Chemical Analysis of Air Particulate Matter Trapped by a Porous Material, Synthesized from Silica Fume and Sodium Alginate

This work shows the ability of a new porous material (SUNSPACE), obtained by industrial by-products, to sequestrate air particulate matter (PM). This activity allows introducing the azure chemistry approach, devoted to better link new remediation strategies and sustainability. In particular, SUNSPACE is synthesized from silica fume and sodium alginate; it can be shaped in a porous solid, and it looks promising for environmental application as nanoparticle sequestration. Studies to evaluate the sequestration capability of SUNSPACE are performed in different environments, with and without anthropogenic sources of PM. Solid SUNSPACE disc samples are used as passive samplers and exposed for one and two months, in vertical and horizontal positions, indoor, and outdoor. Total reflection X-ray fluorescence technique is employed to perform elemental chemical analysis of the entrapped PM. Two sample preparation strategies to evaluate the composition of PM are considered: sample sonication in Milli-Q water and total sample mineralization by microwave acid digestion. These two options are proposed to analyse different PM fractions: in particular, sonication allows removing the coarse PM, entrapped on external material surface pores; on the contrary, digestion can offer information on fine and ultrafine PM, trapped in internal pores. Results confirm the ability of the porous material to sequestrate air PM and the differences in the sample preparation, supported by elemental analysis, and show the difference in the coarse and fine air particulate matter composition. In summary, the new material results as very promising for applications requiring nanoparticle sequestration

Glassy Powder Derived from Waste Printed Circuit Boards for Methylene Blue Adsorption

Electronic waste (e-waste) is one of the fastest-growing waste streams in the world and Europe is classified as the first producer in terms of per capita amount. To reduce the environmental impact of e-waste, it is important to recycle it. This work shows the possibility of reusing glassy substrates, derived from the MW-assisted acidic leaching of Waste Printed Circuit Boards (WPCBs), as an adsorbent material. The results revealed an excellent adsorption capability against methylene blue (MB; aqueous solutions in the concentration range 10−5 M–2 × 10−5 M, at pH = 7.5). Comparisons were performed with reference samples such as activated carbons (ACs), the adsorbent mostly used at the industrial level; untreated PCB samples; and ground glass slides. The obtained results show that MW-treated WPCB powder outperformed both ground glass and ground untreated PCBs in MB adsorption, almost matching AC adsorption. The use of this new adsorbent obtained through the valorization of e-waste offers advantages not only in terms of cost but also in terms of environmental sustainability

Recovery of NMC-lithium battery black mass by microwave heating processes

The exceptional microwave absorption capabilities of carbon-based materials make them highly effective for facilitating various chemical reactions, such as synthesis, reduction, exfoliation, doping, and decoration. In this study, we applied microwave irradiation to the thermochemical treatment of spent nickel manganese cobalt (NMC622) lithium-ion batteries, obtained as a mix of the cathode and the anodic graphite. This approach significantly accelerated the chemical reactions, leveraging carbon's robust ability to absorb microwave energy. As a proof-of-concept, we demonstrated that within just 5 min, the carbothermic reduction reactions in the black mass facilitated the formation of water-soluble Li2O, and enhanced the solubility of Co, Mn, and Ni in a weak acid. More than 90% of Li and 87% of Mn are recovered. This method, which bypasses the need for cathodic and anodic separation, presents a promising new approach for recovering strategic metals from spent lithium-ion batteries

SUNSPACE, A Porous Material to Reduce Air Particulate Matter (PM)

The World Health Organization reports that every year several million people die prematurely due to air pollution. Poor air quality is a by-product of unsustainable policies in transportation, energy, industry, and waste management in the world's most crowded cities. Particulate matter (PM) is one of the major element of polluted air. PM can be composed by organic and inorganic species. In particular, heavy metals present in PM include, lead (Pb), mercury (Hg), cadmium, (Cd), zinc (Zn), nickel (Ni), arsenic (As), and molybdenum (Mo). Currently, vegetation is the only existing sustainable method to reduce anthropogenic PM concentrations in urban environments. In particular, the PM-retention ability of vegetation depends on the surface properties, related to the plant species, leaf and branch density, and leaf micromorphology. In this work, a new hybrid material called SUNSPACE (SUstaiNable materials Synthesized from by-Products and Alginates for Clean air and better Environment) is proposed for air PM entrapment. Candle burning tests are performed to compare SUNSPACE with Hedera Helix L. leafs with respect to their efficacy of reducing coarse and fine PM. The temporal variation of PM10 and PM2.5 in presence of the trapping materials, shows that Hedera Helix L. surface saturates more rapidly. In addition, the capability of SUNSPACE in ultrafine PM trapping is also demonstrated by using titanium dioxide nanoparticles with 25 nm diameter. Scanning electron microscope (SEM) and Transmission electron microscope (TEM) images of SUNSPACE after entrapment tests highlight the presence of collected nanoparticles until to about 0.04 mm in depth from the sample surface. N2 physisorption measurements allow to demonstrate the possibility to SUNSPACE regeneration by washing

