Superprotonic phase transition of CsHSO4: A molecular dynamics simulation study

The superprotonic phase transition (phase II --> phase I; 414 K) of cesium hydrogen sulfate, CsHSO4, was simulated using molecular dynamics with the "first principles" MSXX force field (FF). The structure, binding energy, and vibrational frequencies of the CsHSO4 monomer, the binding energy of the (H2SO4)2 dimer, and the torsion barrier of the HSO4- ion were determined from quantum mechanical calculations, and the parameters of the Dreiding FF for Cs, S, O, and H adjusted to reproduce these quantities. Each hydrogen atom was treated as bonded exclusively to a single oxygen atom (proton donor), but allowed to form hydrogen bonds to various second nearest oxygen atoms (proton acceptors). Fixed temperature-pressure (NPT) dynamics were employed to study the structure as a function of temperature from 298 to 723 K. In addition, the influence of several force field parameters, including the hydrogen torsional barrier height, hydrogen bond strength, and oxygen charge distribution, on the structural behavior of CsHSO4 was probed. Although the FF does not allow proton migration (i.e., proton jumps) between oxygen atoms, a clear phase transition occurred as demonstrated by a discrete change of unit cell symmetry (monoclinic to tetragonal), cell volume, and molar enthalpy. The dynamics of the HSO4- group reorientational motion also changed dramatically at the transition. The observation of a transition to the expected tetragonal phase using a FF in which protons cannot migrate indicates that proton diffusion does not drive the transition to the superprotonic phase. Rather, high conductivity is a consequence of the rapid reorientations that occur in the high temperature phase. Furthermore, because no input from the superprotonic phase was employed in these simulations, it may be possible to employ MD to hypothesize superprotonic materials

Schwinger-Boson Mean-Field Theory of Mixed-Spin Antiferromagnet L2BaNiO5L_2BaNiO_5

The Schwinger-boson mean-field theory is used to study the three-dimensional antiferromagnetic ordering and excitations in compounds $L_2BaNiO_5$, a large family of quasi-one-dimensional mixed-spin antiferromagnet. To investigate magnetic properties of these compounds, we introduce a three-dimensional mixed-spin antiferromagnetic Heisenberg model based on experimental results for the crystal structure of $L_2BaNiO_5$. This model can explain the experimental discovery of coexistence of Haldane gap and antiferromagnetic long-range order below N\'{e}el temperature. Properties such as the low-lying excitations, magnetizations of $Ni$ and rare-earth ions, N\'{e}el temperatures of different compounds, and the behavior of Haldane gap below the N\'{e}el temperature are investigated within this model, and the results are in good agreement with neutron scattering experiments.Comment: 12 pages, 6 figure

Seyfert's Sextet: A Slowly Dissolving Stephan's Quintet?

We present a multiwavelength study of the highly evolved compact galaxy group known as Seyfert's Sextet (HCG79: SS). We interpret SS as a 2-3 Gyr more evolved analog of Stephan's Quintet (HCG92: SQ). We postulate that SS formed by sequential acquisition of 4-5 primarily late-type field galaxies. Four of the five galaxies show an early-type morphology which is likely the result of secular evolution driven by gas stripping. Stellar stripping has produced a massive/luminous halo and embedded galaxies that are overluminous for their size. These are interpreted as remnant bulges of the accreted spirals. H79d could be interpreted as the most recent intruder being the only galaxy with an intact ISM and uncertain evidence for tidal perturbation. In addition to stripping activity we find evidence for past accretion events. H79b (NGC6027) shows a strong counter-rotating emission line component interpreted as an accreted dwarf spiral. H79a shows evidence for an infalling component of gas representing feedback or possible cross fueling by H79d. The biggest challenge to this scenario involves the low gas fraction in the group. If SS formed from normal field spirals then much of the gas is missing. Finally, despite its advanced stage of evolution, we find no evidence for major mergers and infer that SS (and SQ) are telling us that such groups coalesce via slow dissolution.Comment: 70 pages, 19 figures, 15 tables - accepted for publication in the Astronomical Journa

Radio Supernova SN 1998bw and Its Relation to GRB 980425

SN 1998bw is an unusual Type Ic supernova that may be associated with the $\gamma$-ray burst GRB 980425. We use a synchrotron self-absorption model for its radio emission to deduce that the synchrotron-emitting gas is expanding into a circumstellar medium of approximately $r^{-2}$ density profile, at a speed comparable to the speed of light. We assume that the efficiencies of production of relativistic electrons and magnetic field are constant through the evolution. The circumstellar density is consistent with that expected around the massive star core thought to be the progenitor of SN 1998bw. The explosion energy in material moving with velocity $>0.5c$ is $\sim 10^{49}- 3\times 10^{50}$ ergs, with some preference for the high values. The rise in the radio light curves observed at days 20-40 is inferred to be the result of a rise in the energy of the blast wave by a factor $\sim 2.5$. Interaction with a jump in the ambient density is not consistent with the observed evolution. We infer that the boost in energy is from a shell of matter from the explosion that catches up with the decelerating shock front. Both the high explosion energy and the nature of the energy input to the blast wave are difficult to reconcile with energy input from the shock-accelerated high velocity ejecta from a supernova. The implication is that there is irregular energy input from a central engine, which is the type of model invoked for normal $\gamma$-ray bursts. The link between SN 1998bw and GRB 980425 is thus strengthened.Comment: 21 pages, 9 figures, revised version to appear in Ap

