3,713 research outputs found
Inter- and intra-layer excitons in MoS/WS and MoSe/WSe heterobilayers
Accurately described excitonic properties of transition metal dichalcogenide
heterobilayers (HBLs) are crucial to comprehend the optical response and the
charge carrier dynamics of them. Excitons in multilayer systems posses inter or
intralayer character whose spectral positions depend on their binding energy
and the band alignment of the constituent single-layers. In this study, we
report the electronic structure and the absorption spectra of MoS/WS
and MoSe/WSe HBLs from first-principles calculations. We explore the
spectral positions, binding energies and the origins of inter and intralayer
excitons and compare our results with experimental observations. The absorption
spectra of the systems are obtained by solving the Bethe-Salpeter equation on
top of a GW calculation which corrects the independent particle
eigenvalues obtained from density functional theory calculations. Our
calculations reveal that the lowest energy exciton in both HBLs possesses
interlayer character which is decisive regarding their possible device
applications. Due to the spatially separated nature of the charge carriers, the
binding energy of inter-layer excitons might be expected to be considerably
smaller than that of intra-layer ones. However, according to our calculations
the binding energy of lowest energy interlayer excitons is only 20\%
lower due to the weaker screening of the Coulomb interaction between layers of
the HBLs. Therefore, it can be deduced that the spectral positions of the
interlayer excitons with respect to intralayer ones are mostly determined by
the band offset of the constituent single-layers. By comparing oscillator
strengths and thermal occupation factors, we show that in luminescence at low
temperature, the interlayer exciton peak becomes dominant, while in absorption
it is almost invisible.Comment: 17 pages, 4 figure
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene
We present Raman spectroscopy measurements on single- and few-layer graphene
flakes. Using a scanning confocal approach we collect spectral data with
spatial resolution, which allows us to directly compare Raman images with
scanning force micrographs. Single-layer graphene can be distinguished from
double- and few-layer by the width of the D' line: the single peak for
single-layer graphene splits into different peaks for the double-layer. These
findings are explained using the double-resonant Raman model based on ab-initio
calculations of the electronic structure and of the phonon dispersion. We
investigate the D line intensity and find no defects within the flake. A finite
D line response originating from the edges can be attributed either to defects
or to the breakdown of translational symmetry
Raman imaging of doping domains in graphene on SiO2
We present spatially resolved Raman images of the G and 2D lines of
single-layer graphene flakes. The spatial fluctuations of G and 2D lines are
correlated and are thus shown to be affiliated with local doping domains. We
investigate the position of the 2D line -- the most significant Raman peak to
identify single-layer graphene -- as a function of charging up to |n|~4 10^12
cm^-2. Contrary to the G line which exhibits a strong and symmetric stiffening
with respect to electron and hole-doping, the 2D line shows a weak and slightly
asymmetric stiffening for low doping. Additionally, the line width of the 2D
line is, in contrast to the G line, doping-independent making this quantity a
reliable measure for identifying single-layer graphene
Collisions of Slow Highly Charged Ions with Surfaces
Progress in the study of collisions of multiply charged ions with surfaces is
reviewed with the help of a few recent examples. They range from fundamental
quasi-one electron processes to highly complex ablation and material
modification processes. Open questions and possible future directions will be
discussed.Comment: 13 pages, 16 figures, review pape
New records of marine invertebrates from the coast of Gabon, Eastern Atlantic
An underwater inventory mission was conducted in November 2017 by six
naturalists on the north rocky coast of Gabon between Cape Esterias and
Cape Santa Clara.
