629 research outputs found
Extraction and Liquid-Membrane Preconcentration of Vincamine from Periwinkle (VincaMinor L.) Leaves. Process Modelling
An integrated process coupling solid-liquid extraction and liquid-membrane preconcentration of vincamine was studied. The effect of the ratios solid phase/extractant volume and extractant volume/liquid membrane volume on the mass transfer rate and
efficiency of vincamine removal were estimated. It was found that the transfer rate and removal efficiency of the alkaloid were higher with smaller quantities of solids and membrane volume. A mathematical description of the overall integrated process was proposed, and the values of the model parameters â mass transfer coefficients â were evaluated.
An agreement between the model-predicted results and the experimental data obtained was demonstrated. The four-phase integrated process provides simultaneously almost complete extraction and appreciable enrichment of the extracted product
Ferromagnetism and Lattice Distortions in the Perovskite YTiO
The thermodynamic properties of the ferromagnetic perovskite YTiO are
investigated by thermal expansion, magnetostriction, specific heat, and
magnetization measurements. The low-temperature spin-wave contribution to the
specific heat, as well as an Arrott plot of the magnetization in the vicinity
of the Curie temperature K, are consistent with a
three-dimensional Heisenberg model of ferromagnetism. However, a magnetic
contribution to the thermal expansion persists well above , which
contrasts with typical three-dimensional Heisenberg ferromagnets, as shown by a
comparison with the corresponding model system EuS. The pressure dependences of
and of the spontaneous moment are extracted using thermodynamic
relationships. They indicate that ferromagnetism is strengthened by uniaxial
pressures and is weakened by uniaxial
pressures and hydrostatic pressure.
Our results show that the distortion along the - and -axes is further
increased by the magnetic transition, confirming that ferromagnetism is favored
by a large GdFeO-type distortion. The c-axis results however do not fit
into this simple picture, which may be explained by an additional
magnetoelastic effect, possibly related to a Jahn-Teller distortion.Comment: 12 pages, 13 figure
Precision Measurement of 11Li moments: Influence of Halo Neutrons on the 9Li Core
The electric quadrupole moment and the magnetic moment of the 11Li halo
nucleus have been measured with more than an order of magnitude higher
precision than before, |Q| = 33.3(5)mb and mu=3.6712(3)mu_N, revealing a
8.8(1.5)% increase of the quadrupole moment relative to that of 9Li. This
result is compared to various models that aim at describing the halo
properties. In the shell model an increased quadrupole moment points to a
significant occupation of the 1d orbits, whereas in a simple halo picture this
can be explained by relating the quadrupole moments of the proton distribution
to the charge radii. Advanced models so far fail to reproduce simultaneously
the trends observed in the radii and quadrupole moments of the lithium
isotopes.Comment: 4 pages, 4 figures, 1 tabl
Dipole-active optical phonons in YTiO_3: ellipsometry study and lattice-dynamics calculations
The anisotropic complex dielectric response was accurately extracted from
spectroscopic ellipsometry measurements at phonon frequencies for the three
principal crystallographic directions of an orthorhombic (Pbnm) YTiO_3 single
crystal. We identify all twenty five infrared-active phonon modes allowed by
symmetry, 7B_1u, 9B_2u, and 9B_3u, polarized along the c-, b-, and a-axis,
respectively. From a classical dispersion analysis of the complex dielectric
functions \tilde\epsilon(\omega) and their inverses -1/\tilde\epsilon(\omega)
we define the resonant frequencies, widths, and oscillator strengths of the
transverse (TO) and longitudinal (LO) phonon modes. We calculate
eigenfrequencies and eigenvectors of B_1u, B_2u, and B_3u normal modes and
suggest assignments of the TO phonon modes observed in our ellipsometry spectra
by comparing their frequencies and oscillator strengths with those resulting
from the present lattice-dynamics study. Based on these assignments, we
estimate dynamical effective charges of the atoms in the YTiO_3 lattice. We
find that, in general, the dynamical effective charges in YTiO_3 lattice are
typical for a family of perovskite oxides. By contrast to a ferroelectric
BaTiO_3, the dynamical effective charge of oxygen related to a displacement
along the c-axis does not show the anomalously large value. At the same time,
the dynamical effective charges of Y and ab-plane oxygen exhibit anisotropy,
indicating strong hybridization along the a-axis.Comment: 8 pages, 7 figure
Extraction and Liquid-Membrane Preconcentration of Vincamine from Periwinkle (VincaMinor L.) Leaves. Process Modelling
An integrated process coupling solid-liquid extraction and liquid-membrane preconcentration of vincamine was studied. The effect of the ratios solid phase/extractant volume and extractant volume/liquid membrane volume on the mass transfer rate and
efficiency of vincamine removal were estimated. It was found that the transfer rate and removal efficiency of the alkaloid were higher with smaller quantities of solids and membrane volume. A mathematical description of the overall integrated process was proposed, and the values of the model parameters â mass transfer coefficients â were evaluated.
An agreement between the model-predicted results and the experimental data obtained was demonstrated. The four-phase integrated process provides simultaneously almost complete extraction and appreciable enrichment of the extracted product
Ground-State Electromagnetic Moments of Calcium Isotopes
High-resolution bunched-beam collinear laser spectroscopy was used to measure
the optical hyperfine spectra of the Ca isotopes. The ground state
magnetic moments of Ca and quadrupole moments of Ca were
measured for the first time, and the Ca ground state spin was
determined in a model-independent way. Our results provide a critical test of
modern nuclear theories based on shell-model calculations using
phenomenological as well as microscopic interactions. The results for the
neutron-rich isotopes are in excellent agreement with predictions using
interactions derived from chiral effective field theory including three-nucleon
forces, while lighter isotopes illustrate the presence of particle-hole
excitations of the Ca core in their ground state.Comment: Accepted as a Rapid Communication in Physical Review
Spins, Electromagnetic Moments, and Isomers of 107-129Cd
The neutron-rich isotopes of cadmium up to the N=82 shell closure have been
investigated by high-resolution laser spectroscopy. Deep-UV excitation at 214.5
nm and radioactive-beam bunching provided the required experimental
sensitivity. Long-lived isomers are observed in 127Cd and 129Cd for the first
time. One essential feature of the spherical shell model is unambiguously
confirmed by a linear increase of the 11/2- quadrupole moments. Remarkably,
this mechanism is found to act well beyond the h11/2 shell
Single-objective high-resolution confocal light sheet fluorescence microscopy for standard biological sample geometries
Three-dimensional fluorescence-based imaging of living cells and organisms requires the sample to be exposed to substantial excitation illumination energy, typically causing phototoxicity and photobleaching. Light sheet fluorescence microscopy dramatically reduces phototoxicity, yet most implementations are limited to objective lenses with low numerical aperture and particular sample geometries that are built for specific biological systems. To overcome these limitations, we developed a single-objective light sheet fluorescence system for biological imaging based on axial plane optical microscopy and digital confocal slit detection, using either Bessel or Gaussian beam shapes. Compared to spinning disk confocal microscopy, this system displays similar optical resolution, but a significantly reduced photobleaching at the same signal level. This single-objective light sheet technique is built as an add-on module for standard research microscopes and the technique is compatible with high-numerical aperture oil immersion objectives and standard samples mounted on coverslips. We demonstrate the performance of this technique by imaging three-dimensional dynamic processes, including bacterial biofilm dispersal, the response of biofilms to osmotic shocks, and macrophage phagocytosis of bacterial cells
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