123 research outputs found
Donut and dynamic polarization effects in proton channeling through carbon nanotubes
We investigate the angular and spatial distributions of protons of the energy
of 0.223 MeV after channeling through an (11,~9) single-wall carbon nanotube of
the length of 0.2 m. The proton incident angle is varied between 0 and 10
mrad, being close to the critical angle for channeling. We show that, as the
proton incident angle increases and approaches the critical angle for
channeling, a ring-like structure is developed in the angular distribution -
donut effect. We demonstrate that it is the rainbow effect. When the proton
incident angle is between zero and a half of the critical angle for channeling,
the image force affects considerably the number and positions of the maxima of
the angular and spatial distributions. However, when the proton incident angle
is close to the critical angle for channeling, its influence on the angular and
spatial distributions is reduced strongly. We demonstrate that the increase of
the proton incident angle can lead to a significant rearrangement of the
propagating protons within the nanotube. This effect may be used to locate
atomic impurities in nanotubes as well as for creating nanosized proton beams
to be used in materials science, biology and medicine.Comment: 17 pages, 14 figure
Dynamic polarization effects on the angular distributions of protons channeled through carbon nanotubes in dielectric media
The best level of ordering and straightening of carbon nanotube arrays is
often achieved when they are grown in a dielectric matrix, so such structures
present the most suitable candidates for future channeling experiments with
carbon nanotubes. Consequently, we investigate here how the dynamic
polarization of carbon valence electrons in the presence of various surrounding
dielectric media affects the angular distributions of protons channeled through
(11,~9) single-wall carbon nanotubes. Proton speeds between 3 and 10 a.u.,
corresponding to energies of 0.223 and 2.49 MeV, are chosen with the nanotube's
length varied between 0.1 and 1 m. We describe the repulsive interaction
between a proton and the nanotube's atoms in a continuum-potential
approximation based on the Doyle-Turner potential, whereas the attractive image
force on a proton is calculated using a two-dimensional hydrodynamic model for
the dynamic response of the nanotube valence electrons, while assigning to the
surrounding medium an appropriate (frequency dependent) dielectric function.
The angular distributions of channeled protons are generated using a computer
simulation method which solves the proton equations of motion in the transverse
plane numerically. Our analysis shows that the presence of a dielectric medium
can strongly affect both the appearance and positions of maxima in the angular
distributions of channeled protons.Comment: 14 pages, 11 figures, Accepted for publication in Phys. Rev.
Invited Lecture INTERACTIONS OF IONS WITH CARBON NANO-STRUCTURES
Abstract. Investigation into the properties of carbon nano-structures, involving fullerene molecules, carbon nanotubes, and the most recently contrived graphene, has been growing at a relentless rate over the past decade or so owing to prospects of their applications in nanotechnology. While interactions with particle beams have been an important part of this research endeavor in the context of various spectroscopic techniques (TEM, EELS, ...), the use of energetic electron and ion beams has recently emerged as a novel engineering tool for modifications of atomic structure and electronic properties of carbon nano-structures In that context, the most widely studied themes in literature are concerned with changes in carbon nanotubes upon exposure to the ion-beam irradiation at energies ranging from several tens of eV to some MeV. On the other hand, the empty cylindrical space in individual carbon nanotubes, and a high degree of their ordering and alignment in structures called ropes or bundles, provide unique means for achieving the effect of ion channeling. Prospects of realization and a range of possible applications of ion channeling through carbon nanotubes at energies from keV to TeV have stimulated an active research area, which was recently reviewed After assessing some key experimental facts and the status of computer simulations of ion irradiation effects on carbon nanotubes, I shall discuss several problems arising in modeling of ion interactions with carbon nanotube
Trends in Metal Oxide Stability for Nanorods, Nanotubes, and Surfaces