The following twenty-six species are recorded from the coast of Gabon for
the first time : the protozoan Zoothamnium niveum, the octocoral Carijoa
riisei, the sea anemone Actinostella flosculifera, the plathelmint Pseudobiceros wirtzi, nine opisthobranch molluscs, the polychaete Eurythoe sp., the
mudshrimp Neaxius mclaughlinae, seven species of true shrimps, a possibly
undescribed pagurid hermit crab, the mantis shrimp Protosquilla sp., the cirriped Conopea saotomensis, and the sea cucumber Isostichopus cf badionotus. For some of these species, this is a large extension of the known range of
distribution. The poorly explored coasts of Gabon apparently harbour many
still undetected species.info:eu-repo/semantics/publishedVersio
Impact of Many-Body Effects on Landau Levels in Graphene
We present magneto-Raman spectroscopy measurements on suspended graphene to
investigate the charge carrier density-dependent electron-electron interaction
in the presence of Landau levels. Utilizing gate-tunable magneto-phonon
resonances, we extract the charge carrier density dependence of the Landau
level transition energies and the associated effective Fermi velocity
. In contrast to the logarithmic divergence of at
zero magnetic field, we find a piecewise linear scaling of as a
function of charge carrier density, due to a magnetic field-induced suppression
of the long-range Coulomb interaction. We quantitatively confirm our
experimental findings by performing tight-binding calculations on the level of
the Hartree-Fock approximation, which also allow us to estimate an excitonic
binding energy of 6 meV contained in the experimentally extracted
Landau level transitions energies.Comment: 10 pages, 6 figure
Study protocol for a cluster-randomized controlled trial of an NCD access to medicines initative: Evaluation of Novartis Access in Kenya
INTRODUCTION: Novartis recently launched Novartis Access, an initiative to provide a basket of reduced price medicines for non-communicable diseases (NCDs) to be sold through the public and private nonprofit sectors in programme countries. This study will evaluate the impact of Novartis Access on the availability and price of NCD medicines at health facilities and households in Kenya, the first country to receive the programme.
METHODS: This study will be a cluster randomised controlled trial. 8 counties in Kenya will be randomly assigned to the intervention or control group using a covariate constrained randomisation method to maximise balance on demographic and health characteristics. In intervention counties, public and private non-profit health facilities will be able to order Novartis Access NCD medicines from the Mission for Essential Drugs and Supplies (MEDS). Data will be collected from a random sample of 384 health facilities and 800 households at baseline, midline after 1-year of intervention, and end-line after 2 years. Quarterly surveillance data will also be collected from health facilities and a subsample of households through phone-based interviews. Households will be eligible if at least one resident has been previously diagnosed and prescribed a medicine for an NCD addressed by Novartis Access, including hypertension and diabetes. The primary outcomes will be availability and price of NCD medicines at health facilities, and availability, price, and expenditures on NCD medicines at households. Impacts will be estimated using intention-to-treat analysis.
ETHICS AND DISSEMINATION: This protocol was approved by the Institutional Review Boards at Strathmore University and at Boston University. Informed consent will be obtained from all participants at the start of the trial. The findings of the trial will be disseminated through peer-reviewed journals, international conferences, and meetings and events organised with local stakeholders
Excitons in boron nitride nanotubes: dimensionality effects
We show that the optical absorption spectra of boron nitride (BN) nanotubes
are dominated by strongly bound excitons. Our first-principles calculations
indicate that the binding energy for the first and dominant excitonic peak
depends sensitively on the dimensionality of the system, varying from 0.7 eV in
bulk hexagonal BN via 2.1 eV in the single sheet of BN to more than 3 eV in the
hypothetical (2,2) tube. The strongly localized nature of this exciton dictates
the fast convergence of its binding energy with increasing tube diameter
towards the sheet value. The absolute position of the first excitonic peak is
almost independent of the tube radius and system dimensionality. This provides
an explanation for the observed "optical gap" constancy for different tubes and
bulk hBN [R. Arenal et al., to appear in Phys. Rev. Lett. (2005)].Comment: 5 pages, 2 figure
First record of Cobia (Rachycentron canadum) (Pisces: Rachycentridae) at the coast of Madeira Island (NE Atlantic Ocean
The Cobia Rachycentron canadum is recorded from Madeira Island for the first time. An individual of this species was encountered and video-documented while SCUBA-diving in about 12 m depth at the south coast of this island.info:eu-repo/semantics/publishedVersio
Collective Total Synthesis of Casbane Diterpenes: One Strategy, Multiple Targets
Of the more than 100 casbane diterpenes known to date, only the eponymous parent hydrocarbon casbene itself has ever been targeted by chemical synthesis. Outlined herein is a conceptually new approach that brings not a single but a variety of casbane derivatives into reach, especially the more highly oxygenated and arguably more relevant members of this family. The key design elements are a catalystâcontrolled intramolecular cyclopropanation with or without subsequent equilibration, chain extension of the resulting stereoisomeric cyclopropane building blocks by chemoselective hydroboration/crossâcoupling, and the efficient closure of the strained macrobicyclic framework by ringâclosing alkyne metathesis. A hydroxyâdirected catalytic transâhydrostannation allows for lateâstage diversity. These virtues are manifested in the concise total syntheses of depressin, yuexiandajisuâ
A, and entâpekineninâ
C. The last compound turned out to be identical to euphorhylonalâ
A, the structure of which had clearly been misassigned
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