Soft x-ray photoemission studies of Hf oxidation

Charging of oxide films under x rays is an important issue that must be taken into consideration for determination of core-level binding energies as well as valence band offsets. Measurements are taken as a function of time, thickness, and annealing condition. Photoemission results show the presence of metallic Hf with the 4f7/2 binding energy of 18.16 eV, and at least one clear suboxide peak

Instability, Intermixing and Electronic Structure at the Epitaxial LaAlO3/SrTiO3(001) Heterojunction

The question of stability against diffusional mixing at the prototypical LaAlO3/SrTiO3(001) interface is explored using a multi-faceted experimental and theoretical approach. We combine analytical methods with a range of sensitivities to elemental concentrations and spatial separations to investigate interfaces grown using on-axis pulsed laser deposition. We also employ computational modeling based on the density function theory as well as classical force fields to explore the energetic stability of a wide variety of intermixed atomic configurations relative to the idealized, atomically abrupt model. Statistical analysis of the calculated energies for the various configurations is used to elucidate the relative thermodynamic stability of intermixed and abrupt configurations. We find that on both experimental and theoretical fronts, the tendency toward intermixing is very strong. We have also measured and calculated key electronic properties such as the presence of electric fields and the value of the valence band discontinuity at the interface. We find no measurable electric field in either the LaAlO3 or SrTiO3, and that the valence band offset is near zero, partitioning the band discontinuity almost entirely to the conduction band edge. Moreover, we find that it is not possible to account for these electronic properties theoretically without including extensive intermixing in our physical model of the interface. The atomic configurations which give the greatest electrostatic stability are those that eliminate the interface dipole by intermixing, calling into question the conventional explanation for conductivity at this interface - electronic reconstruction. Rather, evidence is presented for La indiffusion and doping of the SrTiO3 below the interface as being the cause of the observed conductivity

Structure of the Dead Sea Pull-Apart Basin From Gravity Analyses

Analyses and modeling of gravity data in the Dead Sea pull-apart basin reveal the geometry of the basin and constrain models for its evolution. The basin is located within a valley which defines the Dead Sea transform plate boundary between Africa and Arabia. Three hundred kilometers of continuous marine gravity data, collected in a lake occupying the northern part of the basin, were integrated with land gravity data from Israel and Jordan to provide coverage to 30 km either side of the basin. Free-air and variable-density Bouguer anomaly maps, a horizontal first derivative map of the Bouguer anomaly, and gravity models of profiles across and along the basin were used with existing geological and geophysical information to infer the structure of the basin. The basin is a long (132 km), narrow (7-10 km), and deep (≤10 km) full graben which is bounded by subvertical faults along its long sides. The Bouguer anomaly along the axis of the basin decreases gradually from both the northern and southern ends, suggesting that the basin sags toward the center and is not bounded by faults at its narrow ends. The surface expression of the basin is wider at its center (≤16 km) and covers the entire width of the transform valley due to the presence of shallower blocks that dip toward the basin. These blocks are interpreted to represent the widening of the basin by a passive collapse of the valley floor as the full graben deepened. The collapse was probably facilitated by movement along the normal faults that bound the transform valley. We present a model in which the geometry of the Dead Sea basin (i.e., full graben with relative along-axis symmetry) may be controlled by stretching of the entire (brittle and ductile) crust along its long axis. There is no evidence for the participation of the upper mantle in the deformation of the basin, and the Moho is not significantly elevated. The basin is probably close to being isostatically uncompensated, and thermal effects related to stretching are expected to be minimal. The amount of crustal stretching calculated from this model is 21 km and the stretching factor is 1.19. If the rate of crustal stretching is similar to the rate of relative plate motion (6 mm/yr), the basin should be ~3.5 m.y. old, in accord with geological evidence

Paleoseismic History of the Dead Sea Fault Zone

International audienceThe aim of this entry is to describe the DSF as a transform plate boundary pointing out the rate of activedeformation, fault segmentation, and geometrical complexities as a control of earthquake ruptures. Thedistribution of large historical earthquakes from a revisited seismicity catalogue using detailedmacroseismic maps allows the correlation between the location of past earthquakes and fault segments.The recent results of paleoearthquake investigations (paleoseismic and archeoseismic) with a recurrenceinterval of large events and long-term slip rate are presented and discussed along with the identification ofseismic gaps along the fault. Finally, the implications for the seismic hazard assessment are also discussed

Origin and metamorphism of ultrabasic rocks associated with a subducted continental margin, Naxos (Cyclades, Greece)

Meta-peridotites outcropping at different structural levels within the Alpine metamorphic complex of the Cycladic island of Naxos were studied to re-examine their metamorphic evolution and possible tectonic mechanisms for emplacement of mantle material into the continental crust. The continental margin section exposed on Naxos, consisting of pre-Alpine basement and c. 7 km thick Mesozoic platform cover, has undergone intense metamorphism of Alpine age, comprising an Eocene (M1) blueschist event strongly overprinted by a Miocene Barrovian-type event (M2). Structural concordance with the country rocks and metasomatic zonation at the contact with the felsic host rocks indicate that the meta-peridotites have experienced the M2 metamorphism. This conclusion is supported by the similarity between metamorphic temperatures of the ultrabasic rocks and those of the host rocks. Maximum temperatures of 730–760 °C were calculated for the upper-amphibolite facies meta-peridotites (Fo–En–Hbl–Chl–Spl), associated with sillimanite gneisses and migmatites. Relict phases in ultrabasics of different structural levels indicate two distinct pre-M2 histories: whereas the cover-associated horizons have been affected by low-grade serpentinization prior to metamorphism, the basement- associated meta-peridotites show no signs of serpentinization and instead preserve some of their original mantle assemblage. The geochemical affinities of the two groups are also different. The basement-associated meta-peridotites retain their original composition indicating derivation by fractional partial melting of primitive lherzolite, whereas serpentinization has led to almost complete Ca-loss in the second group. The cover-associated ultrabasics are interpreted as remnants of an ophiolite sequence obducted on the adjacent continental shelf early in the Alpine orogenesis. In contrast, the basement-associated meta-peridotites were tectonically interleaved with the Naxos section at great depth during the Alpine collision and high P/T metamorphism. Their emplacement at the base of the orogenic wedge is inferred to have involved isobaric cooling from temperatures of c. 1050 °C within the spinel lherzolite field to eclogite facies temperatures of c. 600 °C