Current Treatment of Endolymphatic Sac Tumor of the Temporal Bone

An endolymphatic sac tumor (ELST) is a rare, indolent but locally aggressive tumor arising in the posterior petrous ridge. Patients present with sensorineural hearing loss and tinnitus. As the tumor progresses, patients may experience vertigo, ataxia, facial nerve paresis, pain and otorrhea. Most patients present in their 4th or 5th decade with a wide age range. Patients with von Hippel–Lindau disease have an increased likelihood of developing ELST. Histologically, ELST is a low-grade adenocarcinoma. As it progresses, it destroys bone and extends into adjacent tissues. The likelihood of regional or distant metastases is remote. The optimal treatment is resection with negative margins. Patients with positive margins, gross residual disease, or unresectable tumor are treated with radiotherapy or radiosurgery. Late recurrences are common, so long follow-up is necessary to assess efficacy. The likelihood of cure depends on tumor extent and is probably in the range of 50–75%

The impacts of earthquakes on air pollution and strategies for mitigation: a case study of Turkey

: This study delves into the repercussions of the 2023 earthquake in Turkey, particularity its impact on air pollution. A year post-event, it is evident that scientific literature has paid limited attention to monitoring the situation. However, the release of hazardous substances, such as asbestos, lead, and other toxins, from damaged structures poses a significant threat by contaminating nearby air, soil, and water sources, thereby jeopardizing ecosystems and public well-being. The improper disposal of waste post-earthquake and the presence of mining and oil refinery sites in the region contribute to potential air pollutants. These circumstances create challenging environments conducive to the spread of respiratory diseases, with potential long-term health and social consequences. Unfortunately, existing data gaps hinder a comprehensive understanding of the situation. This paper pioneers the reporting and analysis of data regarding potential sources of air pollution resulting from the earthquake in Turkey. It also pinpoints gaps in knowledge, outlining areas that demand further investigation. To effectively prevent and mitigate air pollution risks and associated health concerns linked to earthquakes, strategic recommendations are proposed. A key suggestion is the establishment of post-disaster air pollution monitoring systems capable of swiftly identifying emerging health issues, facilitating efficient responses, and curtailing potential long-term effects of the disaster. The paper underscores the necessity for continuous health monitoring of the affected population to mitigate possible adverse impacts on human health. These strategies play a pivotal role in reducing the likelihood of air pollution, supporting emergency response and recovery initiatives, and fostering new dedicated scientific studies

The Reuse of Municipal Solid Waste Fly Ash as Flame Retardant Filler: A Preliminary Study

none2noThe growing increase in the production of municipal solid waste incinerator (MSWI) ashes has led to the research of new possibilities to reuse these by-products. This work aims to use MSW fly ash (FA) as a flame retardant filler. The FA was stabilized according to a simple stabilization process involving the mixing of only different ashes: bottom ash (BA), flue gas desulphurization (FGD) residues and coal fly ash (CFA). Stabilized FA, calcite and commercial flame retardants were compared as additives in an epoxy resin or polypropylene (PP) matrix. The self-extinguish performance of fillers was evaluated by fire resistance tests: the vertical burning test (UL94-V) and glow wire test (GWT) at 750 °C and 850 °C. A life cycle assessment (LCA) evaluation was also performed to estimate the reduction in environmental impact related to the production of the flame retardant with stabilized FA. The results show that this new filler is a promising alternative to traditional flame retardant. The ignition time of composites with calcite was lower than the corresponding sample with FA. From an environmental point of view, the replacement of calcite in an epoxy resin matrix or commercial flame retardant in a PP matrix with stabilized FA allows for a reduction in the impact of about 24.1% and 49.5%, respectively.openZanoletti, Alessandra; Ciacci, LucaZanoletti, Alessandra; Ciacci, Luc