Investigation of GdBaCo2-xFexO6-δ (x = 0, 0.2) - Ce0.8Sm0.2O2 composite cathodes for intermediate temperature solid oxide fuel cells

The double perovskites GdBaCo2-xFexO 6-δ (x = 0, 0.2) and composites (100 - y) GdBaCo 2-xFexO6-δ (x = 0, 0.2) - y Ce 0.8Sm0.2O2 (y = 10-50 wt.%) were investigated as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFCs). Chemical compatibility of GdBaCo2-xFexO 6-δ (x = 0, 0.2) with solid electrolyte Ce0.8Sm 0.2O2, thermal expansion, DC conductivity and electrochemical performance of (100 - y) GdBaCo2-xFe xO6-δ (x = 0, 0.2) - y Ce0.8Sm 0.2O2 (y = 10-50 wt.%) were studied. Partial substitution of Fe for Co was shown to lead to decrease of double perovskite GdBaCo 2-xFexO6-δ reactivity with the solid electrolyte Ce0.8Sm0.2O2. Polarization resistance of cathodes studied was found to depend significantly on firing temperature. Variation of solid electrolyte content in (100 - y) GdBaCo 2-xFexO6-δ (x = 0, 0.2) - y Ce 0.8Sm0.2O2 (y = 10-50 wt.%) composites was shown to allow to optimize their electrochemical performance. Cathode materials of 80 wt.% GdBaCo2O6-δ - 20 wt.% Ce 0.8Sm0.2O2 and 65 wt.% GdBaCo 1.8Fe0.2O6-δ - 35 wt.% Ce 0.8Sm0.2O2 were found to have the lowest polarization resistances and reasonable values of thermal expansion coefficient (TEC) and, therefore, can be considered as promising cathode materials for IT-SOFCs. © 2013 Elsevier B.V. All rights reserved

The Reddening-Free Decline Rate Versus Luminosity Relationship for Type Ia Supernovae

We develop a method for estimating the host galaxy dust extinction for type Ia supernovae based on an observational coincidence first noted by Lira (1995), who found that the B-V evolution during the period from 30-90 days after V maximum is remarkably similar for all events, regardless of light curve shape. This fact is used to calibrate the dependence of the B(max)-V(max) and V(max)-I(max) colors on the light curve decline rate parameter delta-m15, which can, in turn, be used to separately estimate the host galaxy extinction. Using these methods to eliminate the effects of reddening, we reexamine the functional form of the decline rate versus luminosity relationship and provide an updated estimate of the Hubble constant of Ho = 63.3 +- 2.2(internal) +- 3.5(external) km/s/Mpc.Comment: 32 pages, 10 figures, AJ 1999 in pres

SiFTO: An Empirical Method for Fitting SNe Ia Light Curves

We present SiFTO, a new empirical method for modeling type Ia supernovae (SNe Ia) light curves by manipulating a spectral template. We make use of high-redshift SN observations when training the model, allowing us to extend it bluer than rest frame U. This increases the utility of our high-redshift SN observations by allowing us to use more of the available data. We find that when the shape of the light curve is described using a stretch prescription, applying the same stretch at all wavelengths is not an adequate description. SiFTO therefore uses a generalization of stretch which applies different stretch factors as a function of both the wavelength of the observed filter and the stretch in the rest-frame B band. We compare SiFTO to other published light-curve models by applying them to the same set of SN photometry, and demonstrate that SiFTO and SALT2 perform better than the alternatives when judged by the scatter around the best fit luminosity distance relationship. We further demonstrate that when SiFTO and SALT2 are trained on the same data set the cosmological results agree.Comment: Modified to better match published version in Ap

Transverse optical plasmons in layered superconductors

We discuss the possible existance of transverse optical plasma modes in superlattices consisting of Josephson coupled superconducting layers. These modes appear as resonances in the current-current correlation function, as opposed to the usual plasmons which are poles in the density-density channel. We consider both bilayer superlattices, and single layer lattices with a spread of interlayer Josephson couplings. We show that our model is in quantitative agreement with the recent experimental observation by a number of groups of a peak at the Josephson plasma frequency in the optical conductivity of La$_{1.85}$Sr$_{0.15}$CuO$_4$Comment: Proceedings of LT21, in press, 4 pages, Latex with LTpaper.sty and epsfig.sty, 2 postscript figure

SN 2003du: 480 days in the life of a normal type Ia supernova

Peer reviewe

Observation of out-of-phase bilayer plasmons in YBa_2Cu_3O_7-delta

The temperature dependence of the c-axis optical conductivity \sigma(\omega) of optimally and overdoped YBa_2Cu_3O_x (x=6.93 and 7) is reported in the far- (FIR) and mid-infrared (MIR) range. Below T_c we observe a transfer of spectral weight from the FIR not only to the condensate at \omega = 0, but also to a new peak in the MIR. This peak is naturally explained as a transverse out-of-phase bilayer plasmon by a model for \sigma(\omega) which takes the layered crystal structure into account. With decreasing doping the plasmon shifts to lower frequencies and can be identified with the surprising and so far not understood FIR feature reported in underdoped bilayer cuprates.Comment: 7 pages, 3 eps figures, Revtex, epsfi

Observation of the Transverse Optical Plasmon in SmLa0.8Sr0.2CuO4-d

We present microwave and infrared measurements on SmLa0.8Sr0.2CuO4-d, which are direct evidence for the existence of a transverse optical plasma mode, observed as a peak in the c-axis optical conductivity. This mode appears as a consequence of the existence of two different intrinsic Josephson couplings between the CuO2 layers, one with a Sm2O2 block layer, and the other one with a (La,Sr)O block layer. From the frequencies and the intensities of the collective modes we determine the value of the compressibility of the two dimensional electron fluid in the copper oxygen planes.Comment: REVTeX, 4 pages, 5 eps-figures, PRL, in pres

Luminescent properties of Bi-doped polycrystalline KAlCl4

We observed an intensive near-infrared luminescence in Bi-doped KAlCl4 polycrystalline material. Luminescence dependence on the excitation wavelength and temperature of the sample was studied. Our experimental results allow asserting that the luminescence peaked near 1 um belongs solely to Bi+ ion which isomorphically substitutes potassium in the crystal. It was also demonstrated that Bi+ luminescence features strongly depend on the local ion surroundings

Kinetic Energy, Condensation Energy, Optical Sum Rule and Pairing Mechanism in High-Tc Cuprates

The mechanism of high-Tc superconductivity is investigated with interests on the microscopic aspects of the condensation energy. The theoretical analysis is performed on the basis of the FLEX approximation which is a microscopic description of the spin-fluctuation-induced-superconductivity. Most of phase transitions in strongly correlated electron system arise from the correlation energy which is copmetitive to the kinetic energy. However, we show that the kinetic energy cooperatively induces the superconductivity in the underdoped region. This unusual decrease of kinetic energy below T_c is induced by the feedback effect. The feedback effect induces the magnetic resonance mode as well as the kink in the electronic dispersion, and alters the properties of quasi-particles, such as mass renormalization and lifetime. The crossover from BCS behavior to this unusual behavior occurs for hole dopings. On the other hand, the decrease of kinetic energy below T_c does not occur in the electron-doped region. We discuss the relation to the recent obserbation of the violation of optical sum rule

The Environments of Supernovae in Post-Refurbishment Hubble Space Telescope Images

The locations of supernovae in the local stellar and gaseous environment in galaxies contain important clues to their progenitor stars. Access to this information, however, has been hampered by the limited resolution achieved by ground-based observations. High spatial resolution Hubble Space Telescope (HST) images of galaxy fields in which supernovae had been observed can improve the situation considerably. We have examined the immediate environments of a few dozen supernovae using archival post-refurbishment HST images. Although our analysis is limited due to signal-to-noise ratio and filter bandpass considerations, the images allow us for the first time to resolve individual stars in, and to derive detailed color-magnitude diagrams for, several environments. We are able to place more rigorous constraints on the masses of these supernovae. A search was made for late-time emission from supernovae in the archival images, and for the progenitor stars in presupernova images of the host galaxies. We have detected SN 1986J in NGC 891 and, possibly, SN 1981K in NGC 4258. We have also identified the progenitor of the Type IIn SN 1997bs in NGC 3627. By removing younger resolved stars in the environments of SNe Ia, we can measure the colors of the unresolved stellar background and attribute these colors generally to an older, redder population. HST images ``accidentally'' caught the Type Ia SN 1994D in NGC 4526 shortly after its outburst; we measure its brightness. Finally, we add to the statistical inferences that can be made from studying the association of SNe with recent star-forming regions.Comment: 20 pages, 29 figures, to appear in A