Critically phase-matched Ti:sapphire-laserpumped deep-infrared femtosecond optical parametric oscillator based on CdSiP2

We report a high-repetition-rate femtosecond optical parametric oscillator (OPO) for the deep-infrared (deep-IR) based on type-I critical phase-matching in CdSiP2 (CSP), pumped directly by a Ti:sapphire laser. Using angle-tuning in the CSP crystal, the OPO can be continuously tuned across 7306–8329 nm (1201–1369  cm−1) in the deep-IR. It delivers up to 18 mW of idler average power at 7306 nm and >7  mW beyond 8000 nm at 80.5 MHz repetition rate, with the spectra exhibiting bandwidths of >150  nm across the tuning range. Moreover, the signal is tunable across 1128–1150 nm in the near-infrared, providing up to 35 mW of average power in ∼266  fs pulses at 1150 nm. Both beams exhibit single-peak Gaussian distribution in TEM00 spatial profile. With an equivalent spectral brightness of ∼5.6×1020photons s−1 mm−2 sr−10.1% BW−1, this OPO represents a viable alternative to synchrotron and supercontinuum sources for deep-IR applications in spectroscopy, metrology, and medical diagnostics.Peer ReviewedPostprint (author's final draft

Terahertz generation by optical rectification in uniaxial birefringent crystals

The angular dependence of terahertz (THz) emission from birefringent crystals can differ significantly from that of cubic crystals. Here we consider optical rectification in uniaxial birefringent materials, such as chalcopyrite crystals. The analysis is verified in (110)-cut ZnGeP_2 and compared to (zincblende) GaP. Although the crystals share the same nonzero second-order tensor elements, the birefringence in chalcopyrite crystals cause the pump pulse polarization to evolve as it propagates through the crystal, resulting in a drastically different angular dependence in chalcopyrite crystals. The analysis is extended to {012}- and {114}-cut chalcopyrite crystals and predicts more efficient conversion for the {114} crystal cut over the {012}- and {110}-cuts.Comment: 6 pages, 3 figure, online journal articl

Pump-tuned deep-infrared femtosecond optical parametric oscillator across 6-7 μm based on CdSiP2

We report on a high-power femtosecond optical parametric oscillator (OPO) at 80 MHz repetition rate, tunable across 6318–7061 nm in the deep-infrared (deep-IR) using pump wavelength tuning. The OPO, based on CdSiP2CdSiP2 (CSP), is synchronously pumped by a commercial Ti:sapphire-pumped femtosecond OPO in the near-IR, enabling rapid static tuning of the CSP OPO with minimal adjustments to its cavity length. The deep-IR CSP OPO provides as much as 32 mW of average idler power at 6808 nm with spectral bandwidth >1000  nm>1000  nm (at −10  dB−10  dB level) across the tuning range. By implementing intracavity dispersion control, near-transform-limited signal pulses of ∼100  fs∼100  fs duration with smooth single-peak spectrum are achieved at 1264 nm, corresponding to an idler wavelength at 6440 nm. To the best of our knowledge, this is the first time such practical idler powers in the deep-IR have been generated from a dispersion-compensated CSP femtosecond OPO at sub-100 MHz repetition rate.Peer ReviewedPostprint (author's final draft

Ti:sapphire-pumped deep-infrared femtosecond optical parametric oscillator based on CdSiP2

We report on a femtosecond optical parametric oscillator (OPO) for the deep-infrared (deep-IR) based on the Kerr-lens-mode-locked Ti:sapphire laser as the pump source. By deploying a novel cascaded intracavity arrangement, comprising a femtosecond OPO based on the nonlinear crystal, CdSiP2CdSiP2, synchronously pumped internal to a MgO:PPLN femtosecond OPO, we have generated broadly tunable radiation across 5958–8117 nm using rapid static cavity delay tuning, with a maximum power of 64 μW at 6791 nm, limited by the absorption in mirror substrates as well as polarization-dependent intracavity losses. The deep-IR idler power exhibits excellent passive stability of better than 1.1% rms over 2 h, with a spectral bandwidth as large as ∼650  nm∼650  nm at ∼6800  nm∼6800  nm. The demonstrated concept is generic and can be similarly deployed in other operating time scales and wavelength regions, also using different laser pump sources and nonlinear materials.Peer ReviewedPostprint (author's final draft

