Molecular imaging of banknote and questioned document using solvent-free gold nanoparticle-assisted laser desorption/ionization imaging mass spectrometry

Direct chemical analysis and molecular imaging of questioned documents in a non/minimal-destructive manner is important in forensic science. Here, we demonstrate that solvent-free gold-nanoparticle-assisted laser desorption/ionization mass spectrometry is a sensitive and minimal destructive method for direct detection and imaging of ink and visible and/or fluorescent dyes printed on banknotes or written on questioned documents. Argon ion sputtering of a gold foil allows homogeneous coating of a thin layer of gold nanoparticles on banknotes and checks in a dry state without delocalizing spatial distributions of the analytes. Upon N 2 laser irradiation of the gold nanoparticle-coated banknotes or checks, abundant ions are desorbed and detected. Recording the spatial distributions of the ions can reveal the molecular images of visible and fluorescent ink printed on banknotes and determine the printing order of different ink which may be useful in differentiating real banknotes from fakes. The method can also be applied to identify forged parts in questioned documents, such as number/writing alteration on a check, by tracing different writing patterns that come from different pens. © 2010 American Chemical Society.link_to_subscribed_fulltex

Tissue-spray ionization mass spectrometry for raw herb analysis

Tissue-spray ionization mass spectrometry is developed for the in situ chemical analysis of raw herbs under ambient conditions. We demonstrated that analyte molecules could be directly sprayed and ionized from solvent-wetted ginseng tissues upon the application of high electrical voltage to the tissue sample. Abundant phytochemicals/metabolites, including ginsenosides, amino acids and oligosaccharides, could be detected from ginseng tissues when the tissue-spray experiments were conducted in positive ion mode. Thermally labile and easily hydrolyzed malonyl-ginsenosides were also detected in negative ion mode. The tissue-spray ionization method enables the direct detection of analytes from raw herb samples and preserves the sample integrity for subsequent morphological and/or microscopic examination. In addition, this method is simple and fast for chemical profiling of wild-type and cultivatedtype American ginsengs with differentiation. Copyright © 2011 John Wiley & Sons, Ltd.link_to_subscribed_fulltex

Ketimido Metallophthalocyanines: An Approach to Phthalocyanine-Supported Mononuclear High-Valent Ruthenium Complexes

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Photosensitizer-free visible light-mediated gold-catalysed cis-difunctionalization of silyl-substituted alkynes

2017-2018 > Academic research: refereed > Publication in refereed journal201805 bcrcVersion of RecordPublishe

Measurements of charged current Lepton universality and vertical bar V-us vertical bar using Tau Lepton decays to e(-)(nu)over-bar(e)nu(tau), mu(-)(nu)over-bar(mu)nu(tau), pi(-)nu(tau), and K-nu(tau)

Using 467 fb(-1) of e(+)e(-) annihilation data collected with the BABAR detector, we measure B(tau(-)->mu(-)(nu) over bar (mu)nu(tau))/B(tau(-)-> e(-)(nu) over bar (e)nu(tau)) = (0.9796 +/- 0.0016 +/- 0.0036), B(tau(-)->pi(-)nu(tau))/B(tau(-)-> e(-)nu(e)nu(tau)) = (0.5945 +/- 0.0014 +/- 0.0061), and B(tau(-)-> K-nu(tau))/B(tau(-)-> e(-)nu(e)nu(tau)) = (0.03882 +/- 0.00032 +/- 0.00057), where the uncertainties are statistical and systematic, respectively. From these precision similar to measurements, we test the standard model assumption of mu - e and tau - mu charge current lepton universality and provide determinations of vertical bar V-us vertical bar experimentally independent of the decay of a kaon

Measurement of |Vcb| and the form-factor slope in B̅ →Dℓ-ν̅ ℓ decays in events tagged by a fully reconstructed B meson

We present a measurement of the Cabibbo-Kobayashi-Maskawa matrix element vertical bar V-cb vertical bar and the form-factor slope rho(2) in (B) over bar -> Dl(-) (nu) over bar (l) decays based on 460 X 10(6) B (B) over bar events recorded at the Gamma(4S) resonance with the BABAR detector. (B) over bar -> Dl(-) (nu) over bar (l) decays are selected in events in which a hadronic decay of the second B meson is fully reconstructed. We measure B(B- -> D(0)l(-) (nu) over bar (l))/B(B- -> Xl(-) (nu) over bar (l)) = (0.255 +/- 0.009 +/- 0.009) and B((B) over bar (0) -> D(+)l(-) (nu) over bar (l))/B((B) over bar (0) -> Xl(-) (nu) over bar (l)) = (0.230 +/- 0.011 +/- 0.011), along with the differential decay distribution in (B) over bar -> Dl(-) (nu) over bar (l) decays. We then determine G(1)vertical bar V-cb vertical bar = 42.3 +/- 1.9 +/- 1.4) X 10(-3) and rho(2) = 1.20 +/- 0.09 +/- 0.04, where G(1) is the hadronic form factor at the point of zero recoil