14,496 research outputs found
High-precision laser spectroscopy of the CO A - X (2,0), (3,0) and (4,0) bands
High-precision two-photon Doppler-free frequency measurements have been
performed on the CO A - X fourth-positive system (2,0),
(3,0), and (4,0) bands. Absolute frequencies of forty-three transitions, for
rotational quantum numbers up to , have been determined at an accuracy
of cm, using advanced techniques of two-color 2+1'
resonance-enhanced multi-photon ionization, Sagnac interferometry,
frequency-chirp analysis on the laser pulses, and correction for AC-Stark
shifts. The accurate transition frequencies of the CO A - X
system are of relevance for comparison with astronomical data in the search for
possible drifts of fundamental constants in the early universe. The present
accuracies in laboratory wavelengths of may be considered exact for the purpose of such comparisons.Comment: 13 pages, 6 figures, The Journal of Chemical Physics (2015) accepte
Masses of a Fourth Generation with Two Higgs Doublets
We use sampling techniques to find robust constraints on the masses of a
possible fourth sequential fermion generation from electroweak oblique
variables. We find that in the case of a light (115 GeV) Higgs from a single
electroweak symmetry breaking doublet, inverted mass hierarchies are possible
for both quarks and leptons, but a mass splitting more than M(W) in the quark
sector is unlikely. We also find constraints in the case of a heavy (600 GeV)
Higgs in a single doublet model. As recent data from the Large Hadron Collider
hints at the existence of a resonance at 124.5 GeV and a single Higgs doublet
at that mass is inconsistent with a fourth fermion generation, we examine a
type II two Higgs doublet model. In this model, there are ranges of parameter
space where the Higgs sector can potentially counteract the effects of the
fourth generation. Even so, we find that such scenarios produce qualitatively
similar fermion mass distributions.Comment: v2: 9 pages, 7 figures, improved analysis of Higgs decay constraints,
typos corrected and reference adde
Extended coherence time on the clock transition of optically trapped Rubidium
Optically trapped ensembles are of crucial importance for frequency
measurements and quantum memories, but generally suffer from strong dephasing
due to inhomogeneous density and light shifts. We demonstrate a drastic
increase of the coherence time to 21 s on the magnetic field insensitive clock
transition of Rb-87 by applying the recently discovered spin self-rephasing.
This result confirms the general nature of this new mechanism and thus shows
its applicability in atom clocks and quantum memories. A systematic
investigation of all relevant frequency shifts and noise contributions yields a
stability of 2.4E-11 x tau^(-1/2), where tau is the integration time in
seconds. Based on a set of technical improvements, the presented frequency
standard is predicted to rival the stability of microwave fountain clocks in a
potentially much more compact setup.Comment: 5 pages, 4 figure
Continuity of Local Time: An applied perspective
Continuity of local time for Brownian motion ranks among the most notable
mathematical results in the theory of stochastic processes. This article
addresses its implications from the point of view of applications. In
particular an extension of previous results on an explicit role of continuity
of (natural) local time is obtained for applications to recent classes of
problems in physics, biology and finance involving discontinuities in a
dispersion coefficient. The main theorem and its corollary provide physical
principles that relate macro scale continuity of deterministic quantities to
micro scale continuity of the (stochastic) local time.Comment: To appear in: "The fascination of Probability, Statistics and Their
Applications. In honour of Ole E. Barndorff-Nielsen on his 80th birthday
Temperature-dependent expression of a collagen splicing defect in the fibroblasts of a patient with Ehlers-Danlos syndrome type VII.