Angle-dependence of the Hall effect in HgBa2CaCu2O6 thin films

Superconducting compounds of the family Hg-Ba-Ca-Cu-O have been the subject of intense study since the current record-holder for the highest critical temperature of a superconductor belongs to this class of materials. Thin films of the compound with two adjacent copper-oxide layers and a critical temperature of about 120 K were prepared by a two-step process that consists of the pulsed-laser deposition of precursor films and the subsequent annealing in mercury-vapor atmosphere. Like some other high-temperature superconductors, Hg-Ba-Ca-Cu-O exhibits a specific anomaly of the Hall effect, a double-sign change of the Hall coefficient close to the superconducting transition. We have investigated this phenomenon by measurements of the Hall effect at different angles between the magnetic field direction and the crystallographic c-axis. The results concerning the upper part of the transition, where the first sign change occurs, are discussed in terms of the renormalized fluctuation model for the Hall conductivity, adapted through the field rescaling procedure in order to take into account the arbitrary orientation of the magnetic field.Comment: to be published in Phys. Rev.

Efek Pemberian Ekstrak Etanol Akar Kolesom (Talinum Triangulare Willd) Terhadap Spermatogenesis Tikus Putih

In Indonesia infertility is still a problem for married couples, because 10-15% of married couples suffer from infertility. Infertility can be caused by the husband and wife, but in reality 40-60% are caused by the husband. Data infertility based on analysis of cement, which is one important way to determine the level of male fertility. Cement circumstances that can cause infertility, among others, the less the number of spermatozoa, sperm motility is low, the velocity of spermatozoa and so on. Kolesom (Talinum triangulare Willd) can increase the number and motility of spermatozoa and to increase testosterone levels. The study aims to determine the effect of kolesom root extract on spermatogenesis of male Wistar rats. The effect of kolesom root extract on spermatogenesis using the WHO (2000) with animal white mouse. 225 doses of ethanol extract; 675 and 2025 mg / kg. administered orally for 45 days. Distilled water as a control and comparative dosage Korean Ginseng 225 mg / kg. The results of the study, kolesom extract doses 225; 675 and 2025 mg / kg BB given for 45 days did not lose reproductive organ testis and epididymis can still increase the number of A spermatogonia, pachytene stage primary spermatocytes and the diameter of seminiferous

Inversion formula and Parsval theorem for complex continuous wavelet transforms studied by entangled state representation

In a preceding Letter (Opt. Lett. 32, 554 (2007)) we have proposed complex continuous wavelet transforms (CCWTs) and found Laguerre--Gaussian mother wavelets family. In this work we present the inversion formula and Parsval theorem for CCWT by virtue of the entangled state representation, which makes the CCWT theory complete. A new orthogonal property of mother wavelet in parameter space is revealed.Comment: 4 pages no figur

Early Science with the Large Millimetre Telescope: Molecules in the Extreme Outflow of a proto-Planetary Nebula

Extremely high velocity emission likely related to jets is known to occur in some proto-Planetary Nebulae. However, the molecular complexity of this kinematic component is largely unknown. We observed the known extreme outflow from the proto-Planetary Nebula IRAS 16342-3814, a prototype water fountain, in the full frequency range from 73 to 111 GHz with the RSR receiver on the Large Millimetre Telescope. We detected the molecules SiO, HCN, SO, and $^{13}$CO. All molecular transitions, with the exception of the latter are detected for the first time in this source, and all present emission with velocities up to a few hundred km s$^{-1}$. IRAS 16342-3814 is therefore the only source of this kind presenting extreme outflow activity simultaneously in all these molecules, with SO and SiO emission showing the highest velocities found of these species in proto-Planetary Nebulae. To be confirmed is a tentative weak SO component with a FWHM $\sim$ 700 km s$^{-1}$. The extreme outflow gas consists of dense gas (n$_{\rm H_2} >$ 10$^{4.8}$--10$^{5.7}$ cm$^{-3}$), with a mass larger than $\sim$ 0.02--0.15 M$_{\odot}$. The relatively high abundances of SiO and SO may be an indication of an oxygen-rich extreme high velocity gas.Comment: Accepted for publication in Monthly Notices of the Royal Astronomical Society Letter

Early Science with the Large Millimeter Telescope: an energy-driven wind revealed by massive molecular and fast X-ray outflows in the Seyfert Galaxy IRAS 17020+4544

We report on the coexistence of powerful gas outflows observed in millimeter and X-ray data of the Radio-Loud Narrow Line Seyfert 1 Galaxy IRAS 17020+4544. Thanks to the large collecting power of the Large Millimeter Telescope, a prominent line arising from the 12CO(1-0) transition was revealed in recent observations of this source. The complex profile is composed by a narrow double-peak line and a broad wing. While the double-peak structure may be arising in a disk of molecular material, the broad wing is interpreted as the signature of a massive outflow of molecular gas with an approximate bulk velocity of -660 km/s. This molecular wind is likely associated to a multi-component X-ray Ultra-Fast Outflow with velocities reaching up to ~0.1c and column densities in the range 10^{21-23.9} cm^-2 that was reported in the source prior to the LMT observations. The momentum load estimated in the two gas phases indicates that within the observational uncertainties the outflow is consistent with being propagating through the galaxy and sweeping up the gas while conserving its energy. This scenario, which has been often postulated as a viable mechanism of how AGN feedback takes place, has so far been observed only in ULIRGs sources. IRAS 17020+4544 with bolometric and infrared luminosity respectively of 5X10^{44} erg/s and 1.05X10^{11} L_sun appears to be an example of AGN feedback in a NLSy1 Galaxy (a low power AGN). New proprietary multi-wavelength data recently obtained on this source will allow us to corroborate the proposed hypothesis.Comment: Accepted for publication on ApJ Letters, 9 pages, 4 figure