Alkali oxide-tantalum oxide and alkali oxide-niobium oxide ionic conductors

A search was made for new cationic conducting phases in alkali-tantalate and niobate systems. The phase equilibrium diagrams were constructed for the six binary systems Nb2O5-LiNbO3, Nb2O5-NaNbO3, Nb2O5-KNbO3, Ta2O5-NaTaO3, Ta2O5-LiTaO3, and Ta2O5-KTaO3. Various other binary and ternary systems were also examined. Pellets of nineteen phases were evaluated (by the sponsoring agency) by dielectric loss measurements. Attempts were made to grow large crystals of eight different phases. The system Ta2O5-KTaO3 contains at least three phases which showed peaks in dielectric loss vs. temperature. All three contain structures related to the tungsten bronzes with alkali ions in non-stoichiometric crystallographic positions

Integration and Conventional Systems at STAR

At the beginning of the design and construction of the STAR Detector, the collaboration assigned a team of physicists and engineers the responsibility of coordinating the construction of the detector. This group managed the general space assignments for each sub-system and coordinated the assembly and planning for the detector. Furthermore, as this group was the only STAR group with the responsibility of looking at the system as a whole, the collaboration assigned it several tasks that spanned the different sub-detectors. These items included grounding, rack layout, cable distribution, electrical, power and water, and safety systems. This paper describes these systems and their performance.Comment: 17 pages, 6 figures, Contribution to a NIM Volume Dedicated to the Detectors and the Accelerator at RHI

Origin and Evolution of Dishevelled

Dishevelled (Dsh or Dvl) is an important signaling protein, playing a key role in Wnt signaling and relaying cellular information for several developmental pathways. Dsh is highly conserved among metazoans and has expanded into a multigene family in most bilaterian lineages, including vertebrates, planarians, and nematodes. These orthologs, where explored, are known to have considerable overlap in function, but evidence for functional specialization continues to mount. We performed a comparative analysis of Dsh across animals to explore protein architecture and identify conserved and divergent features that could provide insight into functional specialization with an emphasis on invertebrates, especially nematodes. We find evidence of dynamic evolution of Dsh, particularly among nematodes, with taxa varying in ortholog number from one to three. We identify a new domain specific to some nematode lineages and find an unexpected nuclear localization signal conserved in many Dsh orthologs. Our findings raise questions of protein evolution in general and provide clues as to how animals have dealt with the complex intricacies of having a protein, such as Dsh, act as a central messenger hub connected to many different and vitally important pathways. We discuss our findings in the context of functional specialization and bring many testable hypotheses to light

Landslide generated impulse waves

Landslide generated impulse waves were investigated in a two-dimensional physical laboratory model based on the generalized Froude similarity. Digital particle image velocimetry (PIV) was applied to the landslide impact and wave generation. Areas of interest up to 0.8m by 0.8m were investigated. The challenges posed to the measurement system in an extremely unsteady three-phase flow consisting of granular matter, air, and water were considered. The complex flow phenomena in the first stage of impulse wave initiation are: high-speed granular slide impact, slide deformation and penetration into the fluid, flow separation, hydrodynamic impact crater formation, and wave generation. During this first stage the three phases are separated along sharp interfaces changing significantly within time and space. Digital masking techniques are applied to distinguish between phases thereafter allowing phase separated image processing. PIV provided instantaneous velocity vector fields in a large area of interest and gave insight into the kinematics of the wave generation process. Differential estimates such as vorticity, divergence, elongational, and shear strain were extracted from the velocity vector fields. The fundamental assumption of irrotational flow in the Laplace equation was confirmed experimentally for these non-linear waves. Applicability of PIV at large scale as well as to flows with large velocity gradients is highlighte

Landslide generated impulse waves. 2. Hydrodynamic impact craters

Landslide generated impulse waves were investigated in a two-dimensional physical laboratory model based on the generalized Froude similarity. Digital particle image velocimetry (PIV) was applied to the landslide impact and wave generation. Areas of interest up to 0.8m by 0.8m were investigated. PIV provided instantaneous velocity vector fields in a large area of interest and gave insight into the kinematics of the wave generation process. Differential estimates such as vorticity, divergence, and elongational and shear strain were extracted from the velocity vector fields. At high impact velocities flow separation occurred on the slide shoulder resulting in a hydrodynamic impact crater, whereas at low impact velocities no flow detachment was observed. The hydrodynamic impact craters may be distinguished into outward and backward collapsing impact craters. The maximum crater volume, which corresponds to the water displacement volume, exceeded the landslide volume by up to an order of magnitude. The water displacement caused by the landslide generated the first wave crest and the collapse of the air cavity followed by a run-up along the slide ramp issued the second wave crest. The extracted water displacement curves may replace the complex wave generation process in numerical models. The water displacement and displacement rate were described by multiple regressions of the following three dimensionless quantities: the slide Froude number, the relative slide volume, and the relative slide thickness. The slide Froude number was identified as the dominant paramete

Alkali oxide-tantalum, niobium and antimony oxide ionic conductors

The phase equilibrium relations of four systems were investigated in detail. These consisted of sodium and potassium antimonates with antimony oxide and tantalum and niobium oxide with rubidium oxide as far as the ratio 4Rb2O:llB2O5 (B=Nb, Ta). The ternary system NaSbO3-Sb2O4-NaF was investigated extensively to determine the actual composition of the body centered cubic sodium antimonate. Various other binary and ternary oxide systems involving alkali oxides were examined in lesser detail. The phases synthesized were screened by ion exchange methods to determine mobility of the mobility of the alkali ion within the niobium, tantalum or antimony oxide (fluoride) structural framework. Five structure types warranted further investigation; these structure types are (1) hexagonal tungsten bronze (HTB), (2) pyrochlore, (3) the hybrid HTB-pyrochlore hexagonal ordered phases, (4) body centered cubic antimonates and (5) 2K2O:3Nb2O5. Although all of these phases exhibit good ion exchange properties only the pyrochlore was prepared with Na(+) ions as an equilibrium phase and as a low porosity ceramic. Sb(+3) in the channel interferes with ionic conductivity in this case, although relatively good ionic conductivity was found for the metastable Na(+) ion exchanged analogs of RbTa2O5F and KTaWO6 pyrochlore phases