Aptidão agrícola e uso do solo baseado nas propriedades pedogenéticas de solos da transição cerrado-caatinga

The sustainable use of soil requires a broad knowledge of its genesis, morphology, properties, and distribution in the landscape. Thus, the objective of this study was to characterize the pedogenetic attributes of representative soils from the cerrado-caatinga transition of the Gurguéia river basin to indicate their agricultural potential and limitations for the implementation of agroforestry systems. National and international soil classification systems were used to define the soil classes. The limiting factors and agricultural potential were characterized following the evaluation system of the agricultural potential of Brazilian land. In general, profiles 1, 3, 5, and 6 had a low nutrient budget and a sandy to loam texture. Profiles 2, 4, and 7 showed high clay content and nutrient budget. The soil profiles were classified as Ustic Quartzipsamments, Udic Haplusterts, Xanthic Haplustox, Arenic Kanhaplustults, Typic Haplustox, and Aridic Dystrustept based on their pedogenetic characteristics. Udic Haplusterts and Arenic Kanhaplustults soils display restrictions regarding the planting of forests owing to oxygen and soil depth limitations. The other soil classes had adequate physical properties for the implementation of agricultural systems and pastures, including good drainage and medium texture; however, they had low natural fertility, and thus require technologies for soil acidity correction and fertilization. Ustic Quartzipsamments and Ustic soils require the implementation of conservation systems, such as agroforestry, to avoid degradation

Bedload and Suspended Sediment of a Watershed Impacted by Dams

Sediment transport relates to suspended sediment and bedload. The suspended sediment plays the most important role on the land-ocen sediment flux. On the other hand, the bedload should be considered in order to assess the impacts of dams on sediment transport and sediment yield. Recent effects of dam construction have been widely reported. The sediment load has been reduced by more than 75% for major rives, such as Nilo, Orange, Volta, Indus, Ebro, Kizil Irmark, Colorado, and Rio Grande and more than 40% of its lux is trapped within large dams. In addition, the multiple trapping through sequential dams has impacted the sediment transfer from terrestrial to coastal zone, triggering the coastal erosion. In terms of sediment retention and transport, China stands out the most impacted country by dams, followed by United States, and continents such as Europe, Africa, and South America. Based on the foregoing, the impact of dams on sediment transport and yield of an important Brazilian watershed with multiple dams will be the focus of this chapter. Thus, a three years field sampling (2009-2011) was carried out to measure the sediment yield of Capibaribe Watershed, and also its contribution to coastal erosion. The ratio between QB and SSQ ranged from 0.12% to 27.3% with 76% of all values lower than 5%. Usually, the bedload transport rate of a river is about 5–25% of the suspended sediment transport. This ranging sheds light on the lack of bedload reaching the coastal zone and it is likely one of the reasons to yield coastal erosion. The low rates can be attributed to the presence of dams which have been admitted to have a strong effect on sediment transport. The sediment yield was equal to 3.69, 4.36, and 6.7 t km-2 ano-1 in 2009, 2010, and 2011, respectively. In comparison with bedload yield, the suspended sediment yield was higher than 95% for all studied years. Therefore, the limited bedload supply – mainly responsible for construction of coastal landform – is likely contributing to the coastal erosion along part of the northeast region, Brazil. The multiple dams along the Capibaribe River watershed produce a deficit in sediment flux to coastal zone of Pernambuco State, Brazil, which relies on the low ratios between bedload and suspended sediment. As a result, it generates energy to coastal erosion of the Brazilian northeast

Geochemistry and Spatial Variability of Rare Earth Elements in Soils under Different Geological and Climate Patterns of the Brazilian Northeast

ABSTRACT Growth in the agricultural and industrial sectors has increased the demand for rare earth elements (REEs) in the production of technological devices and fertilizers. Thus, the accumulation of these elements in the soil has become an environmental concern. Here, we aim to determine the natural contents of REEs in soils derived from different parent materials and under climatic conditions ranging from humid to semi-arid. We then evaluate the influence of major elements and soil properties on the geochemistry of REEs. The contents of REEs were determined using inductively coupled plasma optical emission spectroscopy. Major elements were determined by X-ray fluorescence spectrometry. The mean content of REEs in soils from Rio Grande do Norte (RN), Brazil, were in the followed order (mg kg-1): Ce (40.4) > La (18.9) > Nd (15.8) > Pr (7.3) > Sm (3.0) > Gd (2.6) > Dy (1.0) > Er (0.7) > Yb (0.6) > Eu (0.5) = Tb (0.5) > Ho (0.3) > Lu (0.2). The parent material was the main factor that governed the geochemistry of the REEs in soils of RN. Higher levels of REEs were observed in soils derived from igneous and metamorphic rocks. In contrast, sedimentary rocks - except for the region formed from limestone - generated soils with lower contents of REEs in the state. In addition, soils developed from the same parent material and under different climatic conditions showed the same geochemical signatures for REEs in soils. These results confirm the small effect of climate on REE geochemistry in soils of RN and lead to the conclusion that the geochemical signature of REEs in these soils reflects the composition of the underlying parent material. The lack of significant correlation between (La/Yb)N ratio and the Chemical Alteration Index also confirms the low influence of climate on soil REE geochemistry. Among the major elements, Fe and Si had a greater influence on soil REE geochemistry. Higher REEs were seen in areas with more Fe and less Si. These REE levels were clearly controlled by the type of parent material. The Nd, Sm, Tb, Dy, Ho, Yb, and Er levels showed strong spatial dependence; this dependence was moderate for the Pr, La, Ce, Eu, Gd, and Lu levels. Spatial variability maps of REEs are particularly important to identify areas under environmental impact. Our results represent the most detailed study of the surface geochemistry of REEs in Brazilian soils and contribute to the scarce data available on these elements in Brazil