Abstract In this article we report the characterization of the molecular lesion in a patient with Ehlers-Danlos syndrome Type VII and provide evidence that a de novo substitution of the last nucleotide of exon 6 in one allele of the pro-alpha 2(I) collagen gene produces normally spliced mRNA and transcripts from which exon 6 sequences have been outspliced as well. Unexpectedly, the expression of the alternative splicing was found to be temperature-dependent, for missplicing in cellula is effectively abolished at 31 degrees C and gradually increases to 100% at 39 degrees C. In contrast, in a similar patient harboring a substitution in the obligatory GT dinucleotide of the 5' splice site of intron 6, complete outsplicing of exon 6 sequences was found at all temperatures
Polar phonons and spin-phonon coupling in HgCr2S4 and CdCr2S4
Polar phonons of HgCr2S4 and CdCr2S4 are studied by far-infrared spectroscopy
as a function of temperature and external magnetic field. Eigenfrequencies,
damping constants, effective plasma frequencies and Lyddane-Sachs-Teller
relations, and effective charges are determined. Ferromagnetic CdCr2S4 and
antiferromagnetic HgCr2S4 behave rather similar. Both compounds are dominated
by ferromagnetic exchange and although HgCr2S4 is an antiferromagnet, no phonon
splitting can be observed at the magnetic phase transition. Temperature and
magnetic field dependence of the eigenfrequencies show no anomalies indicating
displacive polar soft mode behavior. However, significant effects are detected
in the temperature dependence of the plasma frequencies indicating changes in
the nature of the bonds and significant charge transfer. In HgCr2S4 we provide
experimental evidence that the magnetic field dependence of specific polar
modes reveal shifts exactly correlated with the magnetization showing
significant magneto-dielectric effects even at infrared frequencies.Comment: 8 pages, 8 figure
Ground-state topology of the Edwards-Anderson +/-J spin glass model
In the Edwards-Anderson model of spin glasses with a bimodal distribution of
bonds, the degeneracy of the ground state allows one to define a structure
called backbone, which can be characterized by the rigid lattice (RL),
consisting of the bonds that retain their frustration (or lack of it) in all
ground states. In this work we have performed a detailed numerical study of the
properties of the RL, both in two-dimensional (2D) and three-dimensional (3D)
lattices. Whereas in 3D we find strong evidence for percolation in the
thermodynamic limit, in 2D our results indicate that the most probable scenario
is that the RL does not percolate. On the other hand, both in 2D and 3D we find
that frustration is very unevenly distributed. Frustration is much lower in the
RL than in its complement. Using equilibrium simulations we observe that this
property can be found even above the critical temperature. This leads us to
propose that the RL should share many properties of ferromagnetic models, an
idea that recently has also been proposed in other contexts. We also suggest a
preliminary generalization of the definition of backbone for systems with
continuous distributions of bonds, and we argue that the study of this
structure could be useful for a better understanding of the low temperature
phase of those frustrated models.Comment: 16 pages and 21 figure
Ferromagnetic Kondo-Lattice Model
We present a many-body approach to the electronic and magnetic properties of
the (multiband) Kondo-lattice model with ferromagnetic interband exchange. The
coupling between itinerant conduction electrons and localized magnetic moments
leads, on the one hand, to a distinct temperature-dependence of the electronic
quasiparticle spectrum and, on the other hand, to magnetic properties, as
e.~g.the Curie temperature T_C or the magnon dispersion, which are strongly
influenced by the band electron selfenergy and therewith in particular by the
carrier density. We present results for the single-band Kondo-lattice model in
terms of quasiparticle densities of states and quasiparticle band structures
and demonstrate the density-dependence of the self-consistently derived Curie
temperature. The transition from weak-coupling (RKKY) to strong-coupling
(double exchange) behaviour is worked out.
The multiband model is combined with a tight-binding-LMTO bandstructure
calculation to describe real magnetic materials. As an example we present
results for the archetypal ferromagnetic local-moment systems EuO and EuS. The
proposed method avoids the double counting of relevant interactions and takes
into account the correct symmetry of atomic orbitals.Comment: 15 pages, 10 figure
Novel Approaches towards Highly Selective Self-Powered Gas Sensors
The prevailing design approaches of semiconductor gas sensors struggle to overcome most of their current limitations such as poor selectivity, and high power consumption. Herein, a new sensing concept based on devices that are capable of detecting gases without the need of any external power sources required to activate interaction of gases with sensor or to generate the sensor read out signal. Based on the integration of complementary functionalities (namely; powering and sensing) in a singular nanostructure, self-sustained gas sensors will be demonstrated. Moreover, a rational methodology to design organic surface functionalization that provide high selectivity towards single gas species will also be discussed. Specifically, theoretical results, confirmed experimentally, indicate that precisely tuning of the sterical and electronic structure of sensor material/organic interfaces can lead to unprecedented selectivity values, comparable to those typical of bioselective processes. Finally, an integrated gas sensor that combine both the self-powering and selective detection strategies in one single device will also be presented. © 2015 Published by Elsevier Ltd.Peer ReviewedPostprint (published version
The use of direct geometry spectrometers in molecular spectroscopy
The advantages and disadvantages of the use of direct geometry spectrometers for molecular spectroscopy and catalysis studies are described. We show that both direct and indirect geometry INS spectrometers are important tools for the study of industrially relevant areas such as catalysis, proton conductors and gas separation. We propose a novel hybrid instrument, Cerberus, that would offer high sensitivity and high-to-reasonable resolution across the entire 'mid-infrared' spectral range that would effectively advance research in these areas
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