAP2, did not require any tuning. Their main comparison among the codes was the radial dependence of the Mach number across the nozzle throat. All five codes yielded a very similar solution with fine, radially uniform and radially nonuniform grids. However, the codes yielded significantly different solutions with coarse, radially uniform and radially nonuniform grids. For all the codes, radially nonuniform zoning across the throat significantly increased solution accuracy with a coarse mesh. None of the codes agrees in detail with the weak shock located downstream of the nozzle throat, but all the codes indicated the presence of a weak downstream shock

Two-billion-year-old evaporites capture Earth's great oxidation

Funding sources: Simons Foundation (SCOL 339006 to C.L.B.), European Research Council (ERC Horizon 2020 grant 678812 to M.C.), Research Council of Norway (RCN Centres of Excellence funding scheme project 223259 to K.P. and A.L.), Estonian Science Agency (PUT696 to K.K., A.L., K.P., T.K.).Major changes in atmospheric and ocean chemistry occurred in the Paleoproterozoic Era (2.5–1.6 billion years ago). Increasing oxidation dramatically changed Earth’s surface, but few quantitative constraints exist on this important transition. This study describes the sedimentology, mineralogy, and geochemistry of a remarkably preserved two-billion-year-old and ~800 meter-thick evaporite succession from the Onega Basin in Russian Karelia. The deposit consists of a basal unit dominated by halite (~100 m) followed by anhydrite-magnesite (~500 m) and dolomite-magnesite (~200 m) dominated units. The evaporite minerals robustly constraint marine sulfate concentrations to at least 10 millimoles per kilogram of water, representing an oxidant reservoir equivalent to over 20% of the modern ocean-atmosphere oxidizing capacity. These results show that substantial amounts of surface oxidant accumulated during this critical transition in Earth’s oxygenation.PostprintPeer reviewe

The freeze-shut of a convectively cooled parallel plate channel subjected to laminar internal liquid flow

The paper presents an approximative solution for the time dependent development of the ice layers at the cooled walls inside a parallel plate channel. The upper and the lower wall of the channel are cooled by an uniform external convection. By assuming a constant pressure drop across the channel, the freeze-shut of the planar channel could be calculated approximately. It was found out that the origin of the freezing fronts moves upstream during the ice layer growth. Furthermore a simple criterion is presented to predict whether a given system will lead to blockade.Die vorliegende Arbeit stellt eine Approximationslösung vor, die das instationäre Wachstum der Eisschichten in einem ebenen, laminar durchströmten Kanal beschreibt. Die obere und die untere Wand des Kanals werden hierbei konvektiv gekühlt. Unter der Annahme eines zeitlich konstanten Druckverlustes im Kanal ist es möglich, das instationäre Verhalten der Erstarrungsfronten, bis hin zur Blockade des Kanals, approximativ zu berechnen. Als ein Ergebnis der Arbeit ergibt sich, daß der örtliche Beginn der erstarrten Schicht an der Kanalwand mit dicker werdenden Eisschichten stromaufwärts wandert. Weiterhin wird ein Kriterium angegeben, das es erlaubt, a priori darüber zu entscheiden, ob das System bei den vorliegenden Verhältnissen zufriert

A theoretical and experimental investigation of smooth- and wavy ice layers in laminar and turbulent flow inside an asymmetrically cooled parallel-plate channel

The present paper shows the adaption of the numerical model originally developed by Weigand and Beer [14] for calculating steady-state ice layers inside an asymmetrically cooled parallel-plate channel. The investigation shows the characteristics in ice formation behaviour due to asymmetrically cooled walls. Further, a simple analytical model is presented for calculating smooth ice layers in turbulent flow. The study is supported by own measurements of the freezing fronts inside an asymmetrically cooled channel. A comparison between theoretical calculations and measurements shows generally good agreement.Die vorliegende Arbeit beschreibt die Anwendung des von Weigand und Beer [14] entwickelten, numerischen Modells zur Vorhersage von Eisschichten in einem ebenen, asymmetrisch gekühlten Kanal. Die Studie befaßt sich mit den Unterschieden in der Eisschichtbildung aufgrund der asymmetrisch gekühlten Kanalwände. Weiterhin wird ein einfaches Verfahren angegeben, mit dem sich die Gestalt von glatten Eisschichten bei turbulenter Strömung und asymmetrischer Kühlung sehr einfach berechnen läßt. Die analytisch und numerisch gewonnenen Resultate werden anschließend mit eigenen Messungen von Eisschichten verglichen, wobei eine im allgemeinen gute Übereinstimmung zwischen Theorie und Experiment zu beobachten ist

