Optimization of terrestrial ecosystem model parameters using atmospheric CO2 concentration data with the Global Carbon Assimilation System (GCAS)

Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 122 (2017): 3218–3237, doi:10.1002/2016JG003716.The Global Carbon Assimilation System that assimilates ground-based atmospheric CO2 data is used to estimate several key parameters in a terrestrial ecosystem model for the purpose of improving carbon cycle simulation. The optimized parameters are the leaf maximum carboxylation rate at 25°C (V25 max), the temperature sensitivity of ecosystem respiration (Q10), and the soil carbon pool size. The optimization is performed at the global scale at 1° resolution for the period from 2002 to 2008. The results indicate that vegetation from tropical zones has lower V25 max values than vegetation in temperate regions. Relatively high values of Q10 are derived over high/midlatitude regions. Both V25 max and Q10 exhibit pronounced seasonal variations at middle-high latitudes. The maxima in V25 max occur during growing seasons, while the minima appear during nongrowing seasons. Q10 values decrease with increasing temperature. The seasonal variabilities of V25 max and Q10 are larger at higher latitudes. Optimized V25 max and Q10 show little seasonal variabilities at tropical regions. The seasonal variabilities of V25 max are consistent with the variabilities of LAI for evergreen conifers and broadleaf evergreen forests. Variations in leaf nitrogen and leaf chlorophyll contents may partly explain the variations in V25 max. The spatial distribution of the total soil carbon pool size after optimization is compared favorably with the gridded Global Soil Data Set for Earth System. The results also suggest that atmospheric CO2 data are a source of information that can be tapped to gain spatially and temporally meaningful information for key ecosystem parameters that are representative at the regional and global scales.National Key R&D Program of China Grant Number: 2016YFA0600204; National Natural Science Foundation of China Grant Number: 415713382018-06-2

Influence of Different Carboxylic Acid Ligands on Luminescent Properties of Eu(Lc) 3

A series of rare earth europium complexes with different carboxylic acid ligands Eu(Lc)3phen (Lc = MAA, AA, BA, SA) were synthesized. The complexes were characterized by FTIR, TG-DSC, XRD, UV absorption spectra, and photoluminescence spectra (PL) to study the structure, thermal stability, the energy absorption, and luminescent properties of the complexes. The results showed that the series complexes are all with good crystallization and relatively high thermal stability. The differences of the luminescent properties of complexes are caused by the different ligand structures. The absorption intensity of the carboxylic acid ligands, BA, was the strongest, followed by the MAA and AA and SA was the weakest. Therefore, the fluorescence intensity of the Eu(BA)3phen was the strongest, followed by the Eu(MAA)3phen and Eu(AA)3phen and the Eu2(SA)3phen2 was the weakest. All complexes showed good luminescence properties

Prediction of Ventilation Effects on Reducing Moisture Damage in Tishun Tang in the Palace Museum in Beijing, China

The Palace Museum in Beijing is World Cultural Heritage and representative of Chinese traditional brick buildings, but has been suffering deterioration for centuries. Environment monitoring showed that the special construction of foundation resulted in the humid micro-environment and moisture damage near wall bottom and floor in buildings. In order to make clear the effects of ventilation on reducing moisture damage, we took Tishun Tang as example and built a two-dimensional hygrothermal simulation model. There are two ventilation plans. One is direct ventilation, letting the outdoor air go into indoor space directly through the flue under floor. The other is to add air temperature and humidity control during that produce, called controlled ventilation. In those two plans, ventilation rate is raised to 1 time per hour from 0.4 times (current state). The results show that compared with direct ventilation, controlled ventilation is more efficient for reducing moisture damage. In controlled ventilation plan, heating outdoor air before the air exchange in winter benefits to raising indoor surface temperature by one degree and reducing area of freezing-thawing damage. Dehumidifying the outdoor air during ventilation in summer is the most important point of decreasing the high mould risk from 22 ~ 25 days to 7 ~ 10 days

Rust Conversion of Proanthocyanidins to Archaeological Steel: A Case Study of Lingzhao Xuan in the Forbidden City

This work was focused on the rust conversion of proanthocyanidins (PC) for goethite (α-FeOOH), akaganeite (β-FeOOH) and lepidocrocite (γ-FeOOH), trying to show the potential of PC as an eco-friendly corrosion inhibitor and rust converter for archaeological steel conservation. The experiment used a rusted steel screw from Lingzhao Xuan of the Forbidden City in the Qing Dynasty and three kinds of pure iron oxyhydroxides as research samples. By means of micro-Raman, FTIR, XRD, XPS, SEM and EIS, PC had the ability to chemically react with iron oxyhydroxides in the rust, forming amorphous PC-FeOOH with a marked signal about 1384 cm−1 as phenolic-Fe in infrared properties. The original relatively stable iron oxides were not induced to phase transformation and still remained. The converted rust layer could be more stable in the corrosive medium and increased the corrosion potential more effectively. Both the rust layer resistance and the charge transfer resistance of the archaeological samples were improved by at least 3 times with 5.0 g/L of PC, which could reasonably stabilize the archaeological rust and hindered external corrosive penetration into the core. It was a mild protection material that showed satisfactory performance for archaeological steel cultural heritage and has a good application prospect