The formation energies of nanostructures play an important role in
determining their properties, including the catalytic activity. For the case of
15 different rutile and 8 different perovskite metal oxides, we find that the
density functional theory (DFT) calculated formation energies of (2,2)
nanorods, (3,3) nanotubes, and the (110) and (100) surfaces may be described
semi-quantitatively by the fraction of metal--oxygen bonds broken and the
bonding band centers in the bulk metal oxide
Quasiparticle interfacial level alignment of highly hybridized frontier levels: HO on TiO(110)
Knowledge of the frontier levels' alignment prior to photo-irradiation is
necessary to achieve a complete quantitative description of HO
photocatalysis on TiO(110). Although HO on rutile TiO(110) has been
thoroughly studied both experimentally and theoretically, a quantitative value
for the energy of the highest HO occupied levels is still lacking. For
experiment, this is due to the HO levels being obscured by hybridization
with TiO(110) levels in the difference spectra obtained via ultraviolet
photoemission spectroscopy (UPS). For theory, this is due to inherent
difficulties in properly describing many-body effects at the
HO-TiO(110) interface. Using the projected density of states (DOS) from
state-of-the-art quasiparticle (QP) , we disentangle the adsorbate and
surface contributions to the complex UPS spectra of HO on TiO(110). We
perform this separation as a function of HO coverage and dissociation on
stoichiometric and reduced surfaces. Due to hybridization with the TiO(110)
surface, the HO 3a and 1b levels are broadened into several peaks
between 5 and 1 eV below the TiO(110) valence band maximum (VBM). These
peaks have both intermolecular and interfacial bonding and antibonding
character. We find the highest occupied levels of HO adsorbed intact and
dissociated on stoichiometric TiO(110) are 1.1 and 0.9 eV below the VBM. We
also find a similar energy of 1.1 eV for the highest occupied levels of HO
when adsorbed dissociatively on a bridging O vacancy of the reduced surface. In
both cases, these energies are significantly higher (by 0.6 to 2.6 eV) than
those estimated from UPS difference spectra, which are inconclusive in this
energy region. Finally, we apply self-consistent QP (scQP1) to obtain
the ionization potential of the HO-TiO(110) interface.Comment: 12 pages, 12 figures, 1 tabl
Long-term stability and optoelectronic performance enhancement of InAsP nanowires with an ultrathin InP passivation layer
The influence of nanowire (NW) surface states increases rapidly with the reduction of diameter and hence severely degrades the optoelectronic performance of narrow-diameter NWs. Surface passivation is therefore critical, but it is challenging to achieve long-term effective passivation without significantly affecting other qualities. Here, we demonstrate that an ultrathin InP passivation layer of 2–3 nm can effectively solve these challenges. For InAsP nanowires with small diameters of 30–40 nm, the ultrathin passivation layer reduces the surface recombination velocity by at least 70% and increases the charge carrier lifetime by a factor of 3. These improvements are maintained even after storing the samples in ambient atmosphere for over 3 years. This passivation also greatly improves the performance thermal tolerance of these thin NWs and extends their operating temperature from <150 K to room temperature. This study provides a new route toward high-performance room-temperature narrow-diameter NW devices with long-term stability
Utilisation of an operative difficulty grading scale for laparoscopic cholecystectomy
Background
A reliable system for grading operative difficulty of laparoscopic cholecystectomy would standardise description of findings and reporting of outcomes. The aim of this study was to validate a difficulty grading system (Nassar scale), testing its applicability and consistency in two large prospective datasets.
Methods
Patient and disease-related variables and 30-day outcomes were identified in two prospective cholecystectomy databases: the multi-centre prospective cohort of 8820 patients from the recent CholeS Study and the single-surgeon series containing 4089 patients. Operative data and patient outcomes were correlated with Nassar operative difficultly scale, using Kendall’s tau for dichotomous variables, or Jonckheere–Terpstra tests for continuous variables. A ROC curve analysis was performed, to quantify the predictive accuracy of the scale for each outcome, with continuous outcomes dichotomised, prior to analysis.
Results
A higher operative difficulty grade was consistently associated with worse outcomes for the patients in both the reference and CholeS cohorts. The median length of stay increased from 0 to 4 days, and the 30-day complication rate from 7.6 to 24.4% as the difficulty grade increased from 1 to 4/5 (both p < 0.001). In the CholeS cohort, a higher difficulty grade was found to be most strongly associated with conversion to open and 30-day mortality (AUROC = 0.903, 0.822, respectively). On multivariable analysis, the Nassar operative difficultly scale was found to be a significant independent predictor of operative duration, conversion to open surgery, 30-day complications and 30-day reintervention (all p < 0.001).
Conclusion
We have shown that an operative difficulty scale can standardise the description of operative findings by multiple grades of surgeons to facilitate audit, training assessment and research. It provides a tool for reporting operative findings, disease severity and technical difficulty and can be utilised in future research to reliably compare outcomes according to case mix and intra-operative difficulty
Can interventions that aim to decrease Lyme disease hazard at non-domestic sites be effective without negatively affecting ecosystem health? A systematic review protocol
Background
Lyme disease (LD) is the most commonly reported, broadly distributed vector-borne disease of the northern temperate zone. It is transmitted by ticks and, if untreated, can cause skin, cardiac, nervous system and musculoskeletal disease. The distribution and incidence of LD is increasing across much of North America and Western Europe. Interventions to decrease exposure to LD hazard by encouraging behavioural change have low acceptance in high risk groups, and a safe, effective human LD vaccine is not presently available. As a result, habitat level interventions to decrease LD hazard itself (i.e. levels of infected ticks) have been proposed. However, some interventions may potentially negatively affect ecosystem health, and consequentially be neither desirable, nor politically feasible. This systematic review will catalogue interventions that aim to reduce LD hazard at non-domestic sites, and examine the evidence supporting those which are unlikely to negatively affect ecosystem health.
Methods
The review will be carried out in two steps. First, a screening and cataloguing stage will be conducted to identify and characterise interventions to decrease LD hazard at non-domestic sites. Secondly, the subset of interventions identified during cataloguing as unlikely to negatively affect ecosystem health will be investigated. In the screening and cataloguing step literature will be collected through database searching using pre-chosen search strings, hand-searching key journals and reviewing the websites of public health bodies. Further references will be identified by contacting stakeholders and researchers. Article screening and assessment of the likely effects of interventions on ecosystem health will be carried out independently by two reviewers. A third reviewer will be consulted if disagreements arise. The cataloguing step results will be presented in tables. Study quality will then be assessed independently by two reviewers, using adapted versions of established tools developed in healthcare research. These results will be presented in a narrative synthesis alongside tables. Though a full meta-analysis is not expected to be possible, if sub-groups of studies are sufficiently similar to compare, a partial meta-analysis will be carried out
Skin Cancer:Epidemiology, Disease Burden, Pathophysiology, Diagnosis, and Therapeutic Approaches
Skin cancer, including both melanoma and non-melanoma, is the most common type of malignancy in the Caucasian population. Firstly, we review the evidence for the observed increase in the incidence of skin cancer over recent decades, and investigate whether this is a true increase or an artefact of greater screening and over-diagnosis. Prevention strategies are also discussed. Secondly, we discuss the complexities and challenges encountered when diagnosing and developing treatment strategies for skin cancer. Key case studies are presented that highlight the practic challenges of choosing the most appropriate treatment for patients with skin cancer. Thirdly, we consider the potential risks and benefits of increased sun exposure. However, this is discussed in terms of the possibility that the avoidance of sun exposure in order to reduce the risk of skin cancer may be less important than the reduction in all-cause mortality as a result of the potential benefits of increased exposure to the sun. Finally, we consider common questions on human papillomavirus infection
SNW1 Is a Critical Regulator of Spatial BMP Activity, Neural Plate Border Formation, and Neural Crest Specification in Vertebrate Embryos
In frog and fish embryos, SNW1 is a protein required for the spatio-temporal activity of BMP signaling necessary for neural plate border formation and specification of neural crest tissue
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