Synthesis of Ni Nanoparticles by Pulsed Laser Ablation Method in Liquid Phase

AbstractLaser ablation in liquids has been intensively studied in recent years, due to present numerous potentials in laser material micro-processing, including nanomaterials and nanostructures synthesize. Compared to others, typically chemical methods, pulsed laser ablation (PLA) in liquid is a simple and “green” technical method that normally operates in water or organic liquids under ambient conditions. Here, pure Ni nanostrutures were synthesized using PLA method in 30mL of acetone. A simple fiber pulsed laser setup has been not only employed to reduce the micron Ni particles to nano-sized by the PLA method, but also with no-induced oxidation at room temperature and free additive in liquid. The particle size, spectral analysis and morphology of the products were characterized by UV-vis spectrometry, energy-dispersive X-ray spectroscopy (EDX) and transmission electron microscopy (TEM). The TEM image indicates spherical shapes with a narrow size distribution, compared with other methods, with ∼10nm in diameter respectively

In situ cathode-electrolyte interphase enables high cycling stability of Co-free Li-rich layered cathodes

Despite the extensive research in Li-rich layered oxides (LLOs), which are promising candidates for high-energy density cathodes, their cycle life still cannot meet the real-world application requirements. The poor cycle performance arises from the electrolyte decomposition at high voltage, resulting in damage and subsequent surface-initiated conversion of the cathode from layered to spinel phase. This problem is even more challenging for Co-free LLO cathodes. Here, we report a one-pot synthesis of in situ carbonate-coated nanostructured Co-free LLO (Li2CO3@LLO) through a polyol-assisted method. This inorganic coating suppresses oxygen release, provides good Li–ion transport, and protects the cathode from adverse reactions with the electrolyte. The obtained material exhibits excellent long-term stability, with 76% capacity retention after 1000 cycles at a 0.2 C rate without any Co addition, demonstrating a path forward for using LLOs as a next-generation Li–ion battery cathode