11 research outputs found

    IR Spectroscopic Evidence for MoS 2 Morphology Change with Sulfidation Temperature on MoS 2 /Al 2 O 3 Catalyst

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    Accessed by 02/2015International audienceLow temperature CO adsorption followed by IR spectroscopy (IR/CO) characterization was used to depict the MoS2 morphology change with sulfidation temperature on MoS2/Al2O3 catalyst. It is found that the morphology of MoS2 slabs on MoS2/Al2O3 catalyst under typical sulfidation temperature range (573 to 723 K) is a truncated triangle exposing both the M-edge and S-edge. Moreover, the IR/CO data indicate that the truncation degree (ratio of S-edge/M-edge) of MoS2 slabs gradually increases with increasing sulfidation temperature. This finding is in line with density functional theory calculation on model catalysts, providing IR evidence of MoS2 morphology change with sulfidation temperature on an Al2O3-supported catalyst. As a further step, it is also found that the MoS2 morphology is strongly influenced by MoS2–Al2O3 interactions under the same sulfidation temperature

    Dispersive wave emission in dual concentric core fiber: the role of soliton-soliton collisions

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    Soliton–soliton collisions have a crucial role in enhancing the spectrum of dispersive waves in optical fibers and collisions among in-phase solitons lead to a dramatic enhancement of the dispersive wave power, as well as to its significant spectral reshaping. We obtained a simple analytical model to estimate the spectral position, width, and amplitude of the dispersive waves induced by a collision of two in-phase solitons. We tested our theory in the case of a dual concentric core microstructured fiber

    IR Spectroscopic Evidence for MoS<sub>2</sub> Morphology Change with Sulfidation Temperature on MoS<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> Catalyst

    No full text
    Low temperature CO adsorption followed by IR spectroscopy (IR/CO) characterization was used to depict the MoS<sub>2</sub> morphology change with sulfidation temperature on MoS<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> catalyst. It is found that the morphology of MoS<sub>2</sub> slabs on MoS<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> catalyst under typical sulfidation temperature range (573 to 723 K) is a truncated triangle exposing both the M-edge and S-edge. Moreover, the IR/CO data indicate that the truncation degree (ratio of S-edge/M-edge) of MoS<sub>2</sub> slabs gradually increases with increasing sulfidation temperature. This finding is in line with density functional theory calculation on model catalysts, providing IR evidence of MoS<sub>2</sub> morphology change with sulfidation temperature on an Al<sub>2</sub>O<sub>3</sub>-supported catalyst. As a further step, it is also found that the MoS<sub>2</sub> morphology is strongly influenced by MoS<sub>2</sub>–Al<sub>2</sub>O<sub>3</sub> interactions under the same sulfidation temperature

    Spatiotemporal dynamics of the agricultural landscape mosaic drives distribution and abundance of dominant carabid beetles

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    International audienceContext Agroecosystems are dynamic, with yearly changing proportions of crops. Explicit consideration of this temporal heterogeneity is required to decipher population and community patterns but remains poorly studied. Objectives We evaluated the impact on the activity-density of two dominant carabid species (Poecilus cupreus and Anchomenus dorsalis) of (1) local crop, current year landscape composition, and their interaction, and (2) inter-annual changes in landscape composition due to crop rotations. Methods Carabids were sampled using pitfall-traps in 188 ïŹelds of winter cereals and oilseed rape in three agricultural areas of western France contrasting in their spatial heterogeneity. We summarized landscape composition in the current and previous years in a multi-scale perspective, using buffers of increasing size around sampling locations. Results Both species were more abundant in oilseed rape, and in landscapes with a higher proportion of oilseed rape in the previous year. P. cupreus abundance was negatively inïŹ‚uenced by oilseed rape proportion in the current year landscape in winter cereals and positively by winter cereal proportion in oilseed rape. A. dorsalis was globally impacted at ïŹner scales than P. cupreus. Conclusions Resource concentration and dilution-concentration processes jointly appear to cause transient dynamics of population abundance and distribution among habitat patches. Inter-patch movements across years appear to be key drivers of carabids’ survival and distribution, in response to crop rotation. Therefore, the explicit consideration of the spatiotemporal dynamics of landscape composition can allow future studies to better evidence ecological processes behind observed species patterns and help developing new management strategies
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