Water-related deterioration risk assessment for sustainable conservation of heritage buildings in the Forbidden City, China

A suitable hygrothermal environment is imperative for sustainably conserving movable and immovable cultural heritage. This paper proposes a combined method for quantitatively assessing water-related deterioration risks in heritage buildings, validated employing the Forbidden City in China, a UNESCO World Heritage site. The approach emphasizes combining hygrothermal coupled transfer simulation with conventional environmental monitoring for systematic risk assessments. Key findings include identifying predominant causes of year-round deteriorations of salt weathering, freeze–thaw damage, microorganism growth, and physical cracking. Secondly, it underscores the persistent dampness at the bottom, stemming from capillary rising in building foundations, rendering the present environment unsuitable for the conservation of single-story heritage buildings. Lastly, in the Forbidden City, significant deteriorations manifest just a few millimeters or centimeters beneath the surfaces of brick walls and floors. Suggested measures include reducing shallow groundwater and enhancing airtightness. This study establishes a scientific framework for deterioration risk assessment and sustainable cultural heritage conservation

Quantitative evaluation of deterioration in west wind-room in the Palace Museum

The Palace Museum in Beijing is a world cultural heritage site. Surviving nearly 600 years, heritage buildings in the Palace Museum have been deteriorated by salting out, exfoliation, cracking and so on. For the purpose of quantitative evaluation on current environment risks and proposing conservation approaches, heat and moisture transfer on buildings was simulated by a numerical model and the West Wind-room in the Hall of Mental Cultivation (Yangxin Dian) in the Palace Museum was taken as example. The results indicated that to reduce freezing-thawing cycles, the indoor temperature should be increased during December to early February. Indoor temperature and humidity should be controlled to a more stable and lower level to decrease the damaging from salt crystallization and hydration. And attention should be paid to more salting-out resulted by evaporation increase in spring and autumn. The results will provide support to environment control of Chinese traditional buildings

Comparative proteomics on deep-sea amphipods after in situ copper exposure

The interest in deep-sea mining increased along with the environmental concerns of these activities to the deep-sea fauna. The discovery of optimal biomarkers of deep-sea mining activities in deep-sea species is a crucial step toward the supply of important ecological information for environmental impact assessment. In this study, an in situ copper exposure experiment was performed on deep-sea scavenging amphipods. Abyssorchomene distinctus individuals were selected among all the exposed amphipods for molecular characterization. Copper concentration within the gut was assessed, followed by a tandem mass tag-based coupled with two-dimensional liquid chromatography-mass spectrometry/mass spectrometry (LC-MS/MS) applied to identify and quantify the protein expression changes after 48 h of exposure. 2937 proteins were identified and annotated, and 1918 proteins among all identified proteins were assigned by at least two nonambiguous peptides. The screening process was performed based on the differences in protein abundance and the specific correlation between the proteins and copper in previous studies. These differentially produced proteins include Na+/K+ ATPase, cuticle, chitinase, and proteins with unknown function. Their abundances showed correlation with copper and had high sensitivity to indicate the copper level, being here proposed as biomarker candidates for deep-sea mining activities in the future. This is a key step in the development of environmental impact assessment of deep-sea mining activities integrating ecotoxicological data.Funding Agency National Key Research Program of China 2016YFC0304105 China Ocean Mineral Resources R&D Association Program DY135-E2-1-03 Hong Kong Branch of South Marine Science and Engineering Guangdong Laboratory Fundacao para a Ciancia e Tecnologia I.P. Portugal (FCT) Direcao-Geral de Politica do Mar (DGPM) through the project Mining-MiningImpact 2 (JPI Oceans) 2/2017/001 Portuguese Foundation for Science and Technology CEECIND005262017info:eu-repo/semantics/publishedVersio

A small climate-amplifying effect of climate-carbon cycle feedback

International audienceAbstract The climate-carbon cycle feedback is one of the most important climate-amplifying feedbacks of the Earth system, and is quantified as a function of carbon-concentration feedback parameter ( β ) and carbon-climate feedback parameter ( γ ). However, the global climate-amplifying effect from this feedback loop (determined by the gain factor, g ) has not been quantified from observations. Here we apply a Fourier analysis-based carbon cycle feedback framework to the reconstructed records from 1850 to 2017 and 1000 to 1850 to estimate β and γ . We show that the β -feedback varies by less than 10% with an average of 3.22 ± 0.32 GtC ppm −1 for 1880–2017, whereas the γ -feedback increases from −33 ± 14 GtC K −1 on a decadal scale to −122 ± 60 GtC K −1 on a centennial scale for 1000–1850. Feedback analysis further reveals that the current amplification effect from the carbon cycle feedback is small ( g is 0.01 ± 0.05), which is much lower than the estimates by the advanced Earth system models ( g is 0.09 ± 0.04 for the historical period and is 0.15 ± 0.08 for the RCP8.5 scenario), implying that the future allowable CO 2 emissions could be 9 ± 7% more. Therefore, our findings provide new insights about the strength of climate-carbon cycle feedback and about observational constraints on models for projecting future climate