Onset of the aerobic nitrogen cycle during the Great Oxidation Event

The rise of oxygen on the early Earth (about 2.4 billion years ago)1 caused a reorganization of marine nutrient cycles2, 3, including that of nitrogen, which is important for controlling global primary productivity. However, current geochemical records4 lack the temporal resolution to address the nature and timing of the biogeochemical response to oxygenation directly. Here we couple records of ocean redox chemistry with nitrogen isotope (15N/14N) values from approximately 2.31-billion-year-old shales5 of the Rooihoogte and Timeball Hill formations in South Africa, deposited during the early stages of the first rise in atmospheric oxygen on the Earth (the Great Oxidation Event)6. Our data fill a gap of about 400 million years in the temporal 15N/14N record4 and provide evidence for the emergence of a pervasive aerobic marine nitrogen cycle. The interpretation of our nitrogen isotope data in the context of iron speciation and carbon isotope data suggests biogeochemical cycling across a dynamic redox boundary, with primary productivity fuelled by chemoautotrophic production and a nitrogen cycle dominated by nitrogen loss processes using newly available marine oxidants. This chemostratigraphic trend constrains the onset of widespread nitrate availability associated with ocean oxygenation. The rise of marine nitrate could have allowed for the rapid diversification and proliferation of nitrate-using cyanobacteria and, potentially, eukaryotic phytoplankton

Earth: Atmospheric Evolution of a Habitable Planet

Our present-day atmosphere is often used as an analog for potentially habitable exoplanets, but Earth's atmosphere has changed dramatically throughout its 4.5 billion year history. For example, molecular oxygen is abundant in the atmosphere today but was absent on the early Earth. Meanwhile, the physical and chemical evolution of Earth's atmosphere has also resulted in major swings in surface temperature, at times resulting in extreme glaciation or warm greenhouse climates. Despite this dynamic and occasionally dramatic history, the Earth has been persistently habitable--and, in fact, inhabited--for roughly 4 billion years. Understanding Earth's momentous changes and its enduring habitability is essential as a guide to the diversity of habitable planetary environments that may exist beyond our solar system and for ultimately recognizing spectroscopic fingerprints of life elsewhere in the Universe. Here, we review long-term trends in the composition of Earth's atmosphere as it relates to both planetary habitability and inhabitation. We focus on gases that may serve as habitability markers (CO2, N2) or biosignatures (CH4, O2), especially as related to the redox evolution of the atmosphere and the coupled evolution of Earth's climate system. We emphasize that in the search for Earth-like planets we must be mindful that the example provided by the modern atmosphere merely represents a single snapshot of Earth's long-term evolution. In exploring the many former states of our own planet, we emphasize Earth's atmospheric evolution during the Archean, Proterozoic, and Phanerozoic eons, but we conclude with a brief discussion of potential atmospheric trajectories into the distant future, many millions to billions of years from now. All of these 'Alternative Earth' scenarios provide insight to the potential diversity of Earth-like, habitable, and inhabited worlds.Comment: 34 pages, 4 figures, 4 tables. Review chapter to appear in Handbook of Exoplanet

Short communication: Estimation of yield stress/viscosity of molten octol

Explosive HMX particles are similar in morphology and chemistry to RDX particles, the main constituent of Composition B-3 (Comp B-3). This suggests molten HMX-TNT formulations may show Bingham plasticity, much like recent studies have shown for Comp B-3. Here a Bingham plastic viscosity model, including yield stress and shear thinning, is presented for octol (70/30wt% HMX/TNT) as a function of HMX particle volume fraction. The effect of HMX dissolution into molten TNT is included in this analysis

Methane Conversion to Fuels and Chemicals: Opportunities and Approaches

This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Methane, the primary component of natural gas, has reserves that are on the order of those of petroleum. Processes that utilize these vast supplies of methane will need to be developed to replace dwindling supplies of petroleum in the future. Processes utilizing natural gas promise to be more environmentally friendly, as natural gas as a feedstock is freer of contaminants and more readily purified than petroleum. Short contact time reactor configurations are likely candidates for this application. The authors objectives are to develop reactor designs and computer models appropriate for short contact time applications. They have succeeded in assembling both an experimental facility for investigating the performance of short contact time reactors, and a computer simulation that includes full mass and heat transport as well as coupled surface and gas phase detailed chemical kinetics