High-power femtosecond mid-infrared optical parametric oscillator at 7 μm based on CdSiP2

We report a femtosecond optical parametric oscillator (OPO) for the mid-infrared (mid-IR), generating a record average power of 110 mW at 7 μm. The OPO, based on CdSiP2 (CSP) as the nonlinear crystal, provides idler wavelength tuning across 6540–7186 nm with spectral bandwidths >400  nm at −10  dB level over the entire range, and a maximum bandwidth of 478 nm at 6.9 μm. To the best of our knowledge, this is the highest average power generated from a femtosecond OPO in the deep mid-IR. The OPO also provides near-IR signal wavelengths tunable across 1204–1212 nm with a usable power of 450 mW in 418-fs pulses at 1207 nm. The simultaneously measured signal and idler power exhibit a passive stability better than 1.6% rms and 3% rms, respectively. A mid-IR idler spectral stability with a standard deviation of the frequency fluctuations better than 40 MHz over 15 min, limited by the measurement resolution, is realized. Using the mid-IR idler from the CSP OPO, we perform Fourier-transform spectroscopy to detect liquid phase organic solvent, toluene (C7H8), in the molecular fingerprint region.Postprint (author’s final draft

Electron paramagnetic resonance and optical absorption study of acceptors in CdSiP2 crystals

Cadmium silicon diphosphide (CdSiP2) is a nonlinear material often used in optical parametric oscillators (OPOs) to produce tunable laser output in the mid-infrared. Absorption bands associated with donors and acceptors may overlap the pump wave- length and adversely affect the performance of these OPOs. In the present investigation, electron paramagnetic resonance (EPR) is used to identify two unintentionally present acceptors in large CdSiP2 crystals. These are an intrinsic silicon-on-phosphorus anti- site and a copper impurity substituting for cadmium. When exposed to 633 nm laser light at temperatures near or below 80 K, they convert to their neutral paramagnetic charge states (Si0P and Cu0Cd) and can be monitored with EPR. The corresponding donor serving as the electron trap is the silicon-on-cadmium antisite (Si2+ before illumina- above 90 K quickly destroys the EPR signals from both acceptors and the associated donor. Broad optical absorption bands peaking near 0.8 and 1.4 μm are also pro- duced at low temperature by the 633 nm light. These absorption bands are associated with the Si0P and Cu0Cd acceptors. © 2018 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). https://doi.org/10.1063/1.504180

Defect-related optical absorption bands in CdSiP2 crystals

When used as optical parametric oscillators, CdSiP2 crystals generate tunable output in the mid-infrared. Their performance, however, is often limited by unwanted optical absorption bands that overlap the pump wavelengths. A broad defect-related optical absorption band peaking near 800 nm, with a shoulder near 1 µm, can be photoinduced at room temperature in many CdSiP2 crystals. This absorption band is efficiently produced with 633 nm laser light and decays with a lifetime of ∼0.5 s after removal of the excitation light. The 800 nm band is accompanied by a less intense absorption band peaking near 1.90 µm. Data from eight CdSiP2 crystals grown at different times show that the singly ionized silicon vacancy (VSi− role= presentation style= box-sizing: border-box; display: inline; font-size: 12.880000114440918px; line-height: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative; \u3e−) is responsible for the photoinduced absorption bands. Electron paramagnetic resonance (EPR) is used to identify and directly monitor these silicon vacancies

Variable-range hopping in quasi-one-dimensional electron crystals

We study the effect of impurities on the ground state and the low-temperature dc transport in a 1D chain and quasi-1D systems of many parallel chains. We assume that strong interactions impose a short-range periodicicity of the electron positions. The long-range order of such an electron crystal (or equivalently, a $4 k_F$ charge-density wave) is destroyed by impurities. The 3D array of chains behaves differently at large and at small impurity concentrations $N$. At large $N$, impurities divide the chains into metallic rods. The low-temperature conductivity is due to the variable-range hopping of electrons between the rods. It obeys the Efros-Shklovskii (ES) law and increases exponentially as $N$ decreases. When $N$ is small, the metallic-rod picture of the ground state survives only in the form of rare clusters of atypically short rods. They are the source of low-energy charge excitations. In the bulk the charge excitations are gapped and the electron crystal is pinned collectively. A strongly anisotropic screening of the Coulomb potential produces an unconventional linear in energy Coulomb gap and a new law of the variable-range hopping $-\ln\sigma \sim (T_1 / T)^{2/5}$. $T_1$ remains constant over a finite range of impurity concentrations. At smaller $N$ the 2/5-law is replaced by the Mott law, where the conductivity gets suppressed as $N$ goes down. Thus, the overall dependence of $\sigma$ on $N$ is nonmonotonic. In 1D, the granular-rod picture and the ES apply at all $N$. The conductivity decreases exponentially with $N$. Our theory provides a qualitative explanation for the transport in organic charge-density wave compounds.Comment: 20 pages, 7 figures. (v1) The abstract is abridged to 24 lines. For the full abstract, see the manuscript (v2) several changes in presentation per referee's comments. No change in result

Sedimentation Tanks for Treating Rainwater: CFD Simulations and PIV Experiments

The removal of solids is the most important step when treating rainwater. The article evaluates two designs of sedimentation tanks that can be used for the continuous separation of fine particles from water: OS—standard sedimentation tanks, and OW—swirl sedimentation tanks. The tanks were studied by conducting computational fluid dynamics (CFD) modeling and particle image velocimetry (PIV) experiments. The settling process in sedimentation tank was carried out at varying operating flow rates. A tank with a modified structure was used for the tests, where water was supplied by a nozzle placed at an angle. This solution made it possible to obtain a rotational flow that transported the suspended particles towards its wall, where downward axial velocity resulted in the settling of particles. Based on the research, it was observed that the flow patterns showed inward flow at the bottom of the tank and an upward flow and the lifting of the settled particles near the hatch at the bottom. The presented experimental measurements provided detailed insight into flow patterns, and valuable calibration and verification data for further CFD modeling. Traditional PIV techniques are useful in the case of standard design, whereas CFD is invaluable for supporting this work and for investigating the design of novel sedimentation tanks

Scaling slowly rotating asteroids with stellar occultations

Context. As evidenced by recent survey results, the majority of asteroids are slow rotators (spin periods longer than 12 h), but lack spin and shape models because of selection bias. This bias is skewing our overall understanding of the spins, shapes, and sizes of asteroids, as well as of their other properties. Also, diameter determinations for large (>60 km) and medium-sized asteroids (between 30 and 60 km) often vary by over 30% for multiple reasons. Aims. Our long-term project is focused on a few tens of slow rotators with periods of up to 60 h. We aim to obtain their full light curves and reconstruct their spins and shapes. We also precisely scale the models, typically with an accuracy of a few percent. Methods. We used wide sets of dense light curves for spin and shape reconstructions via light-curve inversion. Precisely scaling them with thermal data was not possible here because of poor infrared datasets: large bodies tend to saturate in WISE mission detectors. Therefore, we recently also launched a special campaign among stellar occultation observers, both in order to scale these models and to verify the shape solutions, often allowing us to break the mirror pole ambiguity. Results. The presented scheme resulted in shape models for 16 slow rotators, most of them for the first time. Fitting them to chords from stellar occultation timings resolved previous inconsistencies in size determinations. For around half of the targets, this fitting also allowed us to identify a clearly preferred pole solution from the pair of two mirror pole solutions, thus removing the ambiguity inherent to light-curve inversion. We also address the influence of the uncertainty of the shape models on the derived diameters. Conclusions. Overall, our project has already provided reliable models for around 50 slow rotators. Such well-determined and scaled asteroid shapes will, for example, constitute a solid basis for precise density determinations when coupled with mass information. Spin and shape models in general continue to fill the gaps caused by various biases