Rare Earth Element Concentrations in Brazilian Benchmark Soils

ABSTRACT: Studies regarding background concentrations of rare earth elements (REEs) are scarce and have mainly focused on a limited number of soil types from the northern hemisphere. The aim of this study was to determine REE concentrations in thirty-five benchmark soils of Brazil. Composite soil samples were taken from areas under native vegetation or with minimal anthropogenic influence. Concentrations of La, Ce, Pr, Nd, Sm, Eu, Gd, Yb, Lu, Dy, Er, Ho, Tb, Tm, Y, Sc, and Fe were determined by ICP-OES using a cyclonic spray chamber/nebulizer system after microwave acid digestion. Results were assessed by descriptive statistics, Pearson correlation, and principal component analysis (PCA). Regression analyses among Fe, organic carbon, and REEs were performed to provide a tool for estimating REE concentrations in soils. The REE concentrations in the Brazilian benchmark soils were in the following order: Ce > La > Nd > Pr > Y > Sm > Gd > Sc > Dy > Yb > Eu > Er > Tb > Ho > Lu > Tm. The clear decoupling between light and heavy rare earth elements in soils, indicated by multivariate analysis, is mainly related to differences in parent material. The lowest REE concentrations were found in sandy sediments, whereas the highest REE concentrations were observed in basalt, biotite gneiss, and clayey sediments. The organic carbon and Fe concentrations can properly predict REE concentrations in soils; such a finding can assist in estimating REE concentrations in soils not only in Brazil but also in similar soils developed under tropical conditions

Sediment source apportionment using geochemical composite signatures in a large and polluted river system with a semiarid-coastal interface, Brazil

International audienceThe Ipojuca River is the third most polluted fluvial system in Brazil. Sediment-associated metal fluxes threaten the environmental health in the estuary of this system. However, the sources supplying these particle-bound contaminants have not been determined yet. Sediment source fingerprinting provides a powerful technique to obtain such information. Accordingly, the aim of this study was to quantify the source contributions to suspended and bed sediments in this polluted river system with a semiarid-coastal interface using geochemical tracers. A total of 20 geochemical tracers measured on 207 source samples were used as potential fingerprint properties to discriminate and quantify the contributions of potential sources classified according to three distinct typologies (distribution of land uses, soil classes, and the environmental contrasts between the upper and lower catchment). All analyzed elements passed the range test for conservative behaviour. Using the MixSIAR model, the lower catchment, Oxisols, and sugarcane croplands were identified as the dominant sediment sources. These new data provide a basis to target the management of excessive sediment loads and sediment-associated contaminants moving towards estuarine and coastal environments. The multiple sources framework discussed herein can also help to improve the appeal of sediment source fingerprinting among environmental policymakers given the capacity for informing targeted management

Applying geochemical and colour properties to quantify sediment sources in a Brazilian semiarid ephemeral river system

International audienceThe Brazilian semiarid is the most densely populated dry region in the world. Although climate change projections underline the need for the creation of integrated strategies to protect water resources in the semiarid, sediment source apportionment data remain scant for this environment. Accordingly, we evaluated sediment source contributions in one of the most relevant Brazilian semiarid catchments by combining geochemical and colour tracer properties. In doing so, we explored the applicability of colour tracers as a low-cost alternative to the use of time-consuming and costly properties, such as geochemical tracers. Two source classification schemes were used based on environmentally contrasting regions within the catchment (upper, middle and lower catchment parts) and land use (Caatinga biome-natural vegetation, unpaved roads, and channel banks). Suspended sediments (SS) and bed sediments (BS) were used as target sediment. A total of 660 individual source material samples were collected and composited. Geochemical and colour tracers were measured on the source and target sediment samples and used as potential fingerprints to discriminate and quantify the sediment source contributions. The geochemical tracers provided weak source discrimination based on land use. However, combining geochemical and colour tracers improved the final outputs. Using the MixSIAR model, the lower catchment contributed more sediment than the other regional sources. The Caatinga (SS = 49%; BS = 47%) contributed more sediment than channel banks (SS = 35%; BS = 39%). Overall, our results suggest that the recovery and conservation of the Caatinga vegetation and the stabilization of channel banks, especially in the lower catchment part, are critical for improving sediment supply control in the semiarid study basin. More studies are needed to evaluate the conservative behaviour of colour tracers in ephemeral rivers

Quality reference values for rare earth elements in soils from one of the last agricultural frontiers in Brazil

Environmental impacts caused by the addition of rare earth elements (REEs) to agricultural soils are a growing concern. The sedimentary basin of the Gurguéia River is located in one of the last agricultural frontiers in Brazil; nevertheless, data regarding quality reference values (QRVs) for REEs in soils are still scarce. The objective of this study was therefore to determine the natural concentration and establish the QRVs of REEs in soils of Gurguéia watershed, Brazil. Fifty-five composite soil samples were collected at sites under no or minimal anthropic interference. The average REE natural concentrations in soils from the Gurguéia watershed were lower than those found in other regions of Brazil and worldwide, following the order (mg kg–1): Ce (14.01) > Nd (6.19) > La (5.52) > Pr (2.51) > Sm (1.45) > Gd (0.93) > Dy (0.63) > Er (0.42) > Yb (0.39) > Tb (0.28) > Eu (0.26) > Lu (0.20). The parent material was the main factor that controlled the distribution of REEs in soils. The QRVs in soils followed the order (mg kg–1): Ce (18.8) > Nd (7.92) > La (6.32) > Pr (3.3) > Sm (1.97) > Gd (1.35) > Dy (0.85) > Er (0.55) > Yb (0.47) > Tb (0.37) > Lu (0.25). These values serve as a basis to assist the development of legislation, including REE thresholds for Brazilian soils