1,584 research outputs found

    Template synthesis of a poly ionic liquid derived Fe1 xS nitrogen doped porous carbon membrane and its electrode application in lithium sulfur batteries

    Get PDF
    This study deals with the facile synthesis of Fe1 xS nanoparticle containing nitrogen doped porous carbon membranes denoted as Fe1 xS N PCMs via vacuum carbonization of hybrid porous poly ionic liquid PIL membranes, and their successful use as a sulfur host material to mitigate the shuttle effect in lithium sulfur Li S batteries. The hybrid porous PIL membranes as the sacrificial template were prepared via ionic crosslinking of a cationic PIL with base neutralized 1,10 ferrocenedicarboxylic acid, so that the iron source was molecularly incorporated into the template. The carbonization process was investigated in detail at different temperatures, and the chemical and porous structures of the carbon products were comprehensively analyzed. The Fe1xS N PCMs prepared at 900 1C have a multimodal pore size distribution with a satisfactorily high surface area and well dispersed iron sulfide nanoparticles to physically and chemically confine the LiPSs. The sulfur Fe1xS N PCM composites were then tested as electrodes in Li S batteries, showing much improved capacity, rate performance and cycle stability, in comparison to iron sulfide free, nitrogen doped porous carbon membrane

    Delta rho pi interaction leading to N* and Delta* resonances

    Full text link
    We have performed a calculation for the three body Δρπ\Delta \rho \pi system by using the fixed center approximation to Faddeev equations, taking the interaction between Δ\Delta and ρ\rho, Δ\Delta andπ\pi, and ρ\rho and π\pi from the chiral unitary approach. We find several peaks in the modulus squared of the three-body scattering amplitude, indicating the existence of resonances, which can be associated to known I=1/2,3/2I=1/2, 3/2 and JP=1/2+,3/2+J^P=1/2^+, 3/2^+ and 5/2+5/2^+ baryon states.Comment: Presented at the 21st European Conference on Few-Body Problems in Physics, Salamanca, Spain, 30 August - 3 September 201

    Random field sampling for a simplified model of melt-blowing considering turbulent velocity fluctuations

    Full text link
    In melt-blowing very thin liquid fiber jets are spun due to high-velocity air streams. In literature there is a clear, unsolved discrepancy between the measured and computed jet attenuation. In this paper we will verify numerically that the turbulent velocity fluctuations causing a random aerodynamic drag on the fiber jets -- that has been neglected so far -- are the crucial effect to close this gap. For this purpose, we model the velocity fluctuations as vector Gaussian random fields on top of a k-epsilon turbulence description and develop an efficient sampling procedure. Taking advantage of the special covariance structure the effort of the sampling is linear in the discretization and makes the realization possible

    Fractional Quantum Hall States of Clustered Composite Fermions

    Full text link
    The energy spectra and wavefunctions of up to 14 interacting quasielectrons (QE's) in the Laughlin nu=1/3 fractional quantum Hall (FQH) state are investigated using exact numerical diagonalization. It is shown that at sufficiently high density the QE's form pairs or larger clusters. This behavior, opposite to Laughlin correlations, invalidates the (sometimes invoked) reapplication of the composite fermion picture to the individual QE's. The series of finite-size incompressible ground states are identified at the QE filling factors nu_QE=1/2, 1/3, 2/3, corresponding to the electron fillings nu=3/8, 4/11, 5/13. The equivalent quasihole (QH) states occur at nu_QH=1/4, 1/5, 2/7, corresponding to nu=3/10, 4/13, 5/17. All these six novel FQH states were recently discovered experimentally. Detailed analysis indicates that QE or QH correlations in these states are different from those of well-known FQH electron states (e.g., Laughlin or Moore-Read states), leaving the origin of their incompressibility uncertain. Halperin's idea of Laughlin states of QP pairs is also explored, but is does not seem adequate.Comment: 14 pages, 9 figures; revision: 1 new figure, some new references, some new data, title chang

    The number of eigenstates: counting function and heat kernel

    Full text link
    The main aim of this paper is twofold: (1) revealing a relation between the counting function N(lambda) (the number of the eigenstates with eigenvalue smaller than a given number) and the heat kernel K(t), which is still an open problem in mathematics, and (2) introducing an approach for the calculation of N(lambda), for there is no effective method for calculating N(lambda) beyond leading order. We suggest a new expression of N(lambda) which is more suitable for practical calculations. A renormalization procedure is constructed for removing the divergences which appear when obtaining N(lambda) from a nonuniformly convergent expansion of K(t). We calculate N(lambda) for D-dimensional boxes, three-dimensional balls, and two-dimensional multiply-connected irregular regions. By the Gauss-Bonnet theorem, we generalize the simply-connected heat kernel to the multiply-connected case; this result proves Kac's conjecture on the two-dimensional multiply-connected heat kernel. The approaches for calculating eigenvalue spectra and state densities from N(lambda) are introduced.Comment: 17 pages, 1 figure. v2: Equivalent forms of Eqs. (4.8) and (9.2) are adde

    Event Reconstruction in the PHENIX Central Arm Spectrometers

    Full text link
    The central arm spectrometers for the PHENIX experiment at the Relativistic Heavy Ion Collider have been designed for the optimization of particle identification in relativistic heavy ion collisions. The spectrometers present a challenging environment for event reconstruction due to a very high track multiplicity in a complicated, focusing, magnetic field. In order to meet this challenge, nine distinct detector types are integrated for charged particle tracking, momentum reconstruction, and particle identification. The techniques which have been developed for the task of event reconstruction are described.Comment: Accepted for publication in Nucl. Instrum. A. 34 pages, 23 figure

    Equation of state and phonon frequency calculations of diamond at high pressures

    Full text link
    The pressure-volume relationship and the zone-center optical phonon frequency of cubic diamond at pressures up to 600 GPa have been calculated based on Density Functional Theory within the Local Density Approximation and the Generalized Gradient Approximation. Three different approaches, viz. a pseudopotential method applied in the basis of plane waves, an all-electron method relying on Augmented Plane Waves plus Local Orbitals, and an intermediate approach implemented in the basis of Projector Augmented Waves have been used. All these methods and approximations yield consistent results for the pressure derivative of the bulk modulus and the volume dependence of the mode Grueneisen parameter of diamond. The results are at variance with recent precise measurements up to 140 GPa. Possible implications for the experimental pressure determination based on the ruby luminescence method are discussed.Comment: 10 pages, 6 figure
    corecore