1,605 research outputs found
Strain- and Adsorption-Dependent Electronic States and Transport or Localization in Graphene
The chapter generalizes results on influence of uniaxial strain and
adsorption on the electron states and charge transport or localization in
graphene with different configurations of imperfections (point defects):
resonant (neutral) adsorbed atoms either oxygen- or hydrogen-containing
molecules or functional groups, vacancies or substitutional atoms, charged
impurity atoms or molecules, and distortions. To observe electronic properties
of graphene-admolecules system, we applied electron paramagnetic resonance
technique in a broad temperature range for graphene oxides as a good basis for
understanding the electrotransport properties of other active carbons. Applied
technique allowed observation of possible metal-insulator transition and
sorption pumping effect as well as discussion of results in relation to the
granular metal model. The electronic and transport properties are calculated
within the framework of the tight-binding model along with the Kubo-Greenwood
quantum-mechanical formalism. Depending on electron density and type of the
sites, the conductivity for correlated and ordered adsorbates is found to be
enhanced in dozens of times as compared to the cases of their random
distribution. In case of the uniaxially strained graphene, the presence of
point defects counteracts against or contributes to the band-gap opening
according to their configurations. The band-gap behaviour is found to be
nonmonotonic with strain in case of a simultaneous action of defect ordering
and zigzag deformation. The amount of localized charge carriers (spins) is
found to be correlated with the content of adsorbed centres responsible for the
formation of potential barriers and, in turn, for the localization effects.
Physical and chemical states of graphene edges, especially at a uniaxial strain
along one of them, play a crucial role in electrical transport phenomena in
graphene-based materials.Comment: 16 pages, 10 figure
Direct immobilization of phosphine-rhodium complex on MCM-41 for propene hydroformylation
MCM-41 molecular sieve supported Rh-PPh3 catalysts were prepared by the in-situ assembling of the metal complex from smaller moieties of Rh(acac) (CO)(2) and ligand of PPh3. The resulted guest/host materials (Rh-PPh3/MCM-41) were characterized by X-ray powder diffraction, FTIR and P-31 (H-1.) NMR, and served as catalysts for propene hydroformylation. The results showed negligible change in MCM-41 framework after propene hydroformylation at 393 K. Higher hydroformylation activities were obtained on Rh-PPh3/MCM-41 catalysts compared to that on Rh-PPh3/SiO2,
Periodic solutions for a class of nonlinear partial differential equations in higher dimension
We prove the existence of periodic solutions in a class of nonlinear partial
differential equations, including the nonlinear Schroedinger equation, the
nonlinear wave equation, and the nonlinear beam equation, in higher dimension.
Our result covers cases where the bifurcation equation is infinite-dimensional,
such as the nonlinear Schroedinger equation with zero mass, for which solutions
which at leading order are wave packets are shown to exist.Comment: 34 page
Intestinal Absorption and First-Pass Metabolism of Polyphenol Compounds in Rat and Their Transport Dynamics in Caco-2 Cells
<div><h3>Background</h3><p>Polyphenols, a group of complex naturally occurring compounds, are widely distributed throughout the plant kingdom and are therefore readily consumed by humans. The relationship between their chemical structure and intestinal absorption, transport, and first-pass metabolism remains unresolved, however.</p> <h3>Methods</h3><p>Here, we investigated the intestinal absorption and first-pass metabolism of four polyphenol compounds, apigenin, resveratrol, emodin and chrysophanol, using the <em>in vitro</em> Caco-2 cell monolayer model system and <em>in situ</em> intestinal perfusion and <em>in vivo</em> pharmacokinetic studies in rats, so as to better understand the relationship between the chemical structure and biological fate of the dietary polyphenols.</p> <h3>Conclusion</h3><p>After oral administration, emodin and chrysophanol exhibited different absorptive and metabolic behaviours compared to apigenin and resveratrol. The differences in their chemical structures presumably resulted in differing affinities for drug-metabolizing enzymes, such as glucuronidase and sulphatase, and transporters, such as MRP2, SGLT1, and P-glycoprotein, which are found in intestinal epithelial cells.</p> </div
Self-assembled InAs quantum dot formation on GaAs ring-like nanostructure templates
The evolution of InAs quantum dot (QD) formation is studied on GaAs ring-like nanostructures fabricated by droplet homo-epitaxy. This growth mode, exclusively performed by a hybrid approach of droplet homo-epitaxy and Stransky-Krastanor (S-K) based QD self-assembly, enables one to form new QD morphologies that may find use in optoelectronic applications. Increased deposition of InAs on the GaAs ring first produced a QD in the hole followed by QDs around the GaAs ring and on the GaAs (100) surface. This behavior indicates that the QDs prefer to nucleate at locations of high monolayer (ML) step density
Preliminary study on the utilization of Ca2+ and HCO3 − in karst water by different sources of Chlorella vulgaris
This article aims to present a picture of how a university discipline has been created in Lithuania, given the background of changes caused by the Lithuania’s emancipation from the Soviet Union. The theoretical frame of reference is provided by a modified model of Bronfenbrenners developmental ecology. Data collection has primarily been in the form of interviews with university staff from Lithuanian institutions for higher education. In addition to the interviews, literature lists, course schedules and other key documents have been collected and analysed. The analysis focuses on individual’s conceptualisation of three main areas. The study demonstrates how the creation of management and economics as a university discipline in Lithuania has been formed by a combination of political/ideological, economic, institutional and individual factors. One of the study’s main contributions is to highlight the significance of the concept of academic freedom and to focus on the paradox, where constraint under the old system is replaced by another form of constraint. In this case, where the rigidity of the old Soviet doctrine is replaced by a new freedom; but instead of being given greater opportunities to influence and change the subject, the academic staff are forced into a position where, once again they are subjugated to the influences of international sources
Observation of a ppb mass threshoud enhancement in \psi^\prime\to\pi^+\pi^-J/\psi(J/\psi\to\gamma p\bar{p}) decay
The decay channel
is studied using a sample of events collected
by the BESIII experiment at BEPCII. A strong enhancement at threshold is
observed in the invariant mass spectrum. The enhancement can be fit
with an -wave Breit-Wigner resonance function with a resulting peak mass of
and a
narrow width that is at the 90% confidence level.
These results are consistent with published BESII results. These mass and width
values do not match with those of any known meson resonance.Comment: 5 pages, 3 figures, submitted to Chinese